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πd相互作用をもつ磁性分子導体の新機能

Research Project

Project/Area Number 15073211
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

森 健彦  Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (60174372)

Co-Investigator(Kenkyū-buntansha) 榎 敏明  東京工業大学, 大学院・理工学研究科, 教授 (10113424)
宮崎 章  東京工業大学, 大学院・理工学研究科, 助教 (40251607)
川本 正  東京工業大学, 大学院・理工学研究科, 助教 (60323789)
Project Period (FY) 2003 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥55,200,000 (Direct Cost: ¥55,200,000)
Fiscal Year 2007: ¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 2006: ¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 2005: ¥20,400,000 (Direct Cost: ¥20,400,000)
Fiscal Year 2004: ¥11,900,000 (Direct Cost: ¥11,900,000)
Fiscal Year 2003: ¥11,100,000 (Direct Cost: ¥11,100,000)
Keywords電荷移動錯体 / 有機超伝導 / 非線形伝導 / 電荷整列 / 電化移動錯体 / インコメンシュレート / 有機FET / πd相互作用 / 有機サイリスタ / フェリ磁性 / スピンラダー
Research Abstract

有機電荷移動錯体の巨大非線形伝導とそれによる電流振動現象を不均一に生じた電荷整列の競合によって解明した。最初にこのような現象が発見されたθ相の有機導体以外に、(TMET-TTP)(PF_6)_<0.27>、(R_2DCNQI)_2Cu、(MDT-TS)(I_2Br)_<0.42>といった有機導体で相次いで同様の巨大非線形伝導を見出し、なかでも最後の物質については、θ相以外で初めて自発電流振動(有機サイリスタ)を確認した。有機超伝導体κ_L-(DMEDO-TSeF)_2[Au(CN)_4](THF)の構造相転移と低温強磁場の磁気抵抗から、インコヒーレントな伝導層に関連した特異な物性を明らかにした。またα-(BEDT-TTF)_2I_3において提案されているゼロギャップ状態について、強結合近似の立場から一般にゼロギャップ状態の出現条件について検討し、ノンストライプ電荷整列がゼロギャップ状態の出現に重要である可能性を指摘した。有機トランジスタのソース・ドレイン電極に金属的な電荷移動錯体である(TTF)(TCNQ)を用いることによって、電極での接触抵抗が低減され、特にボトム・コンタクト型のFETについて効果が著しいことを、ペンタセン、DB-TTFなどについて明らかにした。他のAu, Ag, Cu電極などと比較することによって、金属電極の場合には有機/金属界面におけるポテンシャルシフトが著しいが、有機電極はポテンシャルシフトがほぼゼロの系として有用であることが分かった。(TTF)(TCNQ)電極はn型トランジスタの場合にも使用でき、特にDCNQIを活性層とする有機トランジスタでは空気に安定なn型デバイスが実現できる。

Report

(6 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (114 results)

All 2008 2007 2006 2005 2004 Other

All Journal Article (70 results) (of which Peer Reviewed: 20 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results) Publications (39 results)

  • [Journal Article] Solution-Processed Carbon Electrodes for Organic Field-Effect Transistors2008

    • Author(s)
      H. Wada, T. Mori
    • Journal Title

      Appl. Phys. Lett. 93

      Pages: 213303-213303

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Organic Field-Effect Transistors Based on Alkyl-Terminated Tetrathiapentalene (TTP) Derivatives2008

    • Author(s)
      Y. Bando, T. Shirahata, K. Shibata, H. Wada, T. Mori, T. Imakubo
    • Journal Title

      Chem. Mater. 20

      Pages: 5119-5121

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Contact Resistance and Electrode Material Dependence of Air-Stablen-Channel Organic Field-Effect Transistors Using Dimethyldicyanoquinonediimine (DMDCNQI)2008

    • Author(s)
      H. Wada, K. Shibata, Y. Bando, T. Mori
    • Journal Title

      J. Mater. Chem. 18

      Pages: 4165-4171

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Giant Nonlinear Conductivity and Spontaneous Current Oscillation in an Incommensurate Organic Conductor2008

    • Author(s)
      T. Mori. Y. Bando, T. Kawamoto. I. Terasaki, K. Takimiya, T. Otsubo
    • Journal Title

      Phys. Rev. Lett. 100

      Pages: 37001-37001

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Contact Resistance of Dibenzotetrathiafulvalene-Based Organic Transistors with Metal and Organic Electrodes2008

    • Author(s)
      K. Shibata, K. Ishikawa, H. Takezoe, H. Wada, T. Mori
    • Journal Title

      Appl. Phys. Lett. 92

      Pages: 3305-3305

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Giant Nonlinear Conductivity and Spontaneous Current Oscillation in an Incom mensurate Organic Conductor2008

    • Author(s)
      T.Mori, Y. Bando, T.Kawamoto, I.T erasaki, K. Takimiya, and T. Otsubo
    • Journal Title

