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Creation of Novel Functional Supramolecular Organic Chemistry

Research Project

Project/Area Number 15205007
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

IYODA Masahiko  Tokyo Metropolitan University, Graduate School of urban Environmental Sciences, Professor (50115995)

Co-Investigator(Kenkyū-buntansha) NISHINAGA Tohru  Tokyo Metropolitan Univ, 理工学研究科, Associate Professor (30281108)
KUWATANI Yoshiyuki  Tokyo Metropolitan Univ, 理工学研究科, Associate Professor (00234625)
三宅 由寛  東京都立大学, 理学研究科, 助手 (00347270)
吉田 正人  島根大学, 医学部, 助教授 (50137030)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥46,800,000 (Direct Cost: ¥36,000,000、Indirect Cost: ¥10,800,000)
Fiscal Year 2005: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2004: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Fiscal Year 2003: ¥25,350,000 (Direct Cost: ¥19,500,000、Indirect Cost: ¥5,850,000)
KeywordsNanomolecules / Self-organization / Inclusion complex / Helical structure / Cyclic Polyheteroarene / Radial donor molecule / Swiching properties / Molecular wire / 超分子化学 / 複合機能 / 分子スイッチ / ホスト-ゲスト化学 / 電気伝導性 / 自己会合 / 大環状ポリアレーン / テトラチアフルバレン / サンドイッチ錯体 / 分子電線
Research Abstract

Self-assembly of organic π-conjugated systems into complex, organized supramolecular structures via specific intermolecular interactions is a promising way to realize functional molecular materials. Many intermolecular interactions such as hydrogen bonding, metal coordination, CT interaction, and π-π stacking have been utilized recently to construct desired supramolecular architectures such as fibers, ribbons, tapes, nanotubes, and nanoparticles. Recently, we have developed a new concept of self-assembly by the use of cooperative S…S and π-π stacking interactions. Although S…S interaction is a weak attractive force in solution, it plays an important role in packing of molecules in crystals. Thus, organic conductors and superconductors based on tetrathiafulvalenes (TTF) are constructed using cooperative S…S and π-π stacking interactions
Crystal engineering of organic conductors suggests that van der Waals and dipole-dipole interactions between neutral sulfur atoms give rise to an attract … More ive force in crystals. The corresponding interactions in the oxidation state are also energetically favorable. Therefore, two TTF molecules tend to align face-to-face to produce a stacking structure in crystals. Although the closely located dimeric TTF/TTF is weakly stable in the neutral, state, the dimeric TTF/TTF^+ is strongly stabilized in the cationic state to produce a mixed valence form and hence the appearance of conductivity in the solid state. Moreover, two cation-radicals TTF^+/TTF^+ also interact attractively (π-dimer formation) in solution leading to the formation of a Mott-insulating semi-conductor in the solid state.
It is known that π-conjugated molecules with either electron-withdrawing or large π-circles and disks self-aggregate in solution, while the surface organization of π-conjugated molecules is frequently used by material scientists employing organic materials as molecular switches and devices. To design a π-donor molecules with these applications, detailed knowledge of the structures of self-aggregates in solution or in mesophase is required, because pre-aggregation of conjugated π-systems may control the arrangement of the molecules on the solid surface. With this in mind, construction of a redox-active nanoscale architecture in solution and in the solid state has been achieved, and structures of neutral and cationic aggregates based on TTF oligomers and macrocyclic oligothiophenes have been investigated as a sulfur-rich π-system. Finally, we suceeded to construct conductive helical donors, conductive nanofibers having hexagonal arrangement, and thermochromic TTF systems. Less

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (59 results)

All 2006 2005 2004 2003 Other

All Journal Article (46 results) (of which Peer Reviewed: 17 results) Presentation (6 results) Book (1 results) Publications (6 results)

  • [Journal Article] Synthesis of Tris(tetrathiafulvaleno)dodecadehydro[18]annulenes and Their Self-Assembly2006

    • Author(s)
      H.Enozawa, M.Hasegawa, D.Takamatsu, K.Fukui, M.Iyoda
    • Journal Title

      Organic Letters 8(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Novel electron-transfer oxidation of Lipshutz cuprates with 1, 4-benzoqumones : An efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems2005

