• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

分子性導体の電荷配列の極低温及び強磁場下X線による観測

Research Project

Project/Area Number 15073217
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOkayama University

Principal Investigator

野上 由夫  Okayama University, 大学院・自然科学研究科, 教授 (10202251)

Co-Investigator(Kenkyū-buntansha) 大嶋 孝吉  岡山大学, 大学院・自然科学研究科, 教授 (10114414)
神戸 高志  岡山大学, 大学院・自然科学研究科, 準教授 (00277386)
池田 直  岡山大学, 大学院・自然科学研究科, 教授 (00222894)
Project Period (FY) 2003 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥66,100,000 (Direct Cost: ¥66,100,000)
Fiscal Year 2007: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2006: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2005: ¥12,300,000 (Direct Cost: ¥12,300,000)
Fiscal Year 2004: ¥17,000,000 (Direct Cost: ¥17,000,000)
Fiscal Year 2003: ¥30,600,000 (Direct Cost: ¥30,600,000)
Keywords分子性導体 / 有機導体 / 有機超伝導体 / 低次元物質 / X線 / 構造解析 / 強磁場 / 電荷密度波
Research Abstract

世界で初めてとなる,超高感度10T磁場下回折装置と磁場中散漫散乱カメラを用いて,磁場下で量子ホール効果示す低次元物質η-Mo4011のX線散漫散乱写真を撮影した。6Kの極低温下では,二種類の電荷密度波転移の内,比較的振幅の大きなCDW1形成に伴う衛星反射だけではなく,特に微弱なCDW2形成に伴う衛星反射を観測する事に成功した。同一の写真に10ヶ以上の反射の撮影に成功しており,これは低温用X線カメラとしても世界最高性能であることを示している。更に8T以上の強磁場でCDW2の衛星反射位置が一次元方向b*成分に大きく変化することを観測した。この磁場領域では磁気輸送や磁場下光学特性にも異常があらわれることと考えあわせると,磁場による電子状態の変化が引き起こされていると考えられる。この装置は低次元分子性導体のような,様々な波数,つまり予測不能な波数の変調構造が現れ,それが電子状態に大きな影響を及ぼす系の構造科学研究にとって不可欠である。更に,EuO. 6SrO. 4MnO3の絶縁体-金属転移に関連し,同じく世界初となる高感度磁場中回転カメラ用いて磁場中冷却の金属相では,磁場なし冷却の絶縁相とくらべ,格子が明瞭に変化していることを観測した。つまり,磁場により格子の歪みが少ない金属相が安定となることを示した。これはこの系の物性が基本的に二重交換相互作用に支配されていることを示している。極低温で2種類の電荷秩序が競合するθ-(BEDT-TTF)2CsZn(SCN)4では,高電場下で巨大な非線形伝導やサイリスタ動作と関連し,3倍の電荷変調は変化しないが,2倍の電荷変調が減少すること,さらにその電荷変調の消長に格子定数の変化が同期していることを見いだした。

Report

(6 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (42 results)

All 2007 2006 2005 2004 2003 Other

All Journal Article (32 results) (of which Peer Reviewed: 21 results) Presentation (2 results) Book (2 results) Publications (6 results)

  • [Journal Article] Spin-Peierls Transition in Charge-Ordered Organic Conductor □-(BEDT-TTF)2RbZn(SCN)42007

    • Author(s)
      Masashi Watanabe, Yukio Noda, Yoshio Nogami, Hatsumi Mori
    • Journal Title

      Journal of the Physical Society of Japan 76

      Pages: 124602-5

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Antiferromagnetic ordering driven by the molecular orbital order of C60 in □'-tetra-kis-(dimethylamino)-ethylene-C602007

    • Author(s)
      T. Kambe, K. Kajiyoshi, M. Fujiwara, K. Oshima
    • Journal Title

      Physical Review Letters 98

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structural properties of a mixed valence compound Fe2BO42007

    • Author(s)
      S. Shimomura, S. Nakamura, N. Ikeda, E. Kaneko, K. Kato, K. Kohn
    • Journal Title

