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Understandings of phase transitions of hydrous silicates at mantle conditions

Research Project

Project/Area Number 15340190
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Geochemistry/Astrochemistry
Research InstitutionThe University of Tokyo

Principal Investigator

KAGI Hiroyuki  University of Tokyo, Graduate School of Sciences, Associate Professor, 大学院・理学系研究科, 助教授 (70233666)

Co-Investigator(Kenkyū-buntansha) TSUNOMORI Fumiaki  University of Tokyo, Graduate School of Sciences, Research Associate, 大学院・理学系研究科, 助手 (60291928)
NARA Masayuki  Tokyo Medical and Dental University, Associate Professor, 教養部, 助教授 (90301168)
OKADA Taku  Institute of Solid State Physics, Research Associate, 物性研究所, 助手 (90343938)
MIZUKAMI Tomoyuki  Nagoya University, Postdoc, 大学院・環境学研究科, 博士研究員
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥16,600,000 (Direct Cost: ¥16,600,000)
Fiscal Year 2005: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2004: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 2003: ¥10,100,000 (Direct Cost: ¥10,100,000)
Keywordshydrogen bonds / interior of the earth / Raman spectroscopy / diamond anvil cell / infrared spectroscopy / in-situ observation / neutron diffraction / 含水鉱物 / ダイヤモンドアンビル
Research Abstract

Pressure response of hydrogen bonds in hydrous minerals stable at the mantle conditions can be an important scientific target for understandings of elastic properties of deep earth materials. In this research project, we have developed an instrument which enables us in-situ high-pressure spectroscopic observations of hydrous materials using a diamond anvil cell. In particular, we have modified a commercially available FTIR and Raman spectra can be observed simultaneously using the same equipment.
Furthermore, fluid inclusions of mantle origins, for example fluid inclusions in natural diamonds, were studied. Near infrared spectra of fluid inclusions demonstrated the residual pressure of fluid inclusions to be significantly high. Spectroscopic measurements with very high spatial resolutions were also developed.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (35 results)

All 2006 2005 2004 Other

All Journal Article (25 results) Book (3 results) Publications (7 results)

  • [Journal Article] Generation history of carbonado inferred from photoluminescence spectra, cathodoluminescence image and carbon isotopic composition2006

    • Author(s)
      Kagi H., Sato S., Akagi T., Kanda H.
    • Journal Title

      American Mineralogist (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Factors determining the stability, resolution, and precision of a conventional Raman spectrometer.2006

    • Author(s)
      Fukura S., Mizukami T., Odake S., Kagi H.
    • Journal Title

      Applied Spectroscopy (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Water related IR characterictics in natural fibrous diamonds2006

    • Author(s)
      Zedgenizov D.A., Shiryaev A.A., Shatsky V.S., Kagi H.
    • Journal Title

      Mineralogical Magazine (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Extended micro-Raman densimeter for CO_2 applicable to mantle-originated fluid inclusions2006

    • Author(s)
      Yamamoto J., Kagi H.
    • Journal Title

      Chemistry Letters (印刷中)

    • NAID

      10019162618

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Infrared Spectroscopic Study of Ca^(2+) Binding to Akazara Scallop Troponin C and Its Peptide Analogues of Ca^(2+) Binding Site IV.2006

    • Author(s)
      Nara M., Yumoto F., Nagata K., Tanokura M., Kagi H., Ojima T., Nishita K., Morii H.
    • Journal Title

      Vibrational Spectroscopy (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fourier Transform Infrared Spectroscopic Study on the Ca^(2+)-bound Coordination Structures of Synthetic Peptide Analogues of the Calcium-binding Site III of Troponin C.2006

    • Author(s)
      Nara M., Morii H., Yumoto F., Kagi H., Tanokura M.
    • Journal Title

      Biopolymers (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Generation history of carbonado inferred from photoluminescence spectra, cathodoluminescence image and carbon isotopic composition2006

    • Author(s)
      Kagi H., Sato S., Akagi T., Kanda H.
    • Journal Title

      American Mineralogist (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Factors determining the stability, resolution, and precision of a conventional Raman spectrometer.2006

    • Author(s)
      Fukura S., Mizukami T., Odake S., Kagi H.
    • Journal Title

      Applied Spectroscopy (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Water related IR characterictics in natural fibrous diamonds2006

    • Author(s)
      Zedgenizov D.A., Shiryaev A.A., Shatsky V.S., Kagi H.
    • Journal Title

      Mineralogical Magazine (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Extended micro-Raman densimeter for CO_2 applicable to mantle-originated fluid inclusions2006

    • Author(s)
      Yamamoto J., Kagi H.
    • Journal Title

      Chemistry Letters (in press)

    • NAID

      10019162618

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Infrared Spectroscopic Study of Ca^<2+> Binding to Akazara Scallop Troponin C and Its Peptide Analogues of Ca^<2+> Binding Site IV.2006

    • Author(s)
      Nara M., Yumoto F., Nagata K., Tanokura M., Kagi H., Ojima T., Nishita K., Morii H.
    • Journal Title

      Vibrational Spectroscopy (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fourier Transform Infrared Spectroscopic Study on the Ca^<2+> -bound Coordination Structures of Synthetic Peptide Analogues of the Calcium-binding Site III of Troponin C.2006

    • Author(s)
      Nara M., Morii H., Yumoto F., Kagi H., Tanokura M.
    • Journal Title

      Biopolymers (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Near infrared spectroscopy determines salinity and internal pressure of fluid inclusions in minerals.2006

    • Author(s)
      Kagi H., Kiyasu A., Akagi T., Nara M., Sawaki T.
    • Journal Title

