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Application of Resonance Oscillation to the Design of Heterogeneous Catalysts with Artificially Controllable Functions for Chemical Reactions

Research Project

Project/Area Number 15206088
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionNagaoka University of Technology

Principal Investigator

INOUE Yasunobu  Nagaoka University of Technology, Department of Chemistry, Professor, 工学部, 教授 (30016133)

Co-Investigator(Kenkyū-buntansha) NISHIYAMA Hiroshi  Nagaoka University of Technology, Analysis Center, Assistant Professor, 分析計測センター, 助手 (50303186)
SAITO Nobuo  Nagaoka University of Technology, Analysis Center, Assistant Professor, 分析計測センター, 助教授 (40313572)
Project Period (FY) 2003 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥46,280,000 (Direct Cost: ¥35,600,000、Indirect Cost: ¥10,680,000)
Fiscal Year 2006: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2005: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2004: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2003: ¥20,800,000 (Direct Cost: ¥16,000,000、Indirect Cost: ¥4,800,000)
KeywordsResonance oscillation / Ferroelectric crystals / Catalysts / Acoustic waves / Reaction selectivity / Activity / Lattice distortion / Work function / 強誘電体基板 / Pt触媒 / AgAu合金触媒 / 強誘電体 / 反応選択性制御 / エタノール分解反応 / 銀触媒 / 共鳴震動効果 / AgCu合金触媒 / Mo担持Pd触媒 / エチレン酸化 / 仕事関数 / Pd / 選択性 / 膜厚依存性
Research Abstract

Resonance oscillation (RO) of bulk acoustic waves generated by piezoelectric effects on poled ferroelectric crystals by rf electric power causes the dynamic distortion of thin metal film surfaces deposited. In C_2H_5OH and CO oxidation and C_2H_5OH decomposition on Ag and Pd catalysts, thickness-extension mode RO (TERO) was found to have a capability of enhancing not only catalytic activity, but also reaction selectivity. In contrast, thickness-shear mode resonance oscillation (TSRO) showed no activation effects. Laser Doppler and photoemission spectroscopic measurements showed that TERO caused large lattice displacement vertical to the surface and to induce work function shifts of the metal catalysts, whereas no such changes occurred with TSRO. The TERO effects on catalyst activation depended on the polarization direction of ferroelectric substrates and resonance frequency, indicating that large vertical lattice displacement and the density of sites causing lattice displacement are responsible for strong catalyst activation. The TERO effects were intrinsically different in ethanol decomposition between Ag and AgAu alloy catalysts. TERO-induced activation occurred only for ethylene production on a Ag metal, whereas TERO effects had strong dependence on alloy compositions. The activation for ethylene production was nearly independent of alloy composition, but that for acetaldehyde production exhibited a maximum at around 80% surface Au content where the vertical lattice displacement became the smallest. Thus, it was proposed that the TERO effects on acetaldehyde production over the AgAu binary alloy catalysts increased in the case where Ag-Au atom interactions became strong. The RO effects on heterogeneous catalysis by metals are new phenomena and are concluded to be quite useful for the development of a heterogeneous catalyst with artificially controllable functions for chemical reactions.

Report

(5 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (31 results)

All 2007 2006 2005 2004 2003 Other

All Journal Article (28 results) Publications (3 results)

  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. VII. Catalytic Activity of AgAu Binary Alloy for Ethanol Decomposition2007

    • Author(s)
      N.Saito, Y.Sato, H.Nishiyama, Y.Inoue
    • Journal Title

      J. Phys. Chem. B 111・3

      Pages: 1428-1433

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. VII. Catalytic Activity of AgAu Binary Alloy for Ethanol Decomposition.2007

    • Author(s)
      Nobuo Saito, Yuichi Sato, Hiroshi Nishiyama, Yasunobu Inoue
    • Journal Title

      J.Phys.Chem. 111

      Pages: 1428-1433

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. VII. Catalytic Activity of AgAu Binary Alloy for Ethanol Decomposition2007

    • Author(s)
      N.Saito, Y.Sato, H.Nishiyama, Y.Inoue
    • Journal Title

      J. Phys. Chem. B 111

      Pages: 1428-1433

    • Related Report
      2006 Annual Research Report
  • [Journal Article] PEEM study of Work Function Changes in Cu, Au and Pd Metal Surfaces with Surface Acoustic Wave Propagation2006

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surf. Sci. 600

      Pages: 2644-2649

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 金属薄膜表面の仕事関数に及ぼす弾性表面波の効果2006

    • Author(s)
      西山 洋, 井上 泰宣
    • Journal Title

      PETROTECH 28

      Pages: 259-263

    • NAID

      10016630411

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] PEEM study of Work Function Changes in Cu, Au and Pd Metal Surfaces with Surface Acoustic Wave Propagation.2006

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surf.Sci. 600

      Pages: 2644-2649

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 金属薄膜表面の仕事関数に 及ぼす弾性表面波の効果2006

    • Author(s)
      西山 洋, 井上泰宣
    • Journal Title

      PETROTECH 28

    • NAID

      10016630411

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] PEEM study of Work Function Changes in Cu, Au and Pd Metal Surfaces with Surface Acoustic Wave Propagation,2006

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surf. Sci., 600

      Pages: 2644-2649

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Promotion of partial oxidation of methanol over thin Pt and Pd film catalysts by resonance oscillation of acoustic waves2005

