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Development of new process for rapid pig iron making in high oxygen potential at low temperature in order to reduce carbon dioxide gas emission

Research Project

Project/Area Number 15106011
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Metal making engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

NAGTA Kazuhiro  Tokyo Institute of Technology, 大学院・理工学研究科, Professor (70114882)

Project Period (FY) 2003 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥109,460,000 (Direct Cost: ¥84,200,000、Indirect Cost: ¥25,260,000)
Fiscal Year 2007: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2006: ¥23,790,000 (Direct Cost: ¥18,300,000、Indirect Cost: ¥5,490,000)
Fiscal Year 2005: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2004: ¥29,250,000 (Direct Cost: ¥22,500,000、Indirect Cost: ¥6,750,000)
Fiscal Year 2003: ¥36,140,000 (Direct Cost: ¥27,800,000、Indirect Cost: ¥8,340,000)
Keywordsiron ore / reduction / pig iron / microwave heating / low temperature ironmaking / carbon-composite pellet / reduction rate / マイクロ波 / マグネタイト / 石炭 / 粉体 / たたら製鉄
Research Abstract

The Tatara was the traditional ironmaking process in Japan and came from Korea in the late of 6 centuries. It had the box-type furnace with 1.2m height using clay and produced mainly pig iron from iron sand and charcoal. This process was the unique way in the world for producing pig iron In the middle of Meiji period, the Tatara was improved and the furnace with 3m height was constructed using firebricks. The furnace was called as "Kakuro". However, the Kakuro process was not so suitable for ironmaking from powder iron ore because of its flying. The reduction rates of iron oxides ground with graphite by a ball-mill were measured using a high temperature X-ray deffractometer. Increasing the milling time, the starting temperature of reduction decreased by 30 to 100K and the activation energies of reduction from hematite to magnetite and from magnetite to wustite decreased. That from wustite to iron increased. The surface of Fe1-xO was analyzed using STM analyzer. The surface broken in va … More cuum was random. When it was heated in vacuum for 15 min. at 800℃, the step with <110> direction grew and the surface construction of (1x1), (4x2) and the mash with about 3nm square appeared on the surface of (100). After heating in vacuum for 15 min at 1000℃, all surface was occupied with the mesh. The mesh meant that the clusters of Fe atomic vacancies in wustite appeared on the surface. The initial reduction of wustite on the surface radiated by H+ ions showed that the mesh structure disappeared and the small iron particles with 2-3nm diameter stayed on the surface. The dielectric constant and magnetic permeability of magnetite were measured to have the maximum near 2.45GHz of microwave. The carbon-composite pellet of about 10g was heated to 1370℃ for 5 min using 3kW microwave and produced pig iron. The increasing rate of temperature depended on the weight of pellets and not on the diameter of iron are powder. The concentration of impurities of pig iron was lower by one tenth than that of pig iron produced in blast furnace. The continuous process of pig iron making by microwave using the mixture of iron ore and coke powder was examined. Two problems were pointed out that insulators absorbed microwave and the absorption efficiency of microwave energy into resources was low. The new types of microwave furnace were proposed. One is the furnace that microwave beams are concentrated in the center of furnace and another is the rotary kiln type microwave furnace. Less

Report

(6 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (49 results)

All 2008 2007 2006 2005 2004 2003 Other

All Journal Article (38 results) (of which Peer Reviewed: 3 results) Presentation (2 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results) Publications (3 results)

  • [Journal Article] Selectivity of microwave energy consumption in the reduction of Fe_3O_4 with carbon black in mixed powder2007

    • Author(s)
      K. Ishizaki and K. Nagata
    • Journal Title

      Iron and Steel Inst. Japan 47

      Pages: 811-816

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Localized heating and reduction of magnetite ore with coal in composite pellets using microwave irradiation2007

    • Author(s)
      K. Ishizaki and K. Nagata
    • Journal Title

      Iron and Steel Inst. Japan 47

      Pages: 817-822

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] In-situ observation of Fe_<0.94>O reduction at high temperature with the use of optical microscopy2007

    • Author(s)
      T. Yamashita, T. Nakada and K. Nagata
    • Journal Title

      Metallurgical and Materials Transactions B 38B

      Pages: 185-191

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Selectivity of microwave energy consumption in the reduction of Fe_<3>O_<4> with carbon black in mixed powder2007

    • Author(s)
      K., Ishizaki, K., Nagata
    • Journal Title

      Iron and Steel Inst. Japan 47

      Pages: 811-816

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Localized heating and reduction of magnetite are with coal in composite pellets using microwave irradiation2007