      Phys. Rev. Lett. 100

      Pages: 37001-37001

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isotropic Uniaxial Strain Effect on the Incommensurate Organic Superconductor:(MDT-TS)(AuI_2)_0.44I2008

    • Author(s)
      Y. Bando, T. Kawamoto, T. Mori, K. Takimiya, and T. Otsubo
    • Journal Title

      J. Phys. Soc. Jpn. 77

      Pages: 14706-14706

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Contact Resistance of Dibenzotetrathiafulvalene-Based Organic Transistors with Metal and Organic Electrodes2008

    • Author(s)
      K. Shibata, K. Ishikawa, H. Takezoe, H. Wada, and T. Mori
    • Journal Title

      Appl. Phys. Lett. 92

      Pages: 3305-3305

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Domain Formation in the Structural Phase Transition of the Organic Superconductor κ_L-(DMED0-TSeF)_2[Au(CN)_4](THF)2007

    • Author(s)
      T. Kawamoto. T. Mori. T. Kakiuchi, H. Sawa
    • Journal Title

      Phys. Rev. B 76

      Pages: 134517-134517

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] New aspects of nonlinear conductivity in organic charge-transfer salts2007

    • Author(s)
      T. Mori. I. Terasaki, H. Mori
    • Journal Title

      J Mater. Chem. (Highlight) 17

      Pages: 4343-4347

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Nonlinear Conductivity with an Extremely Small Threshold Electric Field in the Organic Conductor (TSM-TTP)(I_3)_<5/3>2007

    • Author(s)
      T. Mori. T. Kawamoto. I. Terasaki, T, Kakiuchi, H. Sawa
    • Journal Title

      Phys. Rev. B 75

      Pages: 235103-235103

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Organic Conductors - From Fundamentals to Nonlinear Conductivity2007

    • Author(s)
      T. Mori, T. Kawamoto
    • Journal Title

      Ann. Rep. Prog. Chem. Sect. C Phys. Chem. (Review) 103

      Pages: 134-172

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Domain Formation in the Structural Phase Transition of the Organic Superconductor k_L-(DMEDO-TSeF)_2[Au(CN)_4](THF)2007

    • Author(s)
      T. Kawamoto, T. Mori, T. Kakiuchi, and H. Sawa
    • Journal Title

      Phys. Rev. B 76

      Pages: 134517-134517

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New aspects of nonlinear conductivity in organic charge-transfer salts2007

    • Author(s)
      T. Mori, I. Terasaki and H. Mori
    • Journal Title

      J Mater. Chem. (Highlight) 17

      Pages: 4343-4347

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonlinear Conductivity with an Extremely Small Threshold Electric Field in the Organic Conductor (TSM-TTP)(I_3)_5/32007

    • Author(s)
      T, Mori, T. Kawamoto, I. Terasaki, T. Kakiuchi, and H. Sawa
    • Journal Title

      Phys. Rev. B 75

      Pages: 235103-235103

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Conductors - From Fundamentals to Nonlinear Conductivity2007

    • Author(s)
      T. Mori and T. Kawamoto
    • Journal Title

      Ann. Rep. Prog. Chem. Sect. C Phys. Chem. (Review) 103

      Pages: 134-172

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Air Stability of n-Channel Organic Transistors Based on Nickel Coordination Compounds2007

    • Author(s)
      H. Wada, T. Taguchi, B. Noda, T. Kambayashi, T. Mori, K. Ishikawa, and H. Takezoe
    • Journal Title

      Organic Electronics 8

      Pages: 759-766

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures and transistor properties of phenyl-substituted tetrathiafulvalene derivatives2007

    • Author(s)
      B. Noda, H. Wada, K. Shibata, T. Yoshino, M. Katsuhara, I Aoyagi, T. Mori, T. Taguchi, T. Kambayashi, K. Ishikawa, and H. Takezoe
    • Journal Title

      Nanotechnology 18

      Pages: 424009-424009

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (Tetrathiafhlvalene)(Tetracyanoquinodimethane)as a Low-Contact-Resistance Electrode for Organic Transistors2007

    • Author(s)
      K. Shibata, H. Wada, K. Ishikawa, H. Takezoe, and T. Mori
    • Journal Title

      Appl. Phys. Lett. 90

      Pages: 193509-193509

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] T. Hiraoka, H. Fujiwara, T.Sugimoto, H. Nakazumi, S. Noguchi, A. Kuribayashi, T. Ishida, K. Yokogawa, K. Murata, T. Mori, H. Aruga-Katori S. Kimura, and M. Hagiwara2007

    • Author(s)
      T. Hiraoka, H. Fujiwara, T.Sugimoto, H. Nakazumi, S. Noguchi, A. Kuribayashi, T. Ishida, K. Yokogawa, K. Murata, T. Mori, H. Aruga-Katori S. Kimura, and M. Hagiwara
    • Journal Title

