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BEHAVIOR OF METALS DURING FORMATION OF BASE METAL DEPOSITS

Research Project

Project/Area Number 15340182
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionUNIVERSITY OF TSUKUBA (2004-2005)
Tohoku University (2003)

Principal Investigator

HAYASHI Ken-ichiro  UNIVERSITY OF TSUKUBA, GRADUATE SCHOOL OF LIFE AND ENVIRONMENTAL SCIENCE, PROFESSOR, 大学院・生命環境科学研究科, 教授 (40124614)

Co-Investigator(Kenkyū-buntansha) FUJIMAKI Hirokazu  TOHOKU UNIVERSITY, GRADUATE SCHOOL OF SCIENCE, PROFESSOR, 大学院・理学研究科, 教授 (90133933)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥16,300,000 (Direct Cost: ¥16,300,000)
Fiscal Year 2005: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2004: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2003: ¥11,900,000 (Direct Cost: ¥11,900,000)
KeywordsFLUID INCLUSION / HYDROTHERMAL SYSTEM / BOILING / SYNCHROTRON X-RAY FLUORESCENCE / BASE METAL DEPOSIT / MAGMATIC FLUID / METAMORPHIC FLUID / 熱水鉱床 / 斑岩型鉱床 / 重金属 / 熱水の沸騰 / ラテライト型ニッケル鉱床 / 水-岩石反応 / 変成鉱床 / 酸素同位体
Research Abstract

Magmatic fluid separated from hydrous magma has high salinity, and contains heavy metals and gaseous components such as CO_2. Magmatic fluids are believed to be responsible for the formation of hydrothermal ore deposits. Volatile components dissolved in fluid move into vapor phase, while salts and metals remain in liquid phase during boiling of fluids. However, metals of high concentration are occasionally found in vapor-rich fluid inclusion associated with high temperature hydrothermal system. Such vapor inclusions suggest that the behavior of metals under boiling hydrothermal system is more complex than it has been believed. In order to clarify the behavior of metals during boiling, newly designed high temperature autoclave was introduced in this study. Fractionation of Cu and Zn between coexisting vapor and liquid phases was determined to analyze concentration of these metals in fluid inclusions synthesized under boiling condition. Our result suggests that high concentration of copper occasionally found in vicinity of natural high temperature hydrothermal system is probably dissolved as sulfide complex. Synchrotron X-ray fluorescence was used as a technique to analyze individual fluid inclusion in present study. The quantification of this methodology was established to make up correction lines using synthetic fluid inclusions of known concentrations of metals. Hydrothermal experiments on the solubility of NaCl in the system NaCl-CO_2-H_2O were also conducted. Studies on the origin and nature of ore-forming fluid of the manto-type Cu deposit at the Andes area, Chile, and those of metamorphic water associated with contact metamorphosed bedded manganese deposit were conducted.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (22 results)

All 2006 2005 2003 Other

All Journal Article (18 results) Publications (4 results)

  • [Journal Article] Synthetic fluid inclusions in the system NaCl-H_2O and NaCl-CO_2-H_2O : Dissolution temperatures of halite2006

    • Author(s)
      Nagaseki, H., Hayashi, K.
    • Journal Title

      Resource Geology 56

      Pages: 133-140

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Quantitative analysis of fluid inclusions by synchrotron x-ray fluorescence : calibration of Cu and Zn in artificially made quartz inclusions2006

    • Author(s)
      Nagaseki, H., Hayashi, K.
    • Journal Title

      European Journal of Mineralogy 18(In press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] マグマ性熱水鉱床における金・銅の起源と化学的挙動に関する最近の研究2006

    • Author(s)
      小島晶二, 林謙一郎
    • Journal Title

      資源地質 56(印刷中)

    • NAID

      10017495852

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthetic fluid inclusions in the system NaCl-H_2O and NaCl-CO_2-H_2O : Dissolution temperatures of halite.2006

    • Author(s)
      Nagaseki, H., Hayashi, K.
    • Journal Title

      Resource Geology 56

      Pages: 133-140

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Quantitative analysis of fluid inclusions by synchrotron x-ray fluorescence : calibration of Cu and Zn in artificially made quartz inclusions.2006

    • Author(s)
      Nagaseki, H., Hayashi, K.
    • Journal Title

      European Journal of Mineralogy 18(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent studies on origin and chemical behavior of Au-Cu in magmatic-hydrothermal deposits.2006