    • Author(s)
      K., Ishizaki, K., Nagata
    • Journal Title

      Iron and Steel Inst. Japan 47

      Pages: 817-822

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] In-situ observation of Fe_<0.94>O reduction at high temperature with the use of optical microscopy2007

    • Author(s)
      T., Yamashita, T., Nakada, K., Nagata
    • Journal Title

      Metallurgical and Materials Transactions B 38B

      Pages: 185-191

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] たたら製鉄の技術論(19) たたら製鉄の物質収支と熱収支2007

    • Author(s)
      永田和宏
    • Journal Title

      金属 77・1

      Pages: 83-83

    • NAID

      40015228818

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(20) 村下の枝2007

    • Author(s)
      永田和宏
    • Journal Title

      金属 77・2

      Pages: 204-204

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(21) たたら製鉄復元への道2007

    • Author(s)
      永田和宏
    • Journal Title

      金属 77・3

      Pages: 328-328

    • NAID

      40015351522

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Effect of NaF Addition to Mold Flux on Cuspidine Primary Field2006

    • Author(s)
      Hideko Nakada, Hiroyuki Fukuyama, Kazuhiro Nagata
    • Journal Title

      ISIJ International 46・11

      Pages: 1660-1660

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Effect of Na20 on Crystallization of Mould Fluxes for Continuous Casting of Steel2006

    • Author(s)
      Miyuki Hayashi, Takashi Watanabe, Hideko Nakada, Kazuhiro Nagata
    • Journal Title

      ISIJ International 46・12

      Pages: 1805-1805

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Production of Pig Iron from Magnetite Ore-Coal Composite Pellets by Microwave Heating2006

    • Author(s)
      Kotaro Ishizaki, Kazuhiro Nagata, Testuro Hayashi
    • Journal Title

      ISIJ International 46・10

      Pages: 1403-1403

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Crystallization of Ca0-SiO2-TiO2 Slag as a Candidate for Fluorine Free Mold Flux2006

    • Author(s)
      Hideko Nakada, Kazuhiro Nagata
    • Journal Title

      ISIJ International 46・3

      Pages: 441-441

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Reduction Kinetics of Hematite Powder Mechanically Milled with Graphite2006

    • Author(s)
      Ichiro Seki, Kazuhiro Nagata
    • Journal Title

      ISIJ International 46・1

      Pages: 1-1

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 日本刀の原料-玉鋼-を作るたたら -高炉製鉄を超える低温高速高純度鉄製造法-2006

    • Author(s)
      永田和宏
    • Journal Title

      未来材料 6・4

      Pages: 2-2

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 現代に生きるたたら製鉄2006

    • Author(s)
      永田和宏
    • Journal Title

      Harmony 36

      Pages: 13-13

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 「たたら」とマイクロ波製鉄2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・8

      Pages: 870-870

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(10) 〓と鉄の生成機構(1)2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・4

      Pages: 460-460

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(11) 〓と銃の生成機構(2)2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・5

      Pages: 589-589

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(12) たたら製鉄の発展形態としての鉄精錬炉「角炉」の構造2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・6

      Pages: 711-711

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(13) 「角炉」の操業2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・7

      Pages: 835-835

    • NAID

      40007365412

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(14) 「角炉」の銑滓あるいは砂鉄を用いた製銑反応機構2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・8

      Pages: 953-953

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(15) 製鉄炉の炉高と炉内状態(その1)2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・9

      Pages: 1061-1061

    • NAID

      40007444717

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(16) 製鉄炉の炉高と炉内状態(その2)2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・10

      Pages: 1204-1204

    • NAID

      40015122124

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(17) 大鍛冶による脱炭機構2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・11

      Pages: 1225-1225

    • NAID

      40015147452

    • Related Report
      2006 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(18) 風と炎2006

    • Author(s)
      永田和宏
    • Journal Title

      金属 76・12

      Pages: 1343-1343

    • NAID

      40015186665

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Reduction Kinetics of Hematite Powder Mechanically Milled with Graphite2006

    • Author(s)
      I.Seki, K.Nagata
    • Journal Title

      Iron and Steel Inst.Japan Intern. 46

      Pages: 1-7

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Supersaturation of Carbon in Austenite during Carburization by CO Gas2005

    • Author(s)
      I.Seki, K.Nagata
    • Journal Title

      Iron and Steel Inst.Japan Intern. 45

      Pages: 1536-1542

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Lattice Constant of Iron and Austenite Including Its Supersaturation Phase of Carbon2005

    • Author(s)
      I.Seki, K.Nagata
    • Journal Title

      Iron and Steel Inst.Japan Intern. 45

      Pages: 1789-1794

    • Related Report
      2005 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(1)たたら製鉄との出会い2005