    • Author(s)
      Y. Miyake, M. Wu, M. J. Rahman, M. Iyoda
    • Journal Title

      Chem. Commun

      Pages: 411-413

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Bis(ethylenedioxy)-1, 4, 5, 8-tetraselenanaphthalene : The First Example of Tetxaselenanaphthalene2005

    • Author(s)
      R. Watanabe, Y. Miyake, Y. Kuwatani, M. Iyoda
    • Journal Title

      Chem. Lett 34

      Pages: 68-69

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones2005

    • Author(s)
      Y. Miyake, M. Wu, M. J. Rahman, M. Iyoda
    • Journal Title

      Chem. Commun.

      Pages: 411-412

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Bis(ethylenedioxy)-1,4,5,8-tetraselenanaphthalene : The First Example of Tetraselenanaphthalene.2005

    • Author(s)
      R. Watanabe, Y. Miyake, Y. Kuwatani, M. Iyoda
    • Journal Title

      Chem. Lett. 34

      Pages: 68-69

    • NAID

      10014218055

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones : An efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems2005

    • Author(s)
      Y.Miyake, M.Wu, M.J.Rahman, M.Iyoda
    • Journal Title

      Chemical Communications

      Pages: 411-413

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Bis(ethylenedioxy)-1,4,5,8-tetraselenanaphthalene : The First Example of Tetraselenanaphthalene2005

    • Author(s)
      R.Watanabe, Y.Miyake, Y.Kuwatani, M.Iyoda
    • Journal Title

      Chemistry Letters 34

      Pages: 68-69

    • NAID

      10014218055

    • Related Report
      2005 Annual Research Report
  • [Journal Article] d-Electron-Induced Negative Magnetoresistance of π-d Interaction System Including Brominated-TTF Donor2005

    • Author(s)
      J.Nishijo, A.Miyazaki, T.Enoki, R.Watanabe, Y.Kuwatani, M.Iyoda
    • Journal Title

      Inorganic Chemistry 44

      Pages: 2493-2506

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis of Nonaphenylenes and Dodecaphenylenes Using Electron-Transfer Oxidation of Lipshutz Cuprate Intermediates2005

    • Author(s)
      M.Iyoda, M.Wu, Y.Kuwatani, Y.Miyake
    • Journal Title

      Chemistry Letters 34

      Pages: 1474-1475

    • NAID

      10016843796

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Nickel-catalyzed Dimerization of [5] Cumulenes (Hexapentaenes)2005

    • Author(s)
      Y.Kuwatani, G.Yamamoto, M.Oda, M.Iyoda
    • Journal Title

      Bull.Chem.Soc.Jpn 78

      Pages: 2188-2208

    • NAID

      10017074742

    • Related Report
      2005 Annual Research Report
  • [Journal Article] All-Z-Uexabenzo[24]annulene with a triangular benzene cluster substructure2004

    • Author(s)
      Y. Kuwatani, J. Igarashi, M. Iyoda
    • Journal Title

      Tetrahedron Lett 45

      Pages: 359-362

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Anomalous Ring Cleavage of 1, 3-Dithiole- and 1, 3-Diselenole-2-thiones under the Cross-coupling Conditions Using Triethyl Phosphite2004

    • Author(s)
      M. Iyoda, R. Watanabe, Y, Miyake
    • Journal Title

      Chem. Lett

      Pages: 570-571

    • NAID

      10012943712

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Aggregation of Star-Shaped Tris (tetrathiafulvalenylethynyl) benzene in Solution and in the Solid State.2004

    • Author(s)
      M. Hasegawa, J. Takano, H. Enozawa, Y. Kuwatani, M. Iyoda
    • Journal Title

      Tetrahedron Lett 45

      Pages: 4109-4112

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Interaction and aggregation of TTF oligomers towards supramolecular chemistry2004

    • Author(s)
      M. Iyoda, M. Hasegawa, K. Hara, J. Takano, E. Ogura, Y. Kuwatani
    • Journal Title

      J. Phys. IV France 114

      Pages: 455-458

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Association of poly(tetrathiafulvalenyl)-benzenes in neutral and cationic states2004

    • Author(s)
      M. Hasegawa, Y. Kuwatani, M. Iyoda
    • Journal Title

      J. Phys. IV France 114

      Pages: 505-507

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Copper-Mediated Simple and Efficient Synthesis of Tribenzohexadehydro[12]annulene and Its Derivatives2004

    • Author(s)
      M. Iyoda, S. Sirinintasak, Y. Nishiyama A. Vorasingha, F. Sultana, K. Nakao, Y. Kuwatani, H. Matsuyama, M. Yoshida, Y. Miyake
    • Journal Title

      Synthesis

      Pages: 1527-1531

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Bis(tetrathiafulvaleno)octadehydro[20]- annulene with Multi-Functionality2004

    • Author(s)
      M. Iyoda, H. Enozawa, Y. Miyake
    • Journal Title

      Chem. Lett

      Pages: 1098-1099

    • NAID

      10013527207

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Mono-and bis-(tetrathiafulvaleno)hexadehydro[12]annulenes2004

    • Author(s)
      K. Hara, M. Hasegawa, Y. Kuwatani, H. Enozawa, M. Iyoda
    • Journal Title

      Chem. Commun

      Pages: 2042-2043

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Bi-TTF, Bis-TTF, and Related Oligomers2004

    • Author(s)
      M. Iyoda, M. Hasegawa, Y. Miyake
    • Journal Title

      Chem. Rev 104

      Pages: 5085-5114

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Novel π-Expanded Radialene Macrocycles with Inner Cavity2004

    • Author(s)
      M. Iyoda, Y. Kuwatani, S. Yamagata, N. Nakamura, M. Todaka, G. Yamamoto
    • Journal Title

      Org. Lett 6

      Pages: 4667-4670

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] All-Z-Hexabenzo[24]annulene with a triangular benzene cluster substructure.2004

    • Author(s)
      Y. Kuwatani, J. Igarashi, M. Iyoda
    • Journal Title

      Tetrahedron Lett 45

      Pages: 359-362

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Anomalous Ring Cleavage of 1,3-Dithioleand 1,3-Diselenole-2-thiones under the Cross-coupling Conditions Using Triethyl Phosphite.2004

    • Author(s)
      M. Iyoda, R. Watanabe, Y. Miyake
    • Journal Title

      Chem. Lett.

      Pages: 570-571

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Aggregation of Star-Shaped Tris(tetrathiafulvalenylethynyl)benzene in Solution and in the Solid State.2004

    • Author(s)
      M. Hasegawa, J. Takano, H. Enozawa, Y. Kuwatani, M. Iyoda
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 4109-4112

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Interaction and aggregation of TTF oligomers towards supramolecular chemistry.2004

    • Author(s)
      M. Iyoda, M. Hasegawa, K. Hara, J. Takano, E. Ogura, Y. Kuwatani
    • Journal Title

      J. Phys. IV France 114

      Pages: 455-458

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Association of poly(tetrathiafulvalenyl)benzenes in neutral and cationic states.2004

    • Author(s)
      M. Hasegawa, Y. Kuwatani, M. Iyoda
    • Journal Title

      J. Phys. IV France 114

      Pages: 505-507

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Copper-Mediated Simple and Efficient Synthesis of Tribenzohexadehydro[12]annulene and Its Derivatives.2004

    • Author(s)
      M. Iyoda, S. Sirinintasak, Y. Nishiyama, A. Vorasingha, F. Sultana, K. Nakao, Y. Kuwatani, H. Matsuyama, M. Yoshida, Y. Miyake
    • Journal Title

      Synthesis

      Pages: 1527-1531

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Bis(tetrathiafulvaleno)octadehydro[20]annulene with Multi-Functionality2004

    • Author(s)
      M. Iyoda, H. Enozawa, Y. Miyake
    • Journal Title

      Chem. Lett.

      Pages: 1098-1099

    • NAID

      10013527207

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Mono- and bis-(tetrathiafulvaleno)hexadehydro[12]annulenes.2004

    • Author(s)
      K. Hara, M. Hasegawa, Y. Kuwatani, H. Enozawa, M. Iyoda
    • Journal Title

      Chem. Commun.

      Pages: 2042-2043

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Bi-TTF, Bis-TTF, and Related Oligomers2004

    • Author(s)
      M. Iyoda, M. Hasegawa, Y. Miyake
    • Journal Title

      Chem. Rev. 104

      Pages: 5085-5114

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel π-Expanded Radialene Macrocycles with Inner Cavity.2004

    • Author(s)
      M. Iyoda, Y. Kuwatani, S. Yamagata, N. Nakamura, M. Todaka, G. Yamamoto
    • Journal Title

      Org. Lett. 6

      Pages: 4667-4670

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel π-Extended Radialene Macrocycles with Inner Cavity2004

    • Author(s)
      伊与田正彦他
    • Journal Title

      Organic Letters誌 vol.6

      Pages: 4667-4670

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Bi-TTF, Bis-TTF, and Related Oligomers2004

    • Author(s)
      伊与田正彦他
    • Journal Title

      Chemical Review誌 vol.104

      Pages: 5085-5114

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Mono- and Bis(tetrathiafulvaleno)hexadehydro-[12]annulenes2004

    • Author(s)
      原憲司他
    • Journal Title

      Chemical Communication誌

      Pages: 2042-2043

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Bis(tetrathiafulvaleno)octadehydro[20]annulene with Multi-Functionality2004

    • Author(s)
      伊与田正彦他
    • Journal Title

      Chemistry Letters誌

      Pages: 1098-1099

    • NAID

      10013527207

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Copper-Mediated Simple and Efficient Synthesis of Tribenzohexadehydro[12]annulene and Its Derivatives2004

    • Author(s)
      伊与田正彦他
    • Journal Title

      Synthesis誌

      Pages: 1527-1531

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Aggregation of Strar-Shaped Tris(tetrathiafulvelenylethynyl)benzene in Solution and in the Solid State2004

    • Author(s)
      長谷川真士他
    • Journal Title

      Tetrahedron Letters誌 vol.45

      Pages: 4109-4112

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A twin-rotor system created on a [4]radialene frame2003

    • Author(s)
      Y. Kuwatani, G. Yamamoto, M. Iyoda
    • Journal Title

      Org. Lett. 5

      Pages: 3371-3374

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Unconventional TTF-Based Molecular Magnets2003

    • Author(s)
      T. Enoki, H. Yamazaki, K. Okabe, K. Enomoto, T. Kato, A. Miyazaki, E. Ogura, Y. Kuwatani, M. Iyoda
    • Journal Title

      Synth. Met 133-134

      Pages: 501-503

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Interaction and Metallic Conductivity of Radical Ion Salts (DIEDO)_2 M(mnt)_2 (M =Ni, Pt)2003

    • Author(s)
      J. Nishijo, E. Ogura, J. Yamaura, A. Miyazaki, T. Enoki, T. Takano, Y. Kuwatani, M. Iyoda
    • Journal Title

      Synth. Met. 133-134

      Pages: 539-541

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Novel Magnetism of ED0-TTFX_2 Salts (X = Br, I)2003

    • Author(s)
      T. Enoki, H. Yamazaki, J. Nishijo, A. Miyazaki, K. Ugawa, E. Ogura, Y. Kuwatani, M. Iyoda, Y. V. Sushko
    • Journal Title

      Synth. Met. 137

      Pages: 1173-1174

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Synthesis and inclusion properties of a novel macrocyclic hexaone monohydrate with a hemiacetal structure2003

    • Author(s)
      M. Ohkoshi, T. Horino, M. Yoshida, M. Iyoda
    • Journal Title

      Chem. Commun

      Pages: 2586-2587

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] A twin-rotor system created on a [4]radialene frame.2003

    • Author(s)
      Y. Kuwatani, G. Yamamoto, M. Iyoda
    • Journal Title

      Org. Lett 5

      Pages: 3371-3374

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Unconventional TTF-Based Molecular Magnets.2003

    • Author(s)
      T. Enoki, H. Yamazaki, K. Okabe, K. Enomoto, T. Kato, A. Miyazaki, E. Ogura, Y. Kuwatani, M. Iyoda
    • Journal Title

      Synth. Met. 133-134

      Pages: 501-503

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ferromagnetic Interaction and Metallic Conductivity of Radical Ion Salts (DIEDO)_2M(mnt)_2 (M = Ni, Pt).2003

    • Author(s)
      J. Nishijo, E. Ogura, J. Yamaura, A. Miyazaki, T. Enoki, T. Takano, Y. Kuwatani, M. Iyoda
    • Journal Title