      J. Mater. Chem. 17

      Pages: 1664-1673

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Current-Induced Metallic State in an Organic(EDT-TSF)_2GaCl_4 Conductor2006

    • Author(s)
      H. Endo, T. Kawamoto, T. Mori. I. Terasaki, T. Kakiuchi, H. Sawa, M. Kodani, K. Takimiya, T. Otsubo
    • Journal Title

      J. Am. Chem. Soc. 128・18

      Pages: 9006-9007

    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Charge Transfer Degree and Superconductivity of the Incommensurate Organic Superconductor (MDT-TSF)(I_3)_<0.422>2006

    • Author(s)
      T. Kawamoto, T. Mori. T. Konoike, K. Enomoto, T. Terashima, S. Uji, K. Takimiya, T. Otsubo
    • Journal Title

      Phys. Rev. B 73

      Pages: 94513-94513

    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Many-body Effect on the Superconducting Transition Temperature in Layered Organic Superconductors2006

    • Author(s)
      T. Kawamoto, T. Mori
    • Journal Title

      Phys. Rev, B 74

      Pages: 212502-212502

    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Fermi Surface of the Organic Superconductor (MDT-ST)(I_3)_<0.417> Reconstructed by Incommensurate Potential2006

    • Author(s)
      T. Kawamoto. T. Mori. K. Enomoto, T. Konoike, T. Terashima, S. Uji, A. Takamori, K. Takimiya, T. Otsubo
    • Journal Title

      Phys. Rev. B 73

      Pages: 24503-24503

    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Current-Induced Metallic State in an Organic (EDT-TSF)_2GaCl_4 Conductor2006

    • Author(s)
      H.Endo, T.Kawamoto, T.Mori, I.Terasaki, T.Kakiuchi, H.Sawa, M.Kodani, K.Takimiya, T.Otsubo
    • Journal Title

      J. Am. Chem. Soc. 128・18

      Pages: 9006-9007

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Charge Transfer Degree and Superconductivity of the Incommensurate Organic Superconductor (MDT-TSF)(I_3)_<0.422>2006

    • Author(s)
      T.Kawamoto, T.Mori, T.Konoike, K.Enomoto, T.Terashima, S.Uji, K.Takimiya, T.Otsubo
    • Journal Title

      Phys. Rev. B 73

      Pages: 94513-94513

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Many-body Effect on the Superconducting Transition Temperature in Layered Organic Superconductors2006

    • Author(s)
      T.Kawamoto, T.Mori
    • Journal Title

      Phys. Rev. B 74

      Pages: 212502-212502

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fermi Surface of the Organic Superconductor (MDT-ST)(I_3)_<0.417> Reconstructed by Incommensurate Potential2006

    • Author(s)
      T.Kawamoto, T.Mori, K.Enomoto, T.Konoike, T.Terashima, S.Uji, A.Takamori, K.Takimiya, T.Otsubo
    • Journal Title

      Phys. Rev. B 73

      Pages: 24503-24503

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A High-Conductivity Crystal Containing a Copper(I) Coordination Polymer Bridged by the Organic Acceptor TANC2006

    • Author(s)
      M.Tadokoro, S.Yasuzuka, M.Nakamura, T.Shinoda, T.Tatenuma, M.Mitsumi, Y.Ozawa, K.Toriumi, H.Yoshino, D.Shiomi, K.Sato, T.Takui, T.Mori, K.Murata
    • Journal Title

      Angew. Chem. Int. Ed 45

      Pages: 5144-5147

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Metallic (EDT-DSDTFVSDS)_2FeBr_4 Salt : Antiferromagnetic Ordering of d Spins of FeBr_4^- Ions and Anomalous Magnetoresistance Due to Preferential π-d Interaction2006

    • Author(s)
      T.Hayashi, X.Xiao, H.Fujiwara, T.Sugimoto, H.Nakazumi, S.Noguchi, T.Fujimoto, S.Yasuzuka, H.Yoshino, K.Murata, T.Mori, H.Aruga-Katori
    • Journal Title

      J. Am. Chem. Soc. 128・36

      Pages: 11746-11747

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrical and Structural Properties of q-Type BEDT-TTF Organic Conductors under Uniaxial Strain2006

    • Author(s)
      R.Kondo, M.Higa, S.Kagoshima, H.Hoshino, T.Mori, H.Mori
    • Journal Title

      J. Phys. Soc. Jpn 75・4

      Pages: 44716-44716

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Metallization of (TTM-TTP)I_3 with a Highly One-Dimensional Half-Filled Band under Extremely High Pressure2006

    • Author(s)
      S.Yasuzuka, K.Murata, T.Fujimoto, M.Shimotori, T.Kawamoto, T.Mori, M.Hedo, Y.Uwatoko
    • Journal Title