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      Appl. Surf. Sci. 250

      Pages: 104-108

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] IRAS study of surface acoustic wave effects on CO adsorbed on Cu surfaces2005

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surf. Sci. 594

      Pages: 156-162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Promotion of partial oxidation of methanol over thin Pt and Pd film catalysts by resonance oscillation of acoustic waves.2005

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      Appl.Surf.Sci. 250250

      Pages: 104-108

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] IRAS study of surface acoustic wave effects on CO adsorbed on Cu surfaces.2005

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surf.Sci. 594

      Pages: 156-162

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Promotion of partial oxidation of methanol over thin Pt and Pd film catalysts by resonance oscillation of acoustic waves2005

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      Appl.Surf.Sci. 250

      Pages: 104-108

    • Related Report
      2005 Annual Research Report
  • [Journal Article] IRAS study of surface acoustic wave effects on CO adsorbed on Cu surfaces2005

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      Surface Science 594

      Pages: 156-162

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effects Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. V. Effects of Ferroelectric Crystal Thickness on Catalytic Behavior of Ag for Ethanol Decomposition2004

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      J. Phys. Chem. B 108・52

      Pages: 20199-20203

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 共鳴振動によって誘起される金属触媒表面の反応場2004

    • Author(s)
      井上 泰宣
    • Journal Title

      触媒 46

      Pages: 230-236

    • NAID

      10013449857

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. V. Effects of Ferroelectric Crystal Thickness on Catalytic Behavior of Ag for Ethanol Decomposition2004

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 20199-20203

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 共鳴振動によって誘起される金属触媒 表面の反応場2004

    • Author(s)
      井上泰宣
    • Journal Title

      触媒 46

      Pages: 230-236

    • NAID

      10013449857

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation of Acoustic Waves on Catalytic and Surface Properties. V.Effects of Ferroelectric Crystal Thickness on Catalytic Behavior of Ag for Ethanol Decomposition2004

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      J.Phys.Chem. 108・34

      Pages: 20199-20203

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Different Acoustic Wave Effects of Thickness Extension and Thickness Shear Mode Resonance Oscillation on Ethanol Decomposition over Pd Catalysts Deposited on Poled Ferroelectric LiNbO_3 Single Crystals2003

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      Surf. Sci. 532/535

      Pages: 359-363

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resonance Oscillation or Acoustic Waves on Catalytic and Surface Properties IV. Activation of a Ag Catalyst for Ethanol Decomposition by Overtone Resonance Frequency2003

    • Author(s)
      N.Saito, Y.Inoue
    • Journal Title

      J. Phys. Chem., B 107・9

      Pages: 2040-2045

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Opposite Changes in Work Function of Low and High Index Copper Surfaces with Surface Acoustic Wave Propagation2003

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      J. Phys. Chem. B 107・34

      Pages: 8738-8741

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Different Acoustic Wave Effects of Thickness Extension and Thickness Shear Mode Resonance Oscillation on Ethanol Decomposition over Pd Catalysts Depoosited on Poled Ferroelectric LiNbO3 Single Crystals.2003

    • Author(s)
      Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue
    • Journal Title

      Surf.Sci. 532/535

      Pages: 359-363

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Thickness Extension Mode Resononace Oscillation of Acoustic Waves on Catalytic and Surface Properties IV. Activation of a Ag Catalyst for Ethanol Decomposition by Overtone Resonance Frequency.2003

    • Author(s)
      N.Saito, Y.Inoue
    • Journal Title

      J.Phys.Chem. B107(9)

      Pages: 2040-2045

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Opposite Changes in Work Function of Low and High Index Copper Surfaces with Surface Acoustic Wave Propagation.2003

    • Author(s)
      H.Nishiyama, Y.Inoue
    • Journal Title

      J.Phys.Chem.B 107(34)

      Pages: 8738-8741

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Acoustic Waves on Catalytic and Adsorptive Properties of Metal, Alloy and Metal Oxide Surfaces

    • Author(s)
      Y.Inoue
    • Journal Title

      Surf. Sci. Rep. (In press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Acoustic Waves on Catalytic and Adsorptive Properties of Metal, Alloy and Metal Oxide Surfaces.

    • Author(s)
      Y.Inoue
    • Journal Title

      Surf.Sci.Rep. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Acoustic Waves on Catalytic and Adsorptive Properties of Metal, Alloy and Metal Oxide Surfaces

    • Author(s)
      Y.Inoue
    • Journal Title

      Surf. Sci. Rep. (In press)

    • Related Report
      2006 Annual Research Report
  • [Publications] H.Nishiyama, Y.Inoue: "Opposite changes in work function of low and high index copper surfaces with surface acoustic wave propagation"J.Phys.Chem.. 107・34. 8738-8741 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Yukawa, N.Saito, H.Nishiyama, Y.Inoue: "Different acoustic wave effects of thickness extension and thickness shear mode resonance oscillation on ethanol decomposition over Pd catalysts deposited on poled ferroelectric LiNbO3 single crystals"Surf.Sci.. 532-535. 359-363 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Saito, Y.Inoue: "Effects of thickness extension mode resonance oscillation of acoustic waves on catalytic and surface properties. IV. Activation of a Ag catalyst for ethanol decomposition by overtone resonance frequencies"J.Phys.Chem.. 107・9. 2040-2045 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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