      Synth. Met. 133-134

      Pages: 539-541

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel Magnetism of EDO-TTFX_2 Salts (X = Br, I)2003

    • Author(s)
      T. Enoki, H. Yamazaki, J. Nishijo, A. Miyazaki, K. Ugawa, E. Ogura, Y. Kuwatani, M. Iyoda, Y. V. Sushko
    • Journal Title

      Synth. Met. 137

      Pages: 1173-1174

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis and inclusion properties of a novel macrocyclic hexaone monohydrate with a hemiacetal structure.2003

    • Author(s)
      M. Ohkoshi, T. Horino, M. Yoshida, M. Iyoda
    • Journal Title

      Chem. Commun.

      Pages: 2586-2587

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Synthesis and Aggregation Properties of Tris(tetrathiafulvaleno)dodecadehydro[18]annulenes and Related Compounds.2005

    • Author(s)
      H. Enozawa, M. Kakuta, Y. Miyake, M. Iyoda
    • Organizer
      International Symposium on Molecular Conductors
    • Place of Presentation
      Kanagawa, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Constraction of Supramolecular Structures Using Poly(tetrathiafulvalenylethynyl)benzenes.2004

    • Author(s)
      M. Hasegawa, M. Iyoda
    • Organizer
      6th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      NY, USA
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Supramolecular Structures Constructed by Association of TTF Oligomers.2004

    • Author(s)
      M. Iyoda, M. Hasegawa, H. Enozawa, K. Hara, Y. Kuwatani, Y. Miyake
    • Organizer
      21^<st> International Symposium on the Organic Chemistry of Sulfur
    • Place of Presentation
      Spain
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Supramolecular Chemistry Based on the Self-Association of TTF Oligomers2004

    • Author(s)
      M. Iyoda
    • Organizer
      4^<th> Tateshina Conference on Organic Chemistry
    • Place of Presentation
      Tateshina, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Construction of Supramolecular Structures Using Poly(tetrathiafulvalenylethynyl)benzenes.2004

    • Author(s)
      M. Hasegawa, M. Iyoda
    • Organizer
      6th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      NY, USA
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Presentation] Supramolecular Chemistry Based on the Self-Association of TTF Oligomers.2004

    • Author(s)
      M. Iyoda
    • Organizer
      4^<th> Tateshina Conference on Organic Chemistry
    • Place of Presentation
      Tateshina, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Bi-and Bis-TTFs in TTF Chemistry2004

    • Author(s)
      Masahiko Iyoda
    • Total Pages
      28
    • Publisher
      Springer
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] Y.Kuwatani, G.Yamamoto, M.Iyoda: "A twin-rotor system created on the [4]radialene frame"Org.Lett.. 5. 3371-3374 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Enoki, H.Yamazaki, K.Okabe, K.Enomoto, T.Kato, A.Miyazaki.E.Ogura, Y.Kuwatani, M.Iyoda: "Unconventional TTF-Based Molecular Magnets"Synth.Met.. 133-134. 501-503 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Nishijo, E.Ogura, J.Yamaura, A.Miyazaki.T.Enoki, T.Takano, Y.Kuwatani, M.Iyoda: "Ferromagnetic Interaction and Melallic Conductivity of Radical Ion Salts (DIEDO)_2M(mnt)_2(M=Ni,Pt)"Synth.Met.. 133-134. 539-541 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Enoki, H.Yamazaki, J.Nishijo, A.Miyazaki.K.Ugawa, E.Ogura, Y.Kuwatani, M.Iyoda, Y.V.Sushko: "Novel Magnetism of EDO-TTFX_2 Salts (X=Br,I)"Synth.Met.. 137. 1173-1174 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Ohkoshi, T.Horino, M.Yoshida M.Iyoda: "Synthesis and Inclusion Properties of a Novel Macrocyclic Hexaketone Monohydrate with a Hemiacetal Structure"J.Chem.Soc., Chem.Commun.. 2586-2587 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Kuwatani, J.Igarashi, M.Iyoda: "All-Z-Hexabenzo[24]annulene with a triangular benzene cluster substructure"Tetrahedron Lett.. 45. 359-362 (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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