      J. Phys. Soc. Jpn 75・5

      Pages: 53701-53701

    • NAID

      110004702310

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Magnetoresistance Effects Evidencing the p-d Interaction in Metallic Organic Conductors, (EDT-DSDTFVO)_2MX_4 (M=Fe, Ga; X=C1, Br)2006

    • Author(s)
      H.Fujiwara, T.Hayashi, T.Sugimoto, H.Nakazumi, S.Noguchi, L.Li, K.Yokogawa, S.Yasuzuka, K.Murata, T.Mori
    • Journal Title

      Inorg. Chem 45・15

      Pages: 5712-5714

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Anomalous Metallic State in (TTM-TTP)I_3 with a Highly One-Dimensional Half-Filled Band under Pressure beyond 7 GPa2006

    • Author(s)
      S.Yasuzuka, K.Murata, T.Fujimoto, M.Shimotori, T.Kawamoto, T.Mori, M.Hedo, Y.Uwatoko
    • Journal Title

      J. Low Temp. Phys 142・3/4

      Pages: 197-200

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Enhancement of Conductivity in Poly(3-hexylthiophene) Films Prepared by Spin-Coating from Blended Solutions with Small Molecules2006

    • Author(s)
      T.Kambayashi, M.Goto, T.Mori, B.Park, K.Ishikawa, H.Takezoe
    • Journal Title

      Org. Electronics, 7 7

      Pages: 440-444

    • Related Report
      2006 Annual Research Report
  • [Journal Article] An Organic Thyristor2005

    • Author(s)
      F. Sawano, I. Terasaki, H. Mori, T. Mori, M. Watanabe, N. Ikeda, Y. Nogami, Y. Noda
    • Journal Title

      Nature 437

      Pages: 522-525

    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Infrared and Raman Studies of the Phase Transition in the Organic Conductor (TTM-TTP)I_32005

    • Author(s)
      R.Swietlik, K.Yakushi, K.Yamamoto, T.Kawamoto, T.Mori
    • Journal Title

      Synth.Met. 150

      Pages: 83-92

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Anisotropic Three-Dimensional Superconductivity of the Incommensurate Organic Superconductor (MDT-ST)(I_3)_<0.417>2005

    • Author(s)
      T.Kawamoto, T.Mori, T.Terashima, S.Uji, A.Takamori, K.Takimiya, T.Otsubo
    • Journal Title

      J.Phys.Soc.Jpn 74(5)

      Pages: 1529-1533

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structural and Transport Properties of the Incommensurate Organic Superconductor (MDT-ST)(I_3)_<0.417>2005

    • Author(s)
      T.Kawamoto, T.Mori, S.Uji, J.Yamada, H.Kitagawa, A.Takamori, K.Takimiya, T.Otsubo
    • Journal Title

      Phys.Rev.B 71

      Pages: 172503-172503

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Metallic Transport and Ferromagnetic Interaction Achieved by Band Filling Control in Organic Conductors ; β'-ET_3(MCl_4^<2->)_<2-x>(M'Cl_4^<2->)_x [M = Co, Zn, M' = Ga, Fe]2005

    • Author(s)
      M.Suto, K.Yamashita, H.Suzuki, K.Yoshimi, S.Kimura, H.Mori, T.Kawamoto, T.Mori, Y.Nishio, K.Kajita
    • Journal Title

      J.Phys.Soc.Jpn 74(7)

      Pages: 2061-2068

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Organic Field-effect Transistors Based on Tetrathiafulvalene Derivatives2005

    • Author(s)
      B.Noda, M.Katsuhara, I.Aoyagi, H.Nakajima, T.Mori, T.Taguchi, T.Kambayashi, M.Ofuji, Y.Takanishi, K.Ishikawa, H.Takezoe
    • Journal Title

      IPAP Conference Series 6

      Pages: 154-157

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A New Type of Uniformly Stacked Phase in Tetrathiapentalene-Based Organic Metals2005

    • Author(s)
      Y.Bando, T.Matsuzawa, N.Takashita, T.Kawamoto, T.Mori, J.Yamada
    • Journal Title

      Bull.Chem.Soc.Jpn 78(9)

      Pages: 1442-1449

    • NAID

      10019038975

    • Related Report
      2005 Annual Research Report
  • [Journal Article] An Organic Thyristor2005

    • Author(s)
      F.Sawano, I.Terasaki, H.Mori, T.Mori, M.Watanabe, N.Ikeda, Y.Nogami, Y.Noda
    • Journal Title

      Nature 437

      Pages: 522-522

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structures and Physical Properties of New β''-BEDT-TTF Tris-Oxalatometallate (III) Salts Containing Chlorobenzene and Halomethane Guest Molecules2005

