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Development of Aquacatalytic Polymer-Dispersed Nanometal Composites

Research Project

Project/Area Number 15205015
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionInstitute for Molecular Science (2004-2006)
Okazaki National Research Institutes (2003)

Principal Investigator

UOZUMI Yasuhiro  Institute for Molecular Science, Research Center for Molecular-scale Nanoscience, Professor, 分子スケールナノサイエンスセンター, 教授 (90201954)

Project Period (FY) 2003 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥50,830,000 (Direct Cost: ¥39,100,000、Indirect Cost: ¥11,730,000)
Fiscal Year 2006: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2005: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2004: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2003: ¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
KeywordsNanometal / palladium, platinum / catalysis in water / immobilization / pincer complex / amphiphilic polymer
Research Abstract

An amphiphilic resin-dispersion of nanoparticles of platinum and palladium were developed which exhibited high catalytic activity in aerobic oxidation of a wide variety of alcohols in water with an oxygen or air atmosphere. A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdC12(CH3CN)2 and a trisphosphine hub with three flexible alkylchain linkers.
A novel solid-phase self-organized catalyst of palladium nanoparticles was prepared from PdC12 with main-chain viologen polymers via complexation and reduction. This insoluble nanocatalyst nano-Pd catalyst efficiently promoted a-alkylation of ketones with primary alcohols. A tightly convoluted polymeric phosphotungstate catalyst was prepared via ionic-assembly of H3PW12040 and poly (alkylpyridinium).
An oxidative cyclization of various alkenols and alkenoic acids was efficiently promoted by the polymeric catalyst. The pincer complexes bearing a plane coordination structure and functional substituents were prepared to realize stereoselective catalysis and supra complex formation.

Report

(5 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (35 results)

All 2006 2005 2004 Other

All Journal Article (29 results) Book (1 results) Publications (5 results)

  • [Journal Article] Asymmetric π -allylic etherification of cycloalkenyl esters with phenols in water using a resin-supported chiral palladium complex2006

    • Author(s)
      Yasuhiro Uozumi, Masahiro Kimura
    • Journal Title

      Tetrahedron : Asymmetry 17

      Pages: 161-166

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A Solid-Phase Self-Organized Catalyst of Nanopalladium with Main-Chain Viologen Polymers : alfa-Alkylation of Ketones with Primary Alcohols2006

    • Author(s)
      Yoichi M.A.Yamada, Yasuhiro Uozumi
    • Journal Title

      Organic Letters 8

      Pages: 1375-1378

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Amphezonol A, a novel polyhydroxyl metabolite from marine dinoflagellate Amphidinium sp.2006

    • Author(s)
      Takaaki Kubota, Yusuke Sakuma, Kazutaka Shimbo, Masashi Tsuda, Michiko Nakano, Yasuhiro Uozumi, Junichi Kobayashi
    • Journal Title

      Tetrahedron Letters 47

      Pages: 4369-4371

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Novel 3D Coordination Palladium-Network Complex : A Recyclable Catalyst for Suzuki-Miyaura Reaction2006

    • Author(s)
      Yoichi M.A.Yamada, Yasunari Maeda, Yasuhiro Uozumi
    • Journal Title

      Organic Letters 8

      Pages: 4259-4262

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] π-Allylic Azidation in Water with an Amphiphilic Resin-Supported Palladium-Phosphine Complex2006

    • Author(s)
      Yasuhiro Uozumi, Toshimasa Suzuka, Ray Kawade, Hiroe Takenaka
    • Journal Title

      Synlett

      Pages: 2109-2113

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] PCP Pincer Palladium Complexes and Their Catalytic Properties : Synthesis via the Electrophilic Ligand Introduction Route2006

    • Author(s)
      Tsutomu Kimura, Yasuhiro Uozumi
    • Journal Title

      Organometallics 25

      Pages: 4883-4887

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] A Combinatorial Approach to Heterogeneous Asymmetric Aquacatalysis with Amphiphilic Polymer-Supported Chiral Phosphine-Palladium Complexes2006

    • Author(s)
      Yukinari Kobayashi, Daiki Tanaka, Hiroshi Danjo, Yasuhiro Uozumi
    • Journal Title

      Advanced Synthesis & Catalysis 348

      Pages: 1561-1566

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] π -Allylic C1-Substitution in Water with Nitromethane Using Amphiphilic Resin-Supported Palladium Complexes2006

    • Author(s)
      Yasuhiro Uozumi, Toshimasa Suzuka
    • Journal Title

      The Journal of Organic Chemistry 71

      Pages: 8644-8646

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Alkylative Cyclization of 1,6-Enynes in Water with an Amphiphilic Resin-Supported Palladium Catalyst2006

    • Author(s)
      Yasushi Nakai, Tsutomu Kimura, Yasuhiro Uozumi
    • Journal Title

      Synlett

      Pages: 3065-3068

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Instantaneous Carbon-Carbon Bond Formation Using a Microchannel Reactor with a Catalytic Membrane2006

    • Author(s)
      Yasuhiro Uozumi, Yoichi M.A.Yamada, Tomohiko Beppu, Naoshi Fukuyama, Masaharu Ueno, Takehiko Kitamori
    • Journal Title

      Journal of The American Chemical Society 128

      Pages: 15994-15995

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Asymmetric π-allylic etherification of cycloalkenyl esters with phenols in water using a resin-supported chiral palladium complex2006

    • Author(s)
      Yasuhiro Uozumi, Masahiro Kimura
    • Journal Title

      Tetrahedron : Asymmetry 17

      Pages: 161-166

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Amphezonol A, a novel polyhydroxyl metabolitee from marine dinoflagellate Amphidiniium sp2006

    • Author(s)
      Takaaki Kubota, Yusuke Sakuma, Kazutaka Shimbo, Masashi Tsuda, Michiko Nakano, Yasuhiro Uozumi, Junichhi Kobayashi
    • Journal Title

      Tetrahedron Letters 47

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A Combinatorial Approach to Heterogeneous Asymmetric Aquacatalysis with Amphiphilic Polymer- Supported Chiral Phosphine-Palladium Complexes2006

    • Author(s)
      Yukinari Kobayashi, Daiki Tanaka, Hiroshi Danjo, Yasuhiro Uozumi
    • Journal Title

      Advanced Synthesis & Catalysis 348

      Pages: 1561-1566

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] π-Allylic Cl-Substitution in Water with Nitromethane Using Amphiphilic Resin-Supported Palladium Complexe2006

    • Author(s)
      Yasuhiro Uozumi, Toshimasa Suzuka
    • Journal Title

      The Journal of Organic Chemistry 71

      Pages: 8644-8646

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Alkylative Cyclization of 1,6-Enynes in Water with an Amphiphilic Resin-Supported Palladium Catalyst2006

    • Author(s)
      Yasushi Nakai, Tsutomu Kimura, Yasuhiro Uozumi.
    • Journal Title

      Synlett

      Pages: 305-3068

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A Solid-phase Self-Organized Catalyst of Nanopalladium with Main-Chain Viologen Polymers : alfa-Alkylation of Ketones with Primary Alcohols2006

    • Author(s)
      Yoichi M, A.Yamada, Yasuhiro Uozumi
    • Journal Title

      Organic Letters 8

      Pages: 1375-1378

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Novel 3D Coordination Palladium-Network Complex : A Recyclable Catalyst for Suzuki-Miyaura Reaction2006

    • Author(s)
      Yoichi M, A.Yamada, Yasunari Maeda, Yasuhiro Uozumi
    • Journal Title

      Organic Letters 8

      Pages: 4259-4262

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Combinatorial Approach to Heterogeneous Asymmetric Aqua catalysis with Amphiphilic Polymer-Supported Chiral Phosphine-Palladium Complexes2006

    • Author(s)
      Yukinari Kobayashi, Daiki Tanaka, Hiroshi Danjo, Yasuhiro Uozumi
    • Journal Title

      Advanced Synthesis & Catalysis 348

      Pages: 1561-1566

    • Related Report
      2006 Annual Research Report
  • [Journal Article] π-Allylic C1-Substitution in Water with Nitro methane Using Amphiphilic Resin-Supported Palladium Complexes2006

    • Author(s)
      Yasuhiro Uozumi, Toshimasa Suzuka
    • Journal Title

      The Journal of Organic Chemistry 71

      Pages: 8644-8646

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Instantaneous Carbon-Carbon Bond Formation Using a Micro channel Reactor with a Catalytic Membrane2006