      J. Mag. Mag. Mat. 310

      Pages: 793-795

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Spin-Peierls Transition in Charge-Ordered Organic Conductor θ-(BEDT-TTF)2RBZn(SCN)42007

    • Author(s)
      Masashi Watanabe, Yukio Noda, Yoshio Nogami, Hatsumi Mori
    • Journal Title

      Journal of the Physical Society of Japan 76

      Pages: 124602-124605

    • NAID

      130005296632

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Antiferromagnetic ordering driven by the molecular order C60 in α' -tetra-kis-(dimethylamino)-ethylene-C602007

    • Author(s)
      T. Kambe, K. Kajiyoshi, M. Fujiwara and k. Oshima
    • Journal Title

      Phydical Review Letters 99

      Pages: 17720-17720

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural properties of a mixed valence compound Fe2B042007

    • Author(s)
      S. Shimomura, S, Nakamura, N. Ikeda, E. Kaneko, K. Kato and k. Kohn
    • Journal Title

      J. Mag. Mag. Mat. 310

      Pages: 793-795

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge Ordering in Organic Conductors2006

    • Author(s)
      T. Takahashi, Y. Nogami, K. Yakushi
    • Journal Title

      Journal of Physical Society of Japan 75

      Pages: 51008-51008

    • NAID

      110004702298

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Antiferromagnetic Ground State in Organic Quasi-1D Ferromagnet □-phase para-Nitrophenyl Nitronyl Nitroxide2006

    • Author(s)
      Y. Horibe, M. Shingu, K. Kurushima, H. Ishibashi, N. Ikeda, K. Kato, Y. Motome, N. Furukawa, S. Mori, T. Katsufuji
    • Journal Title

      Phys. Rev. Lett 96

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Antiferromagnetic Ground State in Organic Quasi-1D Ferromagnet □-phase para-Nitrophenyl Nitronyl Nitroxide2006

    • Author(s)
      Ko-Ichi Kajiyoshi, Takashi Kambe, Masafumi Tamura, Kokichi Oshima
    • Journal Title

      Journal of Physical Society of Japan 75

      Pages: 74702-74702

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Charge Ordering in Organic Conductors2006

    • Author(s)
      T.Takahashi, Y.Nogami, K.Yakushi
    • Journal Title

      Journal of Physical Society of Japan 75-5

      Pages: 51008-51008

    • NAID

      110004702298

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Spontaneous formation of vanadium "molecules" in a geometrically frustrated compound : AlV_2O_42006

    • Author(s)
      Y.Horibe, M.Shingu, K.Kurushima, H.Ishibashi, N.Ikeda, K.Kato, Y.Motome, N.Furukawa, S.Mori, T.Katsufuji
    • Journal Title

      Phys.Rev.Lett 96

      Pages: 86406-86406

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Antiferromagnetic Ground State in Organic Quasi-1D Ferromagnet β-phase para-Nitrophenyl Nitronyl Nitroxide2006

    • Author(s)
      Ko-Ichi Kajiyoshi, Takashi Kambe, Masafumi Tamura, Kokichi Oshima
    • Journal Title

      Journal of Physical Society of Japan 75

      Pages: 74702-74702

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 有機擬一次元物質の秩序無秩序転移と電荷不均一化2006

    • Author(s)
      伊藤崇芳, 野上由夫
    • Journal Title

      日本結晶学会誌 48

      Pages: 59-64

    • NAID

      10020535205

    • Related Report
      2006 Annual Research Report
  • [Journal Article] An organic thyristor2005

    • Author(s)
      F. Sawano, 他, Y. Nogami, 他
    • Journal Title

      Nature 437

      Pages: 522-524

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Crystal Structure of Charge Ordered Compound θ-(BEDT-TTF)2RbCo(SCN)4 at Low Temperatures2005

