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Magnetic Field Induced Transition of liquid and Interfacial properties and Structure.

Research Project

Project/Area Number 15085202
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionSaitama University

Principal Investigator

NAKABAYASHI S.  Saitama University, Department of Chemistry, Professor, 理学部, 教授 (70180346)

Co-Investigator(Kenkyū-buntansha) SAKAGUCHI H.  Shizuoka University, Research Institute of Electronics, Associate professor, 電子工学研究所, 助教授 (30211931)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥24,000,000 (Direct Cost: ¥24,000,000)
Fiscal Year 2005: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2004: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2003: ¥8,000,000 (Direct Cost: ¥8,000,000)
KeywordsStrong magnetic field / surface plasmon resonance / refractive index / water / Poly-thiophene / molecular wire / electrochemistry / Scanning probe microscopy / 吸着 / 水素結合 / 部分電荷移動 / 化学物理 / 物性実験 / 界面 / 自己組織化単分子膜 / 表面プラズモン / 磁場効果 / 磁気力 / 光物性 / 磁気物性
Research Abstract

As for the magnetic field effect of water, we have been observing the change in the optical properties of water under the high magnetic field. The field increased the refractive indices of water and shifted the optical absorption wavelength in the near infrared region. Those effects are assumed by the magnetic stabilization of the hydrogen bonding. At the time, we also pointed out that the refractive index of the adsorbed water on the gold surface might be much sensitive than those in the bulk, which. suggests these surface effects.. The evanescent mirror of SPR (surface plasmon. resonance) is controlled. electrochemically in dilute sulfuric acid aqueous solution. Under the careful electrochemical conditioning combined with the detection of the refractive index by SPR, the gold surface can set the native clean surface, that covered with sulfate ions and the gold oxide. The changes in the refractive indices between OT and 10T were on gold oxide < on sulfate adsorption < on clean gold. When the gold surface was capped by dodecane-thiol or oxide, the refractive index change was identical to that of the bulk. In considering the amount of the trapped water is one or two molecular layers and the evanescent wave samples more than 1000 water in the bulk, the obtained surface effect is tremendous than that of the bulk. As for the magnetic field effect of the electrochemical processing of the molecular wire, we have succeeded the direct observation of the polymerization of thiophene on Au(111). The molecular alignment of origo-thiopphene was affected by the magnetic field. This result was harmonized the observation that the wire moves on the surface by the agitation of the thermal fluctuation under 0T.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (64 results)

All 2006 2005 2004 2003 Other

All Journal Article (55 results) Book (3 results) Publications (6 results)

  • [Journal Article] Synchronization Phenomena in Networks of Coupled Relaxation Electrochemical Oscillators2006

    • Author(s)
      A.Karantonis
    • Journal Title

      Journal of Bifurcation and Chaos (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 導電性ナノワイヤー「ナノオプティクス・ナノフォトニクス」2006

    • Author(s)
      坂口浩司
    • Journal Title

      フロンティア出版 (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 進化する有機半導体「ナノレベルの極微配線技術」2006

    • Author(s)
      坂口浩司
    • Journal Title

      エヌティーエス出版 (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Spatiotemporal Coding in an Electrochemical Oscillator Network2005

    • Author(s)
      Y.Miyakita
    • Journal Title

      Phys.Rev.E 71

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electrochemical Deposition of Stacked Layers of Cu2O/Cu/Cu2O and Rendering of Structural Colors2005

    • Author(s)
      M.Fujita
    • Journal Title

      Trans.Mat.Res.Soc.Jpn. 30

      Pages: 1041-1044

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoluminescence of Electrochemically-Deposited Granular Cu2O Films2005

    • Author(s)
      Y.Terui
    • Journal Title

      Trans.Mat.Res.Soc.Jpn. 30

      Pages: 1049-1052

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Manupilation of Spatio-temporal Patterns in Networks of Relaxation Electrochemical Oscillators2005

    • Author(s)
      A.Karantonis
    • Journal Title

      Electrochem.Acta. 30

      Pages: 5056-5060

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Direct visualization of the formation of single-molecule conjugated copolymers2005