    • Author(s)
      A.Akutsu-Sato, A.Kobayashi, T.Mori, H.Akutsu, J.Yamada, S.Nakatsuji, S.S.Turner, P.Day, D.A.Tocher, M.E.Light, M.B.Hurstho
    • Journal Title

      Synth.Met. 152

      Pages: 373-376

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Tetrathiafulvalene [Fe^<III>(C_2O_4)Cl_2] : An Organic-Inorganic Hybrid Exhibiting Canted Antiferromagnetism2005

    • Author(s)
      B.Zhang, Z.Wang, H.Fujiwara, H.Kobayashi, M.Kurmoo, K.Inoue, T.Mori, S.Gao, Y.Zhang, D.Zhu
    • Journal Title

      Adv.Mater 17(16)

      Pages: 1988-1991

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dielectric ordering and colossal magnetodielectricity in the antiferromagnetic insulating state of λ-(BEDT-TSF)_2FeCl_42005

    • Author(s)
      E.Negishi, T.Kuwabara, S.Komiyama, M.Watanabe, Y.Noda, T.Mori, H.Matsui, N.Toyota
    • Journal Title

      Phys.Rev.B 71

      Pages: 12416-12416

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Stable Metallic Behavior and Antiferromagnetic Ordering of Fe(III) d Spins in (EDO-TTFVO)_2FeCl_42005

    • Author(s)
      H.Fujiwara, K.Wada, T.Hiraoka, T.Hayashi, T.Sugimoto, H.Nakazumi, K.Yokogawa, M.Teramura, S.Yasuzuka, K.Murata, T.Mori
    • Journal Title

      J.Am.Chem.Soc 127

      Pages: 14166-14167

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The first proton-conducting metallic ion-radical salts2005

    • Author(s)
      A.Akutsu-Sato, H.Akutsu, S.S.Turner, P.Day, M.P.Probert, J.A.K.Howard, T.Akutagawa, S.Takeda, T.Nakamura, T.Mori
    • Journal Title

      Angew.Chem.Int.Ed 44(2)

      Pages: 292-295

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Estimation of πd-Interactions in magnetic molecular conductors2005

    • Author(s)
      T.Mori, M.Katsuhara, H.Akutsu, K.Kikuchi, J.Yamada, H.Fujiwara, T.Matsumoto, T.Sugimoto
    • Journal Title

      Polyhedron 24

      Pages: 2315-2320

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Electronic and magnetic properties of π-d interaction system (EDTDM)_2FeBr_42005

    • Author(s)
      K.Okabe, J.-I.Yamaura, A.Miyazaki, T.Enoki
    • Journal Title

      J.Phys.Soc.Jpn. 74

      Pages: 1508-1520

    • Related Report
      2005 Annual Research Report
  • [Journal Article] π-d Interaction-based molecular magnets : Role of sulfur-to-selenium substitution2005

    • Author(s)
      A.Miyazaki, K.Okabe, K.Enomoto, T.Enoki
    • Journal Title

      Phosphorus, Sulfur, and Silicon 180

      Pages: 883-890

    • Related Report
      2005 Annual Research Report
  • [Journal Article] d-Electron-Induced Negative Magnetoresistance of π-d Interaction System Including Brominated-TTF Donor2005

    • Author(s)
      J.Nishijo, A.Miyazaki, T.Enoki
    • Journal Title

      Inorg.Chem 44

      Pages: 2493-2506

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Superconductivity Competing with the Incommensurate Antiferromagnetic Insulating State in the Organic Conductor (MDT-TS)(AuI2)0.4412005

    • Author(s)
      T.Kawamoto, Y.Bando, T.Mori, K.Takimiya, T.Otsubo
    • Journal Title

      Phys.Rev.B 71

      Pages: 52501-52501

    • NAID

      120000879791

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Organic field-effect transistor based on biphenyl substituted TTF2005

    • Author(s)
      B.Noda, M.Katsuhara, I.Aoyagi, T.Mori, T.Taguchi, T.Kambayashi, K.Ishikawa, H.Takezoe
    • Journal Title

      Chem.Lett 34(3)

      Pages: 392-393

    • NAID

      10014464794

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Alloyed Transition-Metal Complexes of Tricyanomethide (tcm), [Mn_<1-x>Co_x(tcm)_2]2004

    • Author(s)
      M.Sayaduzzaman, M.Katsuhara, H.Hoshino, T.Kawamoto, T.Mori
    • Journal Title

      Appl.Organomet.Chem 18

      Pages: 176-180

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Properties of Alkyl-Substituted BEDT-TTF Molecules for Organic Thin Film Devices2004

    • Author(s)
      M.Katsuhara, I.Aoyagi, T.Mori
    • Journal Title

      J.Phys.IV France 114

      Pages: 515-516

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Incommensurate Structure and the Superconducting Properties of the Organic Superconductor (MDT-ST)(I_3)_<0.417>2004