    • Author(s)
      Kojima, S., Hayashi, K.
    • Journal Title

      Resource Geology 56(in press)

    • NAID

      10017495852

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthetic fluid inclusions in the systen NaCl-H_2O and NaCl-CO_2-H_2O : dissolution temperatures of halite.2006

    • Author(s)
      Nagaseki, H., Hayashi, K.
    • Journal Title

      Resource Geology 56(In press)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Quantitative analysis of fluid inclusions by synchrotron x-ray fluorescence : calibration of Cu and Zn in artificially made quartz inclusions.2006

    • Author(s)
      Nagaseki, H., Heyashi, K.
    • Journal Title

      European Journal of Mineralogy 18(In press)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] マグマ性熱水鉱床における金・銅の起源と化学的挙動に関する最近の研究2006

    • Author(s)
      小島晶二, 林 謙一郎
    • Journal Title

      資源地質 56(印刷中)

    • NAID

      10017495852

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The Bilimoia gold deposit, Kainantu, Papua New Guinia : A fault-controlled, lode-type, synorogenic tellurium-rich quartz-gold vein system2005

    • Author(s)
      Espi, J., Hayashi, K.
    • Journal Title

      Mineral Deposit Research : Meeting the Global Challenge (Mao, J. and Bierlein, F.P. eds.) (Springer) 2

      Pages: 941-944

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Contact metamorphism at the manganese deposits of the Noda-Tamagawa mine, northeast Japan : Insight from oxygen isotope data of manganese minerals.2005

    • Author(s)
      Hayashi, K.
    • Journal Title

      Mineral Deposit Research : Meeting the Global Challenge (Mao, J. and Bierlein, F.P. eds.) (Springer) 1

      Pages: 759-760

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Petrological and geochemical characteristics of the Cerro Colorado plutonic complex in the precordillera of northern Chile.2005

    • Author(s)
      Kojima, S. et al.
    • Journal Title

      Resource Geology Vol. 55

      Pages: 45-54

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Oxygen isotope study of metamorphosed manganese deposits of the Noda-Tamagawa mine, northeast Japan2003

    • Author(s)
      Hayashi, K.
    • Journal Title

      Economic Geology 98

      Pages: 181-189

    • NAID

      10002088335

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ore mineralogy, fluid inclusion, and stable isotopic characteristics of stratiform copper deposits in the coastal Cordillera of northern Chile2003

    • Author(s)
      Kojima, S., Hayashi, K.
    • Journal Title

      Mineralium Deposita 38

      Pages: 208-216

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Origin and formational environment of Noda-Tamagawa manganese ore, northeast Japan : Constraints from isotopic studies2003

    • Author(s)
      El Rhazi, M, Hayashi, K.
    • Journal Title

      Chemie der Erde(Geochemistry) 63

      Pages: 149-162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Oxygen isotope study of metamorphosed manganese deposits of the Noda-Tamagawa mine, northeast Japan.2003

    • Author(s)
      Hayashi, K.
    • Journal Title

      Economic Geology 98

      Pages: 181-189

    • NAID

      10002088335

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ore mineralogy, fluid inclusion, and stable isotopic characteristics of stratiform copper deposits in the coastal Cordillera of northern Chile.2003

    • Author(s)
      Kojima, S., Hayashi, K.
    • Journal Title

      Mineralium Deposita 38

      Pages: 208-216

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Origin and formational environment of Noda-Tamagawa manganese ore, northeast Japan : Constraints from isotopic studies.2003

    • Author(s)
      El Rhazi, M., Hayashi, K.
    • Journal Title

      Chemie der Erde (Geochemistiy) 63

      Pages: 149-162

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] Hayashi, K.: "Chemical analysis of individual fluid inclusion by synchrotron X-ray fluorescence microprobe"Geochimica et Cosmochimica Acta. 67. A141 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] El Rhazi, M.: "Origin and formational environment of Noda-Tamagawa manganes ore, northeast Japan : Constraints from isotonic studies"Chemie der Erde(Geochemistry). 63. 149-162 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Hayashi, K.: "Oxygen isotope study of metamorphosed manganese deposit of the Noda-Tamagawa mone, northeast Japan"Economic Geology. 98. 181-189 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kojima, S.: "Ore mineralogy, fluid inclusion, and stable isotopic characteristics of stratiform copper deposits in the coastal Coprdillera_of northern_Chile"Mineralium Deposita. 38. 208-216 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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