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Activation of Small Polar Molecules by Environmentally Benign Transition Metal Catalysts

Research Project

Project/Area Number 15350055
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

KONDO Teruyuki  Kyoto Univ., Graduate School of Eng., Associate Professor, 工学研究科, 助教授 (20211914)

Co-Investigator(Kenkyū-buntansha) MITSUDO Take-aki  Kyoto Univ., Graduate School of Eng., Professor, 工学研究科, 教授 (90026344)
WADA Kenji  Kyoto Univ., Graduate School of Eng., Lecturer, 工学研究科, 講師 (10243049)
URA Yasuyuki  Kyoto Univ., Graduate School of Eng., Instructor, 工学研究科, 助手 (40335196)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥15,100,000 (Direct Cost: ¥15,100,000)
Fiscal Year 2005: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 2004: ¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 2003: ¥8,300,000 (Direct Cost: ¥8,300,000)
KeywordsEnvironmentally Benign Catalyst / Ruthenium Catalyst / Sulfenamides / Cocycloaddition / Codimerization / Carbon-Carbon Bond Cleavage / Cyclobutenones / Aqua Complex / 水 / アルキン / アルケン / 共三量化反応 / [4+2]付加環化反応 / Diels-Alder反応 / フェノール / オキソシクロヘキサジエニル / 酸化的環化反応 / 2,3-ジヒドロフラン / アレーン錯体 / p-キノン錯体 / ピリジル錯体
Research Abstract

Since we have already found that among group 8-10 transition metal complexes, low-valent ruthenium complexes especially show high affinity to heteroatoms such as N, S, and O atoms, characteristic activation of small polar molecules by ruthenium catalysts was investigated. As a result, we have succeeded in developing the following novel ruthenium-catalyzed carbon-carbon and carbon-heteroatom bond forming reactions ; 1)highly regio- and stereoselective addition of sulfenamides to electron-deficient alkynes leading to polyfunctional alkenes, 2)formal [4+2] cycloaddition of alkynes with electron-deficient alkenes to cyclohexenedicarboxylates via isomerization of alkynes and successive Diels-Alder reaction, 3)reconstructive synthesis of 2-pyranones, cyclopentenes, and cyclohexenones via carbon-carbon bond cleavage of cyclobutenones, 4)[2+2+2] cocyclization of three different alkynes (dimethyl acetylenedicarboxylate, 1-decyne and 3-hexyne), 5)regio- and stereoselective codimerization of different alkenes (2-norbornenes with acrylic compounds, and dihydrofurans with α,β-unsaturated esters).
In addition, we succeeded in preparation of various Ru(0) complexes via selective ligand displacement of Ru(η^6-1,3,5-cyclooctatriene)(η^2-dimethyl fumarate)_2 (1), which was originally synthesized in our laboratory in 1999. Further study revealed that the stoichiometric reaction of 1 with phenol gave novel Ru(II) phenolate complexes, while the reaction of 1 with water in the presence of 1,2-bis(diphenylphosphino)ethane (dppe) gave a novel chiral Ru(0) aqua complex, Ru(η^2-dppe)(η^2-dimethyl fumarate)_2(H_2O) (2). Optical resolution of rac-2 was successfully performed by HPLC equipped with a chiral column. On the basis of the VT NMR data and DFT study, the behavior of the coordinated water (rotation and inversion) was disclosed.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (52 results)

All 2006 2005 2004 2003 Other

All Journal Article (37 results) Book (7 results) Patent(Industrial Property Rights) (3 results) Publications (5 results)

  • [Journal Article] 特異的機能を有する新規ルテニウム錯体触媒系の開発-新規有機材料の基盤となるモノマー合成-2006

    • Author(s)
      近藤輝幸
    • Journal Title

      Polyfile 43・2

      Pages: 21-27

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 水を反応剤として用いる有機化学反応2006

    • Author(s)
      近藤輝幸
    • Journal Title

      化学と教育 54・4

      Pages: 212-213

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of Novel Catalytic Performance of Ruthenium Complexes : Synthesis of New and Important Organic Monomers2006

    • Author(s)
      Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Polyfile Vol.43, No.2

      Pages: 21-27

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Organic Reactions Using Water as an Effective Reagent2006

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Chemistry & Education Vol.54, No.4

      Pages: 212-213

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 特異的機能を有する新規ルテニウム錯体触媒系の開発-新規有機材料の基盤となるモノマー合成-2006

    • Author(s)
      近藤 輝幸
    • Journal Title

      Polyfile 43・504

      Pages: 21-27

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis, Structure and Reactivity of Novel Ruthenium(II) Phenolate Complexes2005