    • Author(s)
      T.Kawamoto, T.Mori, T.Terashima, S.Uji, H.Kitagawa, K.Takimiya, A.Takamori, T.Otsubo
    • Journal Title

      J.Phys.IV France 114

      Pages: 517-519

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Conducting Properties of Tris-Fused Tetrathiafulvalenes2004

    • Author(s)
      T.Mori, A.Ashizawa, S.Kimura, A.Akutsu-Sato, B.Noda, Y.Misaki, K.Takimiya
    • Journal Title

      J.Phys.IV France 114

      Pages: 549-551

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Syntheses and Structures of Highly Soluble Bis(ethylenedithio) tetrathiafulvalene Molecules with Alkyl Chains2004

    • Author(s)
      Aoyagi, M.Katsuhara, T.Mori
    • Journal Title

      Sci.Tech.Adv.Mater 5

      Pages: 443-443

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Structures of Highly Conducting Charge-Trasfer Salts of Selenium Containing TTM-TTP Derivatives2004

    • Author(s)
      M.Ashizawa, A.Akutsu, B.Noda, H.Nii, T.Kawamoto, T.Mori, T.Nakayashiki, Y.Misaki, K.Tanaka, K.Takimiya, T.Otsubo
    • Journal Title

      Bull.Chem.Soc.Jpn. 77(1)

      Pages: 1449-1458

    • Related Report
      2004 Annual Research Report
  • [Journal Article] An Organic Spin Ladder System, (BEDT-TTF)[Co(mnt)_2]2004

    • Author(s)
      H.Nakajima, M.Katsuhara, H.Nii, M.Ashizawa, T.Kawamoto, T.Mori
    • Journal Title

      Synth.Metals 145

      Pages: 95-101

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Ferromgnetic Anomaly Associated with the Antiferromagnetic Transitions in (Donor) [Ni(mnt)_2]-Type Charge-Transfer Salts2004

    • Author(s)
      H.Nakajima, M.Katsuhara, T.Kawamoto, T.Mori
    • Journal Title

      Inorg.Chem 43(19)

      Pages: 6075-6082

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Organic Conductors with Unusual Band Fillings2004

    • Author(s)
      T.Mori
    • Journal Title

      Chem.Rev 104(11)

      Pages: 4947-4970

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Estimation of Magnetic Interactions and Magnetic Structures in Charge-transfer Salts Based on [Cr(isoq)_2(NCS)_4]^- (isoq=Isoquinoline)2004

    • Author(s)
      M.Katsuhara, T.Mori
    • Journal Title

      J.Phys.Soc.Jpn. 73(12)

      Pages: 3335-3340

    • NAID

      110001979303

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Large Dielectric Constant and Giant Nonlinear Conduction in the Organic Conductor θ-(BEDT-TTF)_2CsZn(SCN)_42004

    • Author(s)
      K.Inagaki, I.Terasaki, H.Mori, T.Mori
    • Journal Title

      J.Phys.Soc.Jpn. 73(12)

      Pages: 3364-33469

    • NAID

      110001979306

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Magnetic TTF-Based Charge-Transfer Complexes2004

    • Author(s)
      T.Enoki, A.Miyazaki
    • Journal Title

      Chem.Rev 104

      Pages: 5449-5477

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structure and Physical Properties of Molecule-Based Magnets Including Transition Metal Complexes of Crown Thioethers2004

    • Author(s)
      J.Nishijo, A.Miyazaki, T.Enoki
    • Journal Title

      Bull.Chem.Soc.Jpn. 77

      Pages: 715-727

    • NAID

      10012849005

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Strong π-d Interaction Based on Brominated TTF-type Donor EDT-TTFBr_22004

    • Author(s)
      J.Nishijo, A.Miyazaki, T.Enoki, R.Watanabe, Y.Kuwatani, M.Iyoda
    • Journal Title

      J.Phys.IV 114

      Pages: 561-563

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Crystal Structure and Physical Properties of (EDO-TTFBr_2)_2FeX_4 (X=Cl,Br)2004

    • Author(s)
      A.Miyazaki, M.Aimatsu, H.Yamazaki, T.Enoki, K.Ugawa, E.Ogura, Y.Kuwatani, M.Iyoda
    • Journal Title

      J.Phys.IV 114

      Pages: 545-547

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Multiproperty Molecular Materials : TTF-Based Conducting and Magnetic Molecular Materials2004

    • Author(s)
      L.Ouahab, T.Enoki
    • Journal Title

      Eur.J.Inorg.Chem

      Pages: 933-941

    • Related Report
      2004 Annual Research Report
  • [Book] 有機トランジスタ材料の評価と応用II2008

    • Author(s)
      森健彦, 長谷川達生監修
    • Total Pages
      233
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Final Research Report Summary
  • [Remarks]

