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Development of the sample mounted horizontally Laboratory Ultra-Soft X-Ray Absorption Spectrometer.

Research Project

Project/Area Number 15205012
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionFukuoka University

Principal Investigator

WAKITA Hisanobu  Fukuoka University, Faculty of Science, Professor, 理学部, 教授 (50078581)

Co-Investigator(Kenkyū-buntansha) KURISAKI Tsutomu  Fukuoka University, Faculty of Science, Research Associate, 理学部, 助手 (20268973)
TANIGUCHI Kazuo  Osaka Electro-Communication Univ., Faculty of Technology, Professor, 工学部, 教授 (50076832)
WATANABE Takashi  Kobeluko Research Institute Inc., Physical Analysis Dep., Senior Researcher, 物理解析部, 主幹研究員
Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥40,300,000 (Direct Cost: ¥31,000,000、Indirect Cost: ¥9,300,000)
Fiscal Year 2004: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2003: ¥33,800,000 (Direct Cost: ¥26,000,000、Indirect Cost: ¥7,800,000)
KeywordsLaboratory / Ultra-Soft X-Ray Absorption / Development of Spectrometer / Light Element / Total Electron Yield Method / Lithium Compounds / Synchrotron / X-ray Absorption Spectra / 超軟X線分光 / ポリフィリン / TiO_2 / XANESスペクトル / レーザー衝撃光源 / 国際情報交換 / アメリカ
Research Abstract

We have built a novel Laboratory Ultra-Soft X-Ray Absorption(USXA) Spectrometer optimized for the 50 eV to 150 eV Ultra-Soft X-Ray(USX) region and for the sample mounted horizontally. This Spectrometer can be used for scientific and industrial applications of soft x-ray absorption spectroscopy as an analytical tool. The high flux of〜100 eV photons would make it an ideal laboratory based instrument for the study of the chemistry and material properties of light element compounds. Our USXAFS spectrometer utilizes a specially developed laser generated quasi continuum high brightness USX source and a recently developed high efficient low noise detector system, enabling to measure XAS by a total electron yield(TEY) method or another method in the USX region. This efficiency laboratory USXA spectrometer is a complete computer controlled turnkey system, equipped with a user friendly control and data acquisition software and a simple sample loading mechanism to obtain XAS with very fast measurement time and accurate energy positions. The absorption spectra with very high accuracy in energy of the absorption features can be obtained in less than 5 minutes per sample. The results obtained from the reflectivity experiment were compared with those obtained by the ALS instrument. Both results indicate that our laboratory spectrometer gives the similar high flux and narrow beam size and excellent similar repeatability obtained from those of the synchrotron instrument. The measured curves of Li-K absorption edge for several lithium compounds show good fit in with those obtained by the synchrotron measurement within the measured range. These results were already reported and the sample preparations and their characterizations using by synchrotron instruments were also reported.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (26 results)

All 2005 2004 Other

All Journal Article (18 results) Book (2 results) Publications (6 results)

  • [Journal Article] Local Structure of Nitrogen Atoms in a Porphine Ring of meso-Phenyl Substituted Porhyrin with an Electron-Withdrawing Group Using X-ray Photoelectron Spectroscopy and X-ray Absorption Spectroscopy2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Ana.Sci (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural Analysis of a Cu(II) Complex with a Novel Macrocyclic Polyamine in Aqueous Solution2005

    • Author(s)
      T.Kurisaki
    • Journal Title

      J Mol.Liquid 119

      Pages: 153-158

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] XPSおよびXANES法を用いた金属ポルフィリン錯体の電子状態分析2005

    • Author(s)
      山重寿夫
    • Journal Title

      X線分析の進歩 36

      Pages: 313-325

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 全蛍光収量法で測定した軟X線吸収スペクトルの電子状態計算による形状解析:粉末および水溶液中のアルミン酸ナトリウムの構造解析2005

    • Author(s)
      松尾修司
    • Journal Title

      X線分析の進歩 36

      Pages: 303-312

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electronic Structure Analysis of Iron(III)-Porphyrin Complexes by X-ray Absorption spectra at C, N and Fe K-edges2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Ana.Sci 21

      Pages: 309-314

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Local Structure of Nitrogen Atoms in a Porphine Ring of meso-Phenyl Substituted Porhyrin with an Election-Withdrawing Group Using X-ray Photoelectron Spectroscopy and X-ray Absorption Spectroscopy2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Ana.Sci. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural Analysis of a Cu(II) Complex with a Novel Macrocyclic Polyamine in Aqueous Solution2005