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Organometallics 24・5

      Pages: 905-910

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Ruthenium-Complex-Catalyzed Regio- and Stereoselective Linear Codimerization of 2-Norbornenes with Acrylic Compounds2005

    • Author(s)
      Yasuyuki Ura
    • Journal Title

      The Journal of Organic Chemistry 70・17

      Pages: 6623-6628

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed [2+2+2] Cycloaddition of Three Different Alkynes2005

    • Author(s)
      Yasuyuki Ura
    • Journal Title

      Journal of Molecular Catalysis A : Chemical 239・1-2

      Pages: 166-171

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Synthesis of 2-Alkylidenetetrahydrofurans by Ru-Catalyzed Regio- and Stereoselective Codimerization of Dihydrofurans with α,β-Unsaturated Esters2005

    • Author(s)
      Hiroshi Tsujita
    • Journal Title

      Chemical Communications 40号

      Pages: 5100-5102

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Reconstructive Synthesis of Functional Organic Molecules via Cleavage of Carbon-Carbon Bonds2005

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Chemistry Letters 34・11

      Pages: 1462-1467

    • NAID

      10016843598

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Preparation and Characterization of Chiral Zerovalent Organoruthenium Aqua Complexes2005

    • Author(s)
      Yasuyuki Ura
    • Journal Title

      Organometallics 24・23

      Pages: 5724-5731

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Synthesis of Functionalized Hydroquinones via [Cp^*RuCl_2]_2-Catalyzed Cocyclization of Alkynes, α,β-Unsaturated Carbonyl Compounds, and Carbon Monoxide2005

    • Author(s)
      Takahide Fukuyama
    • Journal Title

      Organic Letters 7・26

      Pages: 5781-5783

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis, Structure, and Reactivity of Novel Ruthenium(II) Phenolate Complexes2005

    • Author(s)
      Teruyuki Kondo, Fumiaki Tsunawaki, Yasuyuki Ura, Kazuo Sadaoka, Tomomichi Iwasa, Kenji Wada, Take-aki Mitsudo
    • Journal Title

      Organometallics Vol.24, No.5

      Pages: 905-910

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium Complex-Catalyzed Regio- and Stereo-selective Linear Codimerization of 2-Norbornenes with Acrylic Compounds2005

    • Author(s)
      Yasuyuki Ura, Hiroshi Tsujita, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      The Journal of Organic Chemistry Vol.70, No.17

      Pages: 6623-6628

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of 2-Alkylidenetetrahydrofurans by Ru-Catalyzed Regio- and Stereoselective Codimerization of Dihydrofurans with α,β-Unsaturated Esters2005

    • Author(s)
      Hiroshi Tsujita, Yasuyuki Ura, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Chemical Communications No.40

      Pages: 5100-5102

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Reconstructive Synthesis of Functional Organic Molecules via Cleavage of Carbon-Carbon Bonds2005

    • Author(s)
      Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Chemistry Letters Vol.34, No.11

      Pages: 1462-1467

    • NAID

      10016843598

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preparation and Characterization of Chiral Zerovalent Organoruthenium Aqua Complexes2005

    • Author(s)
      Yasuyuki Ura, Fumiaki Tsunawaki, Kenji Wada, Masashi Shiotsuki, Teruyuki Kondo, Syuhei Yamaguchi, Hideki Masuda, Atsushi Ohnishi, Take-aki Mitsudo
    • Journal Title

      Organometallics Vol.24, No.23

      Pages: 5724-5731

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Functionalized Hydroquinones via [Cp^*RuCl_2]_2-Catalyzed Cocyclization of Alkynes, α,β-Unsaturated Carbonyl Compounds, and Carbon Monoxide2005

    • Author(s)
      Takahide Fukuyama, Ryo Yamaura, Yuki Higashibeppu, Takahiro Okamura, Ilhyong Ryu, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Organic Letters Vol.7, No.26

      Pages: 5781-5783

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Addition of Sulfenamides to Alkynes Leading to Selective Synthesis of Polyfunctional Alkenes2004

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Tetrahedron Letters 45・7

      Pages: 1469-1471

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Novel Organic-Inorganic Hybrid Cages via Cobalt-Catalyzed Cyclotrimerization of Dimethylethynylsilyl Groups on a Silsesquioxane2004

    • Author(s)
      Kenji Wada
    • Journal Title

      Chemistry Letters 33・9

      Pages: 1218-1219

    • NAID

      10013528200

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] ルテニウム錯体触媒によるケミカルズの合成と変換2004