    • URL

      http://www.op.titech.ac.jp/lab/mori/public.html

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 特許2008

    • Inventor(s)
      森健彦, 和田拓
    • Industrial Property Rights Holder
      東京工業大学
    • Filing Date
      2008-08-29
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許2008

    • Inventor(s)
      森健彦, 吉野剛正
    • Industrial Property Rights Holder
      東京工業大学
    • Acquisition Date
      2008-03-26
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 有機半導体材料及び有機トランジスタ2008

    • Inventor(s)
      森健彦、吉野剛正
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2008-081455
    • Filing Date
      2008-03-26
    • Related Report
      2007 Annual Research Report
    • Overseas
  • [Publications] T.Kawamoto, T.Mori他5名: "Incommensurate Anion Potential Effect on the Electronic States of the Organic Superconductor (MDT-TSF)(AuI_2)_<0.436>"Phys.Rev.B. 67. 020508(R) (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kimura, T.Mori他4名: "Ethylenedioxy-Containing Tetrathiapentalene Derivative with Ethylthio Chains, C_2TEO-TTP"Bull.Chem.Soc.Jpn.. 76(1). 89-96 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Mori, M.Katsuhara: "Estimation of Magnetic Interactions in Mixed-Stack Molecular Ferrimagnets"J.Phys.Soc.Jpn.. 72(1). 149-154 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Takimiya, A.Takamori, Y.Aso, T.Otsubo, T.Kawamoto, T.Mori: "Organic Superconductors Based on a New Electron Donor, Methylenedithiodiselenadithiafulvalene (MDT-ST)"Chem.Mater. 15(6). 1225-1227 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Mori, M.Katsuhara, S.Kimura, Y.Misaki, K.Tanaka: "Charge-Ordered Subphases and Band Filling Control in Uniform Two-and One-Dimensional Organic Conductors"Synth.Metals. 133-134. 281-282 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kimura, H.Nii, H.Kurai, T.Mori: "Oxygen Containing Tetrathiapentalene Derivatives Having Ethylthio Chains"Synth.Metals. 133-134. 365-366 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Katsuhara, T.Mori: "Estimation of Magnitude of Magnetic Interactions in Organic Conductors"Synth.Metals. 133-134. 573-575 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kagoshima, T.Mori他5名: "Uniaxial Strain Study of Electronic and Crystal Structures of Organic Conductors"Synth.Metals. 133-134. 145-146 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Shirahata, T.Mori, R.Kato, K.Takahashi: "Synthesis, Cyrstal Structures and Electrical Properties of Cation Radical Salts of Selenium-Containing π-Extended Donors, BEDT-HBDST and BEDT-HSTT"Synth.Metals. 133-134. 321-324 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M Uruichi, T.Mori他4名: "Characterization of Quasi-1D Conductors,(BDTFP)_2X(PhCl)_<0.5>(X=PF_6,AsF_6)"Synth.Metals. 133-134. 133-134 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Yakushi, T.Mori他5名: "Charge Disproportionation in the Charge-Transfer Salts of TTP"Synth.Metals. 133-134. 583-585 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Ashizawa, T.Kawamoto, T.Mori他5名: "Synthesis and Properties of Selenium Containing TTM-TTP Conductors"Synth.Metals. 133-134. 627-628 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nogami, T.Mori, T.Kawamoto他3名: "Superlattice Structure Analysis of (TTM-TTP)I_3 at Low Temperatures"Synth.Metals. 133-134. 637-638 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Ohta, T.Mori他6名: "Magneto-Optical Measurements of β-(BEDT-TTF)_2AuI_2"Synth.Metals. 133-134. 527-528 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kimura, H.Kurai, T.Mori: "Highly Conducting Single-Component Crystals Based on Tetrathiapentalene (TTP) Derivatives with Four Long Alkylthio Chains"Synth.Metals. 133-134. 609-610 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Katsuhara, S.Kimura, T.Mori: "Structures and Properties of Radical Cation Salts Based on Chlorinated TTF and TTP Donors"Synth.Metals. 133-134. 625-626 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Misaki, T.Nakayashiki, S.Yoshida, K.Tanaka, T.Mori: "Structure and Properties of SMEO-ST-TTP Salts"Synth.Metals. 133-134. 669-670 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Takeuchi, T.Kawamoto, T.Mori他4名: "Uniaxial Strain Effect on the θ-Phase Organic Conductor with a Large Dihedral Angle, θ-(TMET-TTP)_4PF_6"J.Phys.Soc.Jpn.. 72(5). 1152-1154 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Mori: "Non-Stripe Charge Order in the θ-Phase Organic Conductors"J.Phys.Soc.Jpn.. 72(6). 