    • Author(s)
      T.Kurisaki
    • Journal Title

      J.Mol.Liquid 119

      Pages: 153-158

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] XPS and XANES Analysis of the Electronic Structure in Metalloporphyrins2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Adv.X-ray.Chem.Anal. 36

      Pages: 313-325

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Analysis of Soft X-Ray Absorption Spectra Measured by a Total Fluorescence X-Ray Yield Mode Using Electronic State Calculations : Structure Analysis of Powder and Aqueous Solution of Sodium Aluminate2005

    • Author(s)
      S.Matsuo
    • Journal Title

      Adv.X-ray.Chem.Anal. 36

      Pages: 303-312

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electronic Structure Analysis of Iron (III)-Porphyrin Complexes by X-ray Absorption spectra at C,N and Fe K-edges2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Ana.Sci. 21

      Pages: 309-314

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural Analysis of a Cu(II) Complex with a Novel Macrocyclic Polyamine in Aqueous Solution2005

    • Author(s)
      T.Kurisaki
    • Journal Title

      J.Mol. Liquid (in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Local Structure around Iron(II) Ion in Lamprey Hemoglobin Using X-ray Absorption Spectroscopy2005

    • Author(s)
      H.Yamashige
    • Journal Title

      X-ray spectrometry (in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] XPSおよびXANES法を用いた金属ポルフィリン錯体の電子状態分析2005

    • Author(s)
      山重寿夫
    • Journal Title

      X線分析の進歩 13

      Pages: 313-325

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 全蛍光収量法で測定した軟X線吸収スペクトルの電子状態計算による形状解析:粉末および水溶液中のアルミン酸ナトリウムの構造解析2005

    • Author(s)
      松尾修司
    • Journal Title

      X線分析の進歩 (in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Electronic Structure Analysis of Iron(III)-Porphyrin Complexes by X-ray Absorption spectra at C, N and Fe K-edges2005

    • Author(s)
      H.Yamashige
    • Journal Title

      Ana.Sci. 21

      Pages: 309-314

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Role in Photocatalysis and Coordination Structure of Metal Ions Adsorbed on Titanium Dioxide Particles : A Comparison between Lanthanide and Iron Ions2004

    • Author(s)
      S.Matsuo
    • Journal Title

      Appl.Surf Sci. 228

      Pages: 233-244

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Role in Photocatalysis and Coordination Structure of Metal Ions Adsorbed on Titanium Dioxide Particles : A Comparison between Lanthanide and Iron Ions2004

    • Author(s)
      S.Matsuo
    • Journal Title

      Appl.Surf.Sci. 228

      Pages: 233-244

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Role in Photocatalysis and Coordination Structure of Metal Ions Adsorbed on Titanium Dioxide Particles : A Comparison between Lanthanide and Iron Ions2004

    • Author(s)
      S.Matuso
    • Journal Title

      Appl.Surf.Sci. 228

      Pages: 233-244

    • Related Report
      2004 Annual Research Report
  • [Book] 環境分析化学2004

    • Author(s)
      脇田久伸
    • Total Pages
      259
    • Publisher
      三共出版
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] Environmental Analytical Chemistry2004

    • Author(s)
      H.Wakita
    • Total Pages
      259
    • Publisher
      Sankyo Shuppan Inc.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] P.Nachimuthu: "Electronic and Structural Properties of "Smart Window" and Liquids Using In-situ X-ray Absorption Spectroscopy"J.Alloys Comp.. 362(1-2). 124-132 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Matsuo: "Role in Photocatalysis and Coordination Structure of Metal Ions Adsorbed on Titanium Dioxide Particles : A Comparison between Lanthanide and Iron Ions"Appl.Surf.Sci.. (in press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Matsuo: "Electronic Structures of Crystalline and Aqueous Solutions of LiBr, NaBr, KBr, and KBrO_3 : In Situ Br L-edge Near-edge X-ray Absorption Fine Structure"J.Phys.Chem.B. 107. 12562-12565 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 栗崎 敏: "XAFS法による金属錯体の溶存構造解析"X線分析の進歩. 34. 41-51 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 松尾修司: "新しく開発した液体セルシステムによる軽金属塩水溶液の軟X線吸収分光測定"X線分析の進歩. 34. 115-123 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 山重 寿夫: "配位子の軟X線吸収スペクトルによる金属ポルフィリン錯体の状態分析"X線分析の進歩. 34. 217-225 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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