    • Author(s)
      H.Sakaguchi
    • Journal Title

      Science 310

      Pages: 1002-1006

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electromechanical and conductance switching properties of single oligothiophene molecules2005

    • Author(s)
      B.Q.Xu
    • Journal Title

      Nano Letters 5

      Pages: 1491-1495

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electrochemical Deposition of Stacked Layers of Cu2O/Cu/Cu2O and Rendering of Structural Colors.2005

    • Author(s)
      M.Fujita
    • Journal Title

      Trans.Mat.Res.Soc.Jpn. 30(4)

      Pages: 1041-1044

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoluminescence of Electrochemically-Deposited Granular Cu20 Films2005

    • Author(s)
      Y.Terui
    • Journal Title

      Trans.Mat.Res.Soc.Jpn. 30(4)

      Pages: 1049-1052

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Manupilation of Spatio-temporal Patterns in Networks of Relaxation Electrochemical Oscillators.2005

    • Author(s)
      A.Karantonis
    • Journal Title

      Electrochem.Acta. 50

      Pages: 5056-5056

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electromechanical and conductance switching properties of single oligothiophene molecules2005

    • Author(s)
      B.Q.Xu
    • Journal Title

      Nano Letters 5(7)

      Pages: 1491-1495

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Spatiotemporal Coding in Electrochemical Network2005

    • Author(s)
      Y.Miyakita, S.Nakabayashi
    • Journal Title

      Phys.Rev.E 71

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Munipulation of Spatiotemporal Patterns2005

    • Author(s)
      A.Korantonis, S.Nakabayashi
    • Journal Title

      Electrochim Acta 50

      Pages: 5056-5060

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Electrochem Deposition of Stacked Layers of Cu_2O/Cu/Cu_2O2005

    • Author(s)
      M.Fujita, S.Nakabayashi
    • Journal Title

      Trans.Mat.Res.Soc.Jpn 30

      Pages: 1041-1044

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Photoluminescence of Eelctrochemically-Doped Cu_2O2005

    • Author(s)
      Y.Terui, S.Nakabayashi
    • Journal Title

      Trans.Mat.Res.Soc.Jpn 30

      Pages: 1049-1052

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 強磁場下での水の物性と電気化学2005

    • Author(s)
      曽越宣仁, 中村誠一郎
    • Journal Title

      Electrochemistry 73

      Pages: 445-449

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 水と強磁場との相互作用2005

    • Author(s)
      中林誠一郎, 曽越宣仁
    • Journal Title

      化学と教育 54

      Pages: 8-11

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Refractive Indices of Water and Aqueous Electrolyte Solutions under High Magnetic Fields2004

    • Author(s)
      H.Hosoda
    • Journal Title

      J.Phys.Chem.B. 108

      Pages: 1461-1464

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Giant negative photoconductivity in La0.7Ca0.3MnO3 thin films2004

    • Author(s)
      V.Moshnyaga
    • Journal Title

      J.Appl.Phys. 95

      Pages: 7360-7362

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] In-phase, anti-phase and fractured synchrony in ring networks of coupled relaxiation electrochemical oscillators2004

    • Author(s)
      A.Karantonis
    • Journal Title

      J.Phys.Chem.B. 108

      Pages: 5836-5840

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoluminescence studies of oligothiophene self-assembled monolayers at low excitation energy2004

    • Author(s)
      E.Mishina
    • Journal Title

      J.Chem.Phys. 120

      Pages: 9763-9768

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Magnetic Composite Particles of g-Fe2O3@SiO2 and the Control of the Structural Color of the Colloidal Crystal by Magnetic Fields2004

    • Author(s)
      K.Kitajima
    • Journal Title

      Chem.Lett.

      Pages: 1106-1107

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ferroelectriv nano-structure suputtered an alumina membranes2004

    • Author(s)
      E.D.Mishina
    • Journal Title

      Physica E 25

      Pages: 35-41

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Adlayers of Keggin type polytungstate anions on platinum : electro-chemically invisible being' and manifestations of molecular upd2004

    • Author(s)
      E.D.Mishina
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 17096-17105

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoluminescence Studies of Oligothiophene Self-assembled Monolayers at Low Excitation Energy2004

    • Author(s)
      E.Mishina
    • Journal Title

      Journal of Chemical Physics 120

      Pages: 9763-9768

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electrochemical Epitaxial Polymerization of Single Molecular Wires2004

    • Author(s)
      H.Sakaguchi
    • Journal Title

      Nature Materials 3

      Pages: 551-557

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Surface Topography of Growing L-Alanine Crystal in Magnetic Field2004

    • Author(s)
      K.Ogawa
    • Journal Title

      J.Chem.Eng.Japan 37

      Pages: 791-795

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Magnetic Gradient on the Growth Rate of L-alanine Crystal2004

    • Author(s)
      Bin Zhao
    • Journal Title

      IEEE Transactions on Applied Superconductivity 14

      Pages: 1596-1599

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Refractive Indices of Water and Aqueous Electrolyte Solutions under High Magnetic Fields2004

    • Author(s)
      H.Hosoda
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 1461-1464

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoluminescence studies of oligothiophene self-assembled monolayers at low excitation energy2004

    • Author(s)
      E.Mishina
    • Journal Title

      J.Chem.Phys 120

      Pages: 9763-9768

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Magnetic Composite Particles of g-Fe2O3$Si02 and the Comtrolof the Structural Color of the Colloidal Crystal by Magnetic Fields2004

    • Author(s)
      K.Kitajima
    • Journal Title

      Chem Lett.

      Pages: 1106-1107

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Adlayers of Keggin type polytungstate anions on platinum : electrochemically invisible being' and manifestations of molecular upd2004

    • Author(s)
      E.D.Mishina
    • Journal Title

      J.Phys.Chem. B108

      Pages: 17096-17105

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Surface Topography of Growing L-Alanine Crystal in Magnetic Field2004

    • Author(s)
      K.Ogawa
    • Journal Title

      J.Chem.Eng.Japan 37, 6

      Pages: 791-795

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Magnetic Gradient on the Growth Rate of L-alanine Crystal2004

    • Author(s)
      Bin Zhao
    • Journal Title

      IEEE Transactions on Applied Superconductivity 14,2

      Pages: 1596-1599

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Giant Negative Photoconductivity2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      J.Appl.Phys 95

      Pages: 7360-7362

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Refractive Indices of Water under High Mgg.2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 1461-1464

    • Related Report
      2004 Annual Research Report
  • [Journal Article] In-phase synchrony in ring networks2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 5836-5838

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Photoluminescence Study of Oligo thiophene2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      J.Chem.Phys 120

      Pages: 9763-9768

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Magnetic Composite Particle2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      Chem.Lett.

      Pages: 1106-1107

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Adlayers of Keggin type Poly-tungstene2004

    • Author(s)
      S.Nakabayashi
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 17096-17105

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Ferroelectrics templated in nanoporous silicon membranes2003

    • Author(s)
      E.D.Mishina
    • Journal Title

      Ferroelectrics 286

      Pages: 205-211

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Kinetic profile of adsorption and self-assembling of thiophene oligomers studied by optical second harmonic generation2003

    • Author(s)
      E.Mishina
    • Journal Title

      Surf.Sci. 544

      Pages: 269-277

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photomodulated second harmonic generation at silicon-silicon oxide in terface : from modeling to application2003

    • Author(s)
      E.D.Mishina
    • Journal Title

      Jpn.J.Appl.Phys.Part1 42

      Pages: 6731-6738

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Kinetics of adsorption and self-assembling of thiophene and dodecanethiol studied by optical second harmonic generation2003

    • Author(s)
      E.Mishina
    • Journal Title

      Chemistry Letters 32

      Pages: 652-653

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ferroelectric nanotubes2003

    • Author(s)
      F.D.Morrison
    • Journal Title

      Rev.Adv.Mat.Sci 4

      Pages: 1-9

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] From Excitatory to Inhibitory Connections in networks of Discrete Electrochemical Oscillators2003