    • Author(s)
      永田 和宏
    • Journal Title

      金属 75

      Pages: 711-719

    • Related Report
      2005 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(2)たたら研究への道2005

    • Author(s)
      永田 和宏
    • Journal Title

      金属 75

      Pages: 804-813

    • NAID

      40006854949

    • Related Report
      2005 Annual Research Report
  • [Journal Article] たたら製鉄の技術論(3)日刀保たたら見聞録(その1)2005

    • Author(s)
      永田 和宏
    • Journal Title

      金属 75

      Pages: 940-944

    • Related Report
      2005 Annual Research Report
  • [Journal Article] たたら製鉄の発展形態としての製鉄製錬炉「角炉」の構造2004

    • Author(s)
      永田 和宏
    • Journal Title

      鉄と鋼 90(4)

      Pages: 220-227

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 「角炉」の鉄滓あるいは砂鉄を用いた製銑反応機構2004

    • Author(s)
      永田 和宏
    • Journal Title

      鉄と鋼 90(4)

      Pages: 228-235

    • NAID

      110001457740

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Low Temperature Production of Pig Iron from Carbon-composite Pettets Heated by Microwave.2004

    • Author(s)
      K.Ishizaki, K.Nagata
    • Journal Title

      Proc.Intern.Meeting on Ironmaking, Espiroto Santo, Brazil 1

      Pages: 617-625

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 非平衡状態を利用した革新的製鉄法と「たたら」2004

    • Author(s)
      永田 和宏
    • Journal Title

      ふぇらむ 9(8)

      Pages: 549-553

    • NAID

      10013327699

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Coordination Environment in the CaO-SiO2-CaF2 Gkasses Bearing Na20 : A Solid-state 19F MAS MNR Study2004

    • Author(s)
      M.Hayashi, T.Watanabe, K.Nagata, S.Hayashi
    • Journal Title

      ISIJ Intern. 44(9)

      Pages: 1527-1533

    • Related Report
      2004 Annual Research Report
  • [Journal Article] History of ModernTatara2003

    • Author(s)
      Kazuhiro, Nagata Co-authors, ed. Minoru, Sasabe Mitsuru, Tate, Keiichi, Terashima
    • Journal Title

      Maruzen Planet Co.

      Pages: 201-234

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] マイクロ波加熱連続製銑法の開発(I)2008

    • Author(s)
      原 恭輔、林幸、永田和宏、佐藤元泰
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      武蔵工業大学
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Continuous Process of Pig Iron Making by Microwave Heating (I)

    • Author(s)
      Kyousuke, Hara, Muyuki, Hayashi, Kazuhiro, Nagata, Motoyasu, Soato
    • Organizer
      155th ISIJ Meeting
    • Place of Presentation
      Tokyo
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 近世たたら製鉄の歴史(雀部、館、寺島編)2004

    • Author(s)
      永田 和宏(分担)
    • Total Pages
      273
    • Publisher
      丸善
    • Related Report
      2004 Annual Research Report
  • [Book] 近世たたら製鉄の歴史2003

    • Author(s)
      永田共著, 雀部実・館充・寺島慶一編者
    • Publisher
      丸善プラネット
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.cms.titech.ac.jp/seminar/function/func_02.html

    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許権2007

    • Inventor(s)
      永田和宏、佐藤元泰
    • Industrial Property Rights Holder
      永田和宏
    • Industrial Property Number
      2007-201388
    • Filing Date
      2007-08-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許権2006

    • Inventor(s)
      永田和宏、佐藤元泰、林哲郎
    • Industrial Property Rights Holder
      永田和宏、自然科学研究機構、岐阜県
    • Industrial Property Number
      2006-025055
    • Filing Date
      2006-02-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 溶鉱炉及びそれを用いた銑鉄の製造方法2006

    • Inventor(s)
      永田 和宏
    • Industrial Property Rights Holder
      永田 和宏
    • Industrial Property Number
      2006-025055
    • Filing Date
      2006-02-24
    • Related Report
      2005 Annual Research Report
  • [Publications] 関一郎, 永田和宏: "酸化鉄還元直後の還元鉄格子面間隔の直接観察"材料とプロセス. 16. 934 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Nagata: "Rapid Ironmaking at low Temperature and High Oxygen Potential"Proc.3^<rd> Intern.Conf.on Science and Technology of Ironinaking. Dusseldorf. 556-562 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] I.Seki, K.Nagata: "Insite-observation of reduction of iron-oxide mixed with graphite using high temperature X-ray diffractometry"Proc.3^<rd> Intern.Conf.on Science and Technology of Ironinaking. Dusseldorf. 68-73 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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