    • Author(s)
      M. Watanabe, Y. Noda, Y. Nogami, H. Mori
    • Journal Title

      J. Phys. Soc. Jpn 74

      Pages: 2011-2016

    • NAID

      210000105547

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structural differences in two polymorphs of tetra-kis-(dimethylamino)ethylene-C60: An x-ray diffraction study2005

    • Author(s)
      M. Fujiwara, T. Kambe, K. Oshima
    • Journal Title

      Phy. Rev. B71

      Pages: 174424-174424

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Ferroelectricity from iron valence ordering in the charge-irustrated system LuFe_2O_42005

    • Author(s)
      N. Ikeda, 他
    • Journal Title

      Nature 436

      Pages: 1136-1138

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] τ-(EDO-S, S-DMEDT-TTF)2(AuBr2)1+y, (y> 0.875) by the Quantum Oscillation of Magnetoresistance.2005

    • Author(s)
      H. Yoshino, 他, Y. Nogami, 他
    • Journal Title

      Journal of the Physical Society of Japan 74

      Pages: 415-424

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] An organic thyristor2005

    • Author(s)
      F.Sawano他, Y.Nogami他
    • Journal Title

      Nature 437

      Pages: 522-524

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Crystal Structure of Charge Ordered Compound θ-(BEDT-TTF)2RbCo(SCN)4 at Low Temperatures2005

    • Author(s)
      M.Watanabe, Y.Noda, Y.Nogami, H.Mori
    • Journal Title

      J.Phys.Soc. Jpn 47

      Pages: 2011-2016

    • NAID

      210000105547

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structural differences in two polymorphs of tetra-kis-(dimethylamino)ethylene-C60: An x-ray diffraction study2005

    • Author(s)
      M.Fujiwara, T.Kambe, K.Oshima
    • Journal Title

      Phy.Rev. B71

      Pages: 174424-174424

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe_2O_42005

    • Author(s)
      N.Ikeda他
    • Journal Title

      Nature 436

      Pages: 1136-1138

    • Related Report
      2005 Annual Research Report
  • [Journal Article] τ-(EDO-S, S-DMEDT-TTF)2(AuBr2)1+y, (y> 0.875) by the Quantum Oscillation of Magnetoresistance.2005

    • Author(s)
      H.Yoshino 他, Y.Nogami 他
    • Journal Title

      Journal of the Physical Society of Japan 74

      Pages: 415-424

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural phase transition in the two-dimensional kagome antiferromagnet m-MPYNN BF41/3 acetone2004

    • Author(s)
      T. Kambe, Y. Nogami, K. Oshima, W. Fujita, K. Awaga
    • Journal Title

      Journal of the Physical Society of Japan 73

      Pages: 796-799

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] ESR study on the distorted kagome antiferromagnet m-MPYNN BF41/3 acetone2004

    • Author(s)
      T. Kambe, K. Oshima, W. Fujita, K. Awaga
    • Journal Title

      Journal of Magnetism and Magnetic Materials 272-276

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Transfer integrals and the spatial pattern of charge ordering in θ-(BEDT-TTF)_2RbZn(SCN)_4 at 90 K2004

    • Author(s)
      M. Watanabe, Y. Noda, Y. Nogami, H. Mori
    • Journal Title

      Journal of the Physical Society of Japan 73

      Pages: 116-122

    • NAID

      110001954701

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structural phase transition in the two-dimensional kagome antiferromagnet m-MPYNN BF41/3 acetone2004

    • Author(s)
      T.Kambe, Y.Nogami, K.Oshima, W.Fujita, K.Awaga
    • Journal Title

      Journal of the Physical Society of Japan 73

      Pages: 796-799

    • Related Report
      2004 Annual Research Report
  • [Journal Article] ESR study on the distorted kagome antiferromagnet m-MPYNN BF41/3 acetone2004

    • Author(s)
      T.Kambe, K.Oshima, W.Fujita, K.Awaga
    • Journal Title

      Journal of Magnetism and Magnetic Materials 272-276

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Superlattice structural analysis of (TTM-TTP)I_3 at low temperatures2003