    • Author(s)
      A.Karantonis
    • Journal Title

      J.Phys.Chem.B 107

      Pages: 14622-14630

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Current-sensing scanning near-field optical microscopy using a metal probe for nanometer-scale observation of electrochromic film2003

    • Author(s)
      F.Iwata
    • Journal Title

      J.Microscopy 210

      Pages: 241-246

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Magnetic Field on the Growth Rate of L-Alanine Crystal2003

    • Author(s)
      Bin Zhao
    • Journal Title

      J.Chem.Eng.Japan 36

      Pages: 959-962

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Formation kinetics and structure of self-assembled poly (3-alkyithiophene) films on gold surface2003

    • Author(s)
      T.Matsumura
    • Journal Title

      Journal of Materials Science : Materials in Electronics 14

      Pages: 353-356

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photomodulated second harmonic generation at silicon-silicon oxide interface : from modeling to application2003

    • Author(s)
      E.D.Mishina
    • Journal Title

      Jpn.J.Appl.Phys. 42Part1

      Pages: 6731-6731

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ferroelectric nanotubes2003

    • Author(s)
      F.D.Morrison
    • Journal Title

      Rev.Adv.Mat.Sci. 4

      Pages: 1-9

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Magnetic Field on the Growth Rate of L-Alanine Crystal2003

    • Author(s)
      Bin Zhao
    • Journal Title

      J.Chem.Eng.Japan 36, 8

      Pages: 959-962

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Formation kinetics and structure of self-assembled poly(3-alkylthiophene) films on gold surface2003

    • Author(s)
      T.Matsumura
    • Journal Title

      Journal of Materials Science : Materials in Electronics 14

      Pages: 353-356

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Magnetic field effect on optical properties of water and aqueous electrolyte solutions in Magneto-Science2006

    • Author(s)
      S.Nakabayashi
    • Publisher
      Kodansha-Springer(印刷中)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Refractive indices of water and aqueous electrolyte solutions under high magnetic fields in "Materials Processing in Magnetic Fields"2005

    • Author(s)
      S.Nakabayashi
    • Total Pages
      373
    • Publisher
      World Scientific
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Materials Processing in Magnetic Field2005

    • Author(s)
      S.Nakabayashi
    • Total Pages
      11
    • Publisher
      World Scientific
    • Related Report
      2005 Annual Research Report
  • [Publications] H.Hosoda, H.Mori, N.Sogoshi, A.Nagasawa, S.Nakabayashi: "Refractive Indices of Water and Aqueous Electrolyte Solutions under High Magnetic Fields"J.Phys.Chem.A. 108. 1461-1464 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Karantonis, M.Paitas, Y.Miyakita, S.Nakabayashi: "From excitatory to inhibitory connections in networks of discrete electrochemical oscillators"J.Phys.Chem.B. 107. 14622-14630 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] E.Mishina, T.Tamura, H.Sakaguchi, S.Nakabayashi: "Kinetics of Adsorption and Self-Assembling of Thiophene and Dodecanethiol Studied by Optical Second Harmonic Generation"Chemistry Letters. 32. 652-653 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] E.Mishina, Q.-K.Yu, T.Tamura, H.Sakaguchi, A.Karantonis, S.Nakabayashi: "Kinetic profile of adsorption and self-assembling of thiophene oligomers studied by optical second harmnic generation"Surface Science. 544. 269-277 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Q-K.Yu, Y.Miyakita, S.Nakabayashi, R.Baba: "Magnetic Field Effect on Electrochemical Oscillation during Iron Dissolution"Electrochemistry Communications. 5. 321-324 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Nawa, R.Baba, S.Nakbayashi, C.Dushkin: "Ordering Effect of high magnetic Field on Silver Nanoparticle Arrays for Electron Transfer Devices"Nano.Lett. 3. 293-297 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2018-03-28  

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