1469-1475 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Sayaduzzaman, M.Katsuhara, H.Nii, T.Kawamoto, T.Mori: "Structural and magnetic properties of (C_2TEO-TTP)[Cr(ispq)_2(NCS)_4]CH_2Cl_2"CrytsEngComm. 5. 300-302 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Takimuya, M.Kodani, Y.Kataoka, Y.Aso, T.Otsubo, T.Kawamoto, T.Mori: "New Organic Superconductors with an Incommensurate Anion Lattice Consisting of Polyhalide Chains (MDT-TSF)Xy(MDT-TSF=Methylenedithiotetraselenafulvalene;X=Halogen:y=1.27-1.29"Chem.Mater.. 15. 3250-3255 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Ashizawa, T.Mori, 他5名: "Synthesis and Structure of Neutral Crystals and Charge-Transfer Salts of Selenium Containing TMET-TTP Derivatives"Bull.Chem.Soc.Jpn.. 76(11). 2091-2097 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Kawamoto, T.Mori他7名: "Electronic State Anisotropy and the Fermi Surface Topology of the Incommensurate Organic Superconducting Crystal (MDT-TSF)(AuI_2)_<0.436>"Eur.Phys.J.B. 36. 161-167 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Ashizawa, S.Kimura, T.Mori, Y.Misaki, K.Tanaka: "Tris-Fused Tetrathiafulvalenes (TTF) : Highly Conducting Single-Component Organics and Metallic Charge-Transfer Salt"Synth.Metals. 141(3). 307-313 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Shirahata, T.Mori, K.Takahashi: "Synthesis of a New Donor, BEDT-HBDST and Crystal Structures, Electrical and Magnetic Properties of (BEDT-HBDST)_2MX_4(M=Fe,Ga, X=Cl,Br), where BEDT-HBDS=2,5-bis(4,5-ethylenedithio-1,3-diselenol-2-ylidene)-2,3,4,5-tetrahydrothiophene"J.Solid State Chem.. 177. 332-342 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] L.Ouahab, T.Enoki: "Multiproperty Molecular Materials : TTF-Based Conducting and Magnetic Molecular Materials"Eur.J.Inorg.Chem.. 933-941 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Miyazaki, T.Enoki他5名: "Anomalous metallic state of one-dimensional molecular conductor (EDO-TTFBr2)3I3"Phys.Rev.B. 68(8). 085108 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] F.Setifi, L.Ouahab, S.Golhen, A.Miyazaki, T.Enoki, J.Yamad: "New Bulk Weak Ferromagnet in Ferrimagnetic Chains of Molecular Material based on DTDH-TTP and Paramagnetic Thiocyanato Complex Anion : (DTDH-TTP)[Cr(isoq)2(NCS)4]"C.R.Chimie. 6. 309-316 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Miyazaki, T.Enoki他8名: "π-d Interaction-based Molecular Magnets"Polyhedron. 22. 2227-2234 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Nishijo, A.Miyazaki, T.Enoki: "Weak-ferromagnetism in molecular magnets based on transition metal complexes of crown thioether"Polyhedron. 22. 1755-1758 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Enomoto, J.-I.Yamaura, A.Miyazaki, T.Enoki: "Electronic and Magnetic Properties of Organic Conductors (DMET)2MBr4(M=Fe,Ga)"Bull.Chem.Soc.Jpn.. 76. 945-959 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Enoki他7名: "Novel Magnietism of EDO-TTFX2 Salts(X=Br,I)"Synth.Metals. 137. 1173-1174 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Miyazaki, T.Enoki他6名: "Weak ferromagnetism of (BDH-TTP)[M(isoq)2(NCS)4](M=Cr,Fe;isoq=isoquinoline)"Synth.Metals. 137. 1195-1196 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] F.Setifi, L.Ouahab, A.Miyazaki, T.Enoki, J.Yamada: "New Organic-Inorganic Hybrid Materials based on DTDH-TTP and Paramagnetic Isothiocyanato Complex Anion : (DTDH-TTP)2[Cr(phen)(NCS)4].CH2Cl2"Synth.Metals. 137. 1177-1178 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Okabe, A.Miyazaki, T.Enoki: "Transport property of ケ-d interaction system (EDTDM)2FeBr4 under pressure and magnetic field"Synth.Metals. 135-136. 693-694 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Enomoto, A.Miyazaki, T.Enoki: "Novel important role of ケ-d interaction in (DMET)2FeCl4"Synth.Metals. 135-136. 561-56 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Nishijo, A.Miyazaki, T.Enoki, 他5名: "Ferromagnetic Interaction and Metallic Conductivity of Radical Ion Salts (DIEDO)2M(mnt)2(M=Ni,Pt)"Synth.Metals. 133-134. 539-541 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Miyazaki, T.Enoki: "Crystal Structure and Physical Properties of (EDS-TTF)2FeBr4"Synth.Metals. 133-134. 543-545 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Enoki, A.Miyazaki他7名: "Unconventional TTF-Based Molecular Magnets"Synth.Metals. 133-134. 501-503 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2018-03-28  

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