    • Author(s)
      Y. Nogami. T. Kambe, N. Fujimura, K. Oshima, et al.
    • Journal Title

      Synthetic Metals 135-136

      Pages: 637-638

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Shubnikov-de Haas oscillations and Fermi surface of τ-phase conductors2003

    • Author(s)
      T. Konoike, K. Iwashita, I. Nakano, H. Yoshino, T. Sasaki, Y. Nogami, et al.
    • Journal Title

      Physica E18

      Pages: 188-189

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Fermi surface and low temperature structure in (DMET-TSeF)_2Au(CN)_22003

    • Author(s)
      K. Kato, K. Oshima, T. Kambe, Y. Nogami, et al.
    • Journal Title

      Synthetic Metals 135-136

      Pages: 577-578

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] X-ray study of modulated structures of β'-Cu_xV_2O_5 (x=0.29, 0.39)2003

    • Author(s)
      N. Nagao, Y. Nogami, K. Oshima, H. Yamada, Y. Ueda
    • Journal Title

      Physica B329-333

      Pages: 713-714

    • NAID

      110002219304

    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Presentation] Generalized Method of Structural Analysis for Micro Imperfect Crystals using SR2007

    • Author(s)
      K. Yamamoto, Y. Nogami, 他
    • Organizer
      Asian Crystallographic Association 2007
    • Place of Presentation
      Taipei/Taiwan
    • Year and Date
      2007-05-11
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Generalized Method of Structural Analysis for Micro Imeperfect Crystals usingSR2007

    • Author(s)
      K. Yamamoto, Y. Nogami,他
    • Organizer
      Asian Crystallographic Association 2007
    • Place of Presentation
      Taipei/Taiwan
    • Year and Date
      2007-05-11
    • Related Report
      2007 Annual Research Report
  • [Book] Topology in Ordered Phase2006

    • Author(s)
      Y. Nogami, T. Tsuneta, K. Yamamoto D, N. Ikeda, T. Ito P, N. Irie M, S. Tanda
    • Total Pages
      374
    • Publisher
      World Scientific
    • Related Report
      2007 Final Research Report Summary
  • [Book] Topology in Ordered Phase2006

    • Author(s)
      Y.Nogami, T.Tsuneta, K.Yamamoto, D, N.Ikeda, T.Ito P, N.Irie M, S.Tanda
    • Total Pages
      374
    • Publisher
      World Scientific
    • Related Report
      2006 Annual Research Report
  • [Publications] M.Watanabe, Y.Noda, Y.Nogami, H.Mori: "Transfer integrals and the spatial pattern of charge ordering in θ-(BEDT-TTF)_2RbZn(SCN)_4 at 90K"Journal of the Physical Society of Japan. 73. 116-122 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nogami, T.Kambe, N.Fujimura, K.Oshima, et al.: "Superlattice structural analysis of (TTM-TTP)I_3 at low temperatures"Synthetic Metals. 135-136. 637-638 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Konoike, K.Iwashita, I.Nakano, H.Yoshino, T.Sasaki, Y.Nogami, et al.: "Shubnikov-de Haas oscillations and Fermi surface of τ-phase conductors"Physica. E18. 188-189 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Kato, K.Oshima, T.Kambe, Y.Nogami, et al.: "Fermi surface and low temperature structure in (DMET-TSeF)_2Au(CN)_2"Synthetic Metals. 135-136. 577-578 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Nagao, Y.Nogami, K.Oshima, H.Yamada, Y.Ueda: "X-ray study of modulated structures of β'-Cu_xV_2O_5(x=0.29,0.39)"Physica. B329-333. 713-714 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Kambe, Y.Nogami, K.Oshima, W.Fujita, K.Awaga: "Structural phase transition in two-dimensional kagome anitiferromagnet m-N-Methylpyridinium α-nitronyl nitroxide BF_4 1/3(Acetone)"Journal of the Physical Society of Japan. 73(掲載予定). (2004)

    • Related Report
      2003 Annual Research Report

URL: 

Published: 2003-04-01   Modified: 2018-03-28  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi