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Defect reduction of super widegap semiconductor AlN by high temperature metalorganic vapor phase epitaxy and device applications

Research Project

Project/Area Number 15206003
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionMeijo University

Principal Investigator

AMANO Hiroshi  Meijo Univ., Materials Science and Engineering, Professor, 理工学部, 教授 (60202694)

Co-Investigator(Kenkyū-buntansha) KAMIYAMA Satoshi  Meijo Univ., Materials Science and Engineering, Associate Professor, 理工学部, 助教授 (10340291)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥47,840,000 (Direct Cost: ¥36,800,000、Indirect Cost: ¥11,040,000)
Fiscal Year 2005: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2004: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2003: ¥40,040,000 (Direct Cost: ¥30,800,000、Indirect Cost: ¥9,240,000)
KeywordsAlN / UV Laser Diode / UV Light Emitting_Diode / Epitaxial Lateral Overgrowth / Sapphire / UV photo Diode / High temperature MOVPE / AlN / 紫外レーザダイオード / ホモエピタキシャル成長
Research Abstract

Blue, green and white light emitting diodes and violet laser diodes on sapphire substrates have been already commercialized which are based on the low temperature buffer layer technology developed by us. Applications of nitride semiconductors are not limited to visible range, but can be applied to ultraviolet range. Expected applications of solid state UV/DUV light emitters/detectors include sterilizer, DNA analyzer, laser knife, flame sensor, dermatology, molecular tweezers, weather observation, gas decomposition, photolithography, etc. Formerly, AlN was grown at or lower than 1,200□ on other materials such as sapphire or SiC. Our previous mass transport study showed that in order to achieve sufficient migration of Al precursor, AlN should be grown higher than 1,200□.
The objective of this study is as follows ;
(1)Growth of AlN substrate by sublimation
(2)Growth of AlN on sapphire by metalorganic vapor phase epitaxy (MOVPE) at high temperature, and
(3)Fabrication of high quality AlGaN-based quantum structure and UV emitting device
In 2003, custom designed MOVPE reactor which is capable of raising temperature as high as 1,800□ was installed and operated with the cooperation of Ibiden Co.,Ltd. Sublimation growth of AlN on SiC and spontaneous nucleation was performed. In 2004, world's shortest wavelength laser diode on sapphire was successfully fabricated on epitaxially lateral overgrown (ELO) low dislocation density AlGaN. High quality and thick AlN was grown on sapphire by high temperature MOVPE. In 2005, we successfully grow low dislocation density AlN on sapphire using ELO technique with a dislocation density as low as 10^7cm^<-2> or less.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (27 results)

All 2006 2005 2004 2003 Other

All Journal Article (20 results) Book (1 results) Patent(Industrial Property Rights) (1 results) Publications (5 results)

  • [Journal Article] Microstructure of thick AIN grown on sapphire by high-temperature MOVPE2006

    • Author(s)
      M.Imura, K.Nakano, T.Kitano, N.Fujimoto, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica Status Solide (a) 233

      Pages: 1626-1631

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Growth of high-quality AIN with high growth rate by high-temperature MOVPE2006

    • Author(s)
      N.Fujimoto, T.Kitano, G.Narita, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amana, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica Status Solidi (c) 3

      Pages: 1617-1619

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Thermodynamic Aspects of Growth of AlGaN by High-Temperature Metal Organic Vapor Phase Epitaxy2006

    • Author(s)
      N.Okada, N.Fujimoto, T.Kiano, G.Narita, M.Imura, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Japanese Journal of Applied physics 45、No.4a

      Pages: 2502-2504

    • NAID

      40007227457

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructure of thick AlN grown on sapphire by high-temperature MOVPE2006

    • Author(s)
      M.Imura, K.Nakano, T.Kitano, N.Fujimoto, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica.Status Solidi (a) 233

      Pages: 1626-1631

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Growth of high-quality AlN with high growth rate by high-temperature MOVPE2006

    • Author(s)
      N.Fujimoto, T.Kitano, G.Narita, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica.Status Solidi (c) 3

      Pages: 1617-1619

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Thermodynamic Aspects of Growth of AlGaN by High-Temperature Metal Organic Vapor Phase Epitaxy2006

    • Author(s)
      N.Okada, N.Fujimoto, T.Kitano, G.Narita, M.Imura, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Japanese Journal of Applied Physics 45, No.4a

      Pages: 2502-2504

    • NAID

      40007227457

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructure of thick AlN grown on sapphire by high-temperature MOVPE2006

    • Author(s)
      M.Imura, K.Nakano, T.Kitano, N.Fujimoto, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica Status Solidi (To be published)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Growth of High-Quality AlN with High Growth Rate by High Temperature MOVPE2006

    • Author(s)
      N.Fujimoto, T.Kitano, G.Narita, N.Okada, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Physica Status Solidi (To be published)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Thermodynamic Aspects of Growth of AlGaN by High-Temperature Metal Organic Vapor Phase Epitaxy2006

    • Author(s)
      N.Okada, N.Fujimoto, T.Kitano, G.Narita, M.Imura, K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, K.Shimono, T.Noro, T.Takagi, A.Bandoh
    • Journal Title

      Japanese Journal of Applied Physics 45,No.4a(未定)

    • NAID

      40007227457

    • Related Report
      2005 Annual Research Report
  • [Journal Article] High-Efficiency Nitride-Based Light-Emitting Diodes with Moth-Eye Structure2005

    • Author(s)
      H.Kasugai, Y.Miyake, A.Honshio, S.Mishima, T.Kawashima, K.Iida, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, H.Kinoshita, H.Shiomi
    • Journal Title

      Japanese Journal of Applied Physics 44,No.10

      Pages: 7414-7417

    • NAID

      130004766017

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Laser Diode of 350.9nm wavelength Grown on Sapphire substrate by MOVPE2004

    • Author(s)
      K.Iida, T.Kawashima, A.Miyazaki, H.Kasugai, S.Mishima, A.Honshio, Y.Miyake, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki
    • Journal Title

      Journal of Crystal Growth 272

      Pages: 270-273

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] High-quality Al_<0.12>Ga_<0.88>N with low dislocation density grown on facet-controlled Al_<0.12>Ga_<0.88>N by MOVPE2004

    • Author(s)
      T.Kawashima, K.Iida, Y.Miyake, A.Honshio, H.Kasugai, M.Imura, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki
    • Journal Title

      Journal of Crystal Growth 272

      Pages: 377-380

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Study on the Seeded Growth of AIN Bulk Crystals by Sublimation2004

    • Author(s)
      K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, T.Takagi, T.Noro
    • Journal Title

      Japanese Journal of Applied Physics 43

      Pages: 7448-7453

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Defect and stress control of AIGaN for fabrication of high performance UV light emitters2004

    • Author(s)
      H.Amano, A.Miyazaki, K.Iida, T.Kawashima, M.Iwaya, S.Kamiyama, I.Akasaki, R.Liu, A.Bell, F.A.Ponce
    • Journal Title

      Physica.Status solidi (a) (a)201

      Pages: 2679-2685

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Laser Diode of 350.9nm wavelength grown on sapphire substrate by MOVPE2004

    • Author(s)
      K.Iida, T.Kawashima, A.Miyazaki, H.Kasugai, S.Mishima, A.Honshio, Y.Miyake, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki
    • Journal Title

      Journal of Crystal Growth 272

      Pages: 270-273

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Study on the Seeded Growth of AlN Bulk Crystals by Sublimation2004

    • Author(s)
      K.Balakrishnan, M.Iwaya, S.Kamiyama, H.Amano, I.Akasaki, T.Takagi, T.Noro
    • Journal Title

      Japanese Journal of Applied Physics 43

      Pages: 7448-7453

    • NAID

      10014029896

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Defect and stress control of AlGaN for fabrication of high performance UV light emitters2004

    • Author(s)
      H.Amano, A.Miyazaki, K.Iida, T.Kawashima, M.Iwaya, S.Kamiyama, I.Akasaki, R.Liu, A.Bell, F.A.Ponce
    • Journal Title

      Physica.Status Solidi (a) 201

      Pages: 2679-2685

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Defect and stress control of AlGaN for fabrication of high performance UV light emitters2004

    • Author(s)
      H.Amano, A.Miyazaki, K.Iida, T.Kawashima, M.Iwaya, S.Kamiyama, I.Akasaki, R.Liu, A.Bell, F.A.Ponce
    • Journal Title

      Physica.Status Solidi (a)201

      Pages: 2679-2685

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Platelet Inversion Domains Induced by Mg-Doping in ELOG AlGaN Films2004

    • Author(s)
      R.Liu, F.A.Ponce, D.Cherns, H.Amano, I.Akasaki
    • Journal Title

      Materials Research Society Symposium Proceedings 798

      Pages: 765-770

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Spatial variation of luminescence from AlGaN grown by facet controlled epitaxial lateral overgrowth2004

    • Author(s)
      A.Bell, R.Liu, U.K.Parasuraman, F.A.Ponce, S.Kamiyama, H.Amano, I.Akasaki
    • Journal Title

      Applied Physics Letters

      Pages: 3417-3419

    • Related Report
      2004 Annual Research Report
  • [Book] "Nitride Semiconductors", Handbook on Materials and Devices, Edited by P.Ruterana,M.Albrecht,J.Neugebauer2003

    • Author(s)
      H.Amano
    • Total Pages
      664
    • Publisher
      Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 窒化物系化合物半導体の製造方法2005

    • Inventor(s)
      天野 浩
    • Industrial Property Rights Holder
      名城大学
    • Filing Date
      2005-11-14
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] H.Amano, S.Takanami, M.Iwaya, S.Kamiyama, I.Akasaki: "Group-III Nitride-Based UV-Light Emitting Devices"Phys.Stat.Sol.(a). 195. 491-495 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] R.Liu' A.Bell, F.Ponce, D.Cherns, H.Amano, I.Akasaki: "Distinct Magnesium Incorporation Behavior in Laterally Grown AlGaN"Mat.Res.Soc.Symp.Proc.. 743. 27-34 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] D.Cherns, Y.Wang, R.Liu, F.Ponce, H.Amano, I.Akasaki: "Hollow Core Dislocations in Mg-Doped AlGaN"Mat.Res.Soc.Symp.Proc.. 743. 609-614 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] E.Valcheva, T.Paskova, G.Z.Radnoczi, L.Hultman, B.Monemar, H.Amano, I.Akasaki: "Growth-induced defects in AlN/GaN superlattices with different periods"PHYSICA B. 340-342. 1129-1132 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Amano: ""Nitride Semiconductors",Handbook on Materials and Devices,"Wiley-VCH Verlag GmbH & Co.KGaA, Weinheim(Edited by P.Ruterana, M.Albrecht, J.Neugebauer). 664 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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