    • Author(s)
      光藤武明
    • Journal Title

      PETROTECH 27・9

      Pages: 692-697

    • NAID

      10016752048

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Formal [4+2] Cycloaddition of Alkynes with Alkenes : Formation of Cyclohexenedicarboxylates via Isomerization of Alkynes and Successive Diels-Alder Reaction2004

    • Author(s)
      Masashi Shiotsuki
    • Journal Title

      Journal of Organometallic Chemistry 689・20

      Pages: 3168-3172

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Ru- and Rh-Catalyzed C-C Bond Cleavage of Cyclobutenones : Reconstructive and Selective Synthesis of 2-Pyranones, Cyclopentenes, and Cyclohexenones2004

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Angewandte Chemie International Edition 43・40

      Pages: 5369-5372

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ru(η^6-1,3,5-cyclooctatriene)(η^2-dimethyl fumarate)_2 : A Novel, Versatile Zerovalent Ruthenium Complex with Electron-Deficient Olefinic Ligands2004

    • Author(s)
      Take-aki Mitsudo
    • Journal Title

      Journal of Organometallic Chemistry 689・24

      Pages: 4530-4539

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Ruthenium-Catalyzed Addition of Sulfenamides to Alkynes Leading to Selective Synthesis of Polyfunctional Alkenes2004

    • Author(s)
      Teruyuki Kondo, Atsushi Baba, Yumiko Nishi, Take-aki Mitsudo
    • Journal Title

      Tetrahedron Letters Vol.45, No.7

      Pages: 1469-1471

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Novel Organic-Inorganic Hybrid Cages via Cobalt-Catalyzed Cyclotrimerization of Dimethylethynylsilyl Groups on a Silsesquioxane2004

    • Author(s)
      Kenji Wada, Takuro Yamasaki, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Chemistry Letters Vol.33, No.9

      Pages: 1218-1219

    • NAID

      10013528200

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium Complex-Catalyzed Synthesis and Conversion of Industrially Important Chemicals2004

    • Author(s)
      Take-aki Mitsudo
    • Journal Title

      PETROTECH Vol.27, No.9

      Pages: 692-697

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Formal [4+2] Cycloaddition of Alkynes with Alkenes : Formation of Cyclohexenedicarboxylates via Isomerization of Alkynes and Successive Diels-Alder Reaction2004

    • Author(s)
      Masashi Shiotsuki, Yasuyuki Ura, Takashi Ito, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Journal of Organometallic Chemistry Vol.689, No.20

      Pages: 3168-3172

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ru- and Rh-Catalyzed C-C Bond Cleavage of Cyclobutenones : Reconstructive and Selective Synthesis of 2-Pyranones, Cyclopentenes, and Cyclohexenones2004

    • Author(s)
      Teruyuki Kondo, Yoshinori Taguchi, Yushi Kaneko, Masatsugu Niimi, Take-aki Mitsudo
    • Journal Title

      Angewandte Chemie International Edition Vol.43, No.40

      Pages: 5369-5372

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ru(η^6-1,3,5-cyclooctatriene)(η^2-dimethyl fumarate)_2 : A Novel, Versatile Zerovalent Ruthenium Complex with Electron-Deficient Olefinic Ligands2004

    • Author(s)
      Take-aki Mitsudo, Yasuyuki Ura, Teruyuki Kondo
    • Journal Title

      Journal of Organometallic Chemistry Vol.689, No.24

      Pages: 4530-4539

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates2004

    • Author(s)
      Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Ruthenium in Organic Synthesis (Wiley-VCH)

      Pages: 129-151

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed Reactions with CO and CO_22004

    • Author(s)
      Take-aki Mitsudo, Teruyuki Kondo
    • Journal Title

      Ruthenium in Organic Synthesis (Wiley-VCH)

      Pages: 277-307

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ru-and Rh-Catalyzed C-C Bond Cleavage of Cyclobutenones : Reconstructive and Selective Synthesis of 2-Pyranones, Cyclopentenes, and Cyclohexenones2004

    • Author(s)
      Teruyuki Kondo
    • Journal Title

      Angewandte Chemie International Edition 43・40

      Pages: 5369-5372

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Novel Organic-Inorganic Hybrid Cages via Cobalt-Catalyzed Cyclotrimerization of Dimethylethynylsilyl Groups on a Silsesquioxane2004

    • Author(s)
      Kenji, Wada
    • Journal Title

      Chemistry Letters 33・9

      Pages: 1218-1219

    • NAID

      10013528200

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Novel Zerovalent Ruthenium η^6-Arene Complexes via Direct Displacement of a 1,3,5-Cyclooctatriene Ligand by Arenes2003

    • Author(s)
      Yasuyuki Ura
    • Journal Title