      Applied Spectroscopy 60・4(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Spectroscopic analysis for organic chemistry2005

    • Author(s)
      Niitsu T., Unno M., Kagi H.
    • Journal Title

      Sankyo Shuppan

      Pages: 200-200

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] High spatial resolution photoluminescence and Raman spectroscopic measurements of a natural polycrystalline diamond, carbonado.2005

    • Author(s)
      Fukura S., Nakagawa T., Kagi H.
    • Journal Title

      Diamond and Related Materials 14

      Pages: 1950-1954

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure dependence of OH stretching mode in F-rich natural topaz and topaz-OH2005

    • Author(s)
      Komatsu K., Kagi H., Okada T., Kuribayashi T., Parise J.B., Kudoh Y.
    • Journal Title

      American Mineralogist 90

      Pages: 118-129

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure response on hydrogen bonds in potassium hydrogen carbonate and sodium hydrogen carbonate.2005

    • Author(s)
      Kagi H., Nagai T., Komatsu K., Okada T., Wada C., Loveday J.S., Parise J.B.
    • Journal Title

      Journal of Neutron Research 13

      Pages: 21-26

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components.2005

    • Author(s)
      Osawa T., Kagi H., Nakamura T., Noguchi T.
    • Journal Title

      Meteoritics and Planetary Science 40

      Pages: 71-86

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure response of Raman spectra of water and its implication to the change in hydrogen bond interactions.2005

    • Author(s)
      Okada T., Komatsu K., Kawamoto T., Yamanaka T., Kagi H.
    • Journal Title

      Spectrochimica Acta A 61

      Pages: 2423-2427

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure response on hydrogen bonds in potassium hydrogen carbonate and sodium hydrogen carbonate2005

    • Author(s)
      Kagi H., Nagai T., Komatsu K., Okada T., Wada C., Loveday J.S., Parise J.B.
    • Journal Title

      Journal of Neutron Research 13

      Pages: 21-26

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Pressure response of Raman spectra of water and its implication to the change in hydrogen bond interactions.2005

    • Author(s)
      Okada T., Komatsu K., Kawamoto T., Yamanaka T., Kagi H.
    • Journal Title

      Spectrochimica Acta (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] FTIR spectroscopic study on the binding of Mg2+ to a mutant Akazara scallop troponin C (E142Q)2004

    • Author(s)
      Nara M., Yumoto F., Nagata K., Tanokura M., Kagi H., Ojima T., Nishita K.
    • Journal Title

      Biospectroscopy, Biopolymers 74

      Pages: 77-81

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Changes in water structure based on pressure dependence of Raman OH frequency2004

    • Author(s)
      Kawamoto T., Ochiai S., Kagi H.
    • Journal Title

      Journal of Chemical Physics 120

      Pages: 5867-5670

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Carbonatitic melts in cuboid diamonds from Udachnaya kimberlite pipe (Yakutia) : evidence from vibrational spectroscopy2004

    • Author(s)
      Zedgenizov D.A., Kagi H., Shatsky V.S., Sobolev N.V.
    • Journal Title

      Mineralogical Magazine 68

      Pages: 61-73

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Effect of trace lanthanum ion on dissolution and crystal growth of calcite.2004

    • Author(s)
      Kamiya N., Kagi H., Tsunomori F., Tsuno H., Notsu K.
    • Journal Title

      Journal of Crystal Growth 267

      Pages: 635-645

    • Related Report
      2004 Annual Research Report
  • [Book] 10年使える有機スペクトル解析2005

    • Author(s)
      新津 隆士, 海野 雅史, 鍵 裕之
    • Total Pages
      200
    • Publisher
      三共出版
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 10年使える有機スペクトル解析2005

    • Author(s)
      新津隆士, 海野雅史, 鍵 裕之
    • Total Pages
      200
    • Publisher
      三共出版
    • Related Report
      2005 Annual Research Report
  • [Book] 10年使える有機スペクトル解析2005

    • Author(s)
      新津隆士, 海野雅史, 鍵 裕之
    • Publisher
      三共出版(印刷中)
    • Related Report
      2004 Annual Research Report
  • [Publications] Kagi H., Nagai T., Loveday J.S., Wada C., Parise J.B.: "Pressure-induced phase transformations of kalicinite (KHCO_3) at 2.8 GPa and local structural changes around hydrogen atoms."American Mineralogist. 88. 1446-1451 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Nagai T., Kagi H., Yamanaka T.: "Compression mechanism and variation of interatomic distance in geothite at high pressure."American Mineralogist. 88. 1423-1427 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kawakami Y., Yamamoto J., Kagi H.: "Micro-Raman densimeter for CO_2 inclusions in mantle-derived minerals."Applied Spectroscopy. 57. 1333-1339 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Zedgenizov D.A., Kagi H., Shatsky V.S., Sobolev N.V.: "Carbonatitic melts in cuboid diamonds from Udachnaya kimberlite pipe (Yakutia) : evidence from vibrational spectroscopy."Mineralogical Magazine. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Tsuno, H., Kagi, H., Takahashi Y., Akagi T., Nomura M.: "Incorporation of divalent ytterbium in synthesized crystals of calcite."Chemistry Letters. 32. 500-501 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yamamoto J., Kaneoka I., Nakai S., Kagi H., Prikho'ko V.S., Arai S.: "Extremely low ^3He/^4He and relatively low ^<40>Ar/^<36>Ar ratios observed in ultramafic mantle xenoliths from far eastern Siberia : Evidence for incorporation of recycled components into the subcontinental mantle."Chemical Geology. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 鍵 裕之: "固体地球物質の化学と同位体組成、マントル・地殻の地球化学(分担執筆)"培風館. 23-51 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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