    • Author(s)
      Yasuhiro Uozumi, Yoichi M, A.Yamada, Tomohiko Beppu, Naoshi Fukuyama, Masaharu Ueno, Takehiko Kitamori
    • Journal Title

      Journal of The American Chemical Society 128

      Pages: 15994-15995

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hydrogenation and Dehalogenation under Aqueous Conditions with an Amphiphilic-Polymer-Supported Nanopalladium Catalyst2005

    • Author(s)
      Ryu Nakao, Hakjyune Rhee, Yasuhiro Uozumi*
    • Journal Title

      Organic Letters 7

      Pages: 163-165

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Cycloisomerization of 1,6-Enynes : Asymmetric Multistep Preparation of a Hydrindane Framework in Water with Polymeric Catalysts2005

    • Author(s)
      Yasushi Nakai, Yasuhiro Uozumi*
    • Journal Title

      Organic Letters 7

      Pages: 291-293

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Controlled Monoarylation of Dibromoarenes in Water with a Polymeric Palladium Catalyst2005

    • Author(s)
      Yasuhiro Uozumi, Makoto Kikuchi
    • Journal Title

      Synlett

      Pages: 1775-1778

    • Related Report
      2005 Annual Research Report
  • [Journal Article] NCN Pincer Palladium Complexes ; Their Preparation via Ligand Introduction Route and Their Catalytic Properties2005

    • Author(s)
      Kazuhiro Takenaka, Maki Minakawa, Yasuhiro Uozumi
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 12273-12281

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 高分子固定化遷移金属触媒による水中有機変換反応2005

    • Author(s)
      魚住 泰広
    • Journal Title

      触媒学会 47(NO.7)

      Pages: 550-555

    • Related Report
      2005 Annual Research Report
  • [Journal Article] PS-PEG resin-supported palladium-MOP complexes, Application in asymmetric π-allylic reduction2004

    • Author(s)
      Heiko Hocke, Yasuhiro Uozumi
    • Journal Title

      Tetrahedron 60

      Pages: 9297-9306

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Development of Chiral Pincer Palladium Complexes Bearing a Pyrroloimidazolone Unit. Catalytic Use for Asymmetric Michael Addition2004

    • Author(s)
      Kazuhiro Takenaka, Yasuhiro Uozumi
    • Journal Title

      Organic Lett. 6(No11)

      Pages: 1833-1835

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Deuterium-Labeling Studies Establishing Stereochemistry at the Oxypalladation Step in Wacker-Type Oxidative Cyclization of an o-Allylphenol2004

    • Author(s)
      Tamio Hayashi, Kaori Yamasaki, Michihiro Mimura, Yasuhiro Uozumi
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 3036-3037

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Asymmetric Allylic Amination in Water Catalyzed by an Amphiphilic Resin-Supported Chiral Palladium Complex2004

    • Author(s)
      Yasuhiro Uozumi, Hirotaka Tanaka, Kazutaka Shibatomi
    • Journal Title

      Organic Lett. 6

      Pages: 281-283

    • Related Report
      2004 Annual Research Report
  • [Book] Recent Progress in Polymeric Palladium Catalysts for Organic Synthesis2004

    • Author(s)
      Yasuhiro Uozumi
    • Publisher
      Topics in Current Chemistry
    • Related Report
      2004 Annual Research Report
  • [Publications] Uozumi, Yasuhiro, Tanaka, Hirotaka, Shibatomi, Kazutaka: "Asymmetric Allylic Amination in Water Catalyzed by an Amphiphilic Resin-Supported Chiral Palladium Complex"Org.Lett.. 6. 281-283 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Hocke, Heiko, Uozumi, Yasuhiro: "A Simple Synthetic Approach to Homochiral 6- and 6'-substituted 1,1'-Binaphthyl Derivatives"Tetrahedron. 59. 619-630 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 魚住 泰広: "水中機能性固定化パラジウム錯体触媒反応"ファルマシア. 39. 647-649 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 魚住 泰広: "先端科学シリーズI 有機金属/キラル/触媒/高分子 日本化学会編 不斉工程開発へのコンビナトリアルアプローチ"丸善株式会社. 99-105 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 魚住 泰広: "先端科学シリーズV 海洋天然物/錯体/コンビナトリアル/全合成 日本化学会編 錯体触媒反応における近年のブレークスルー"丸善株式会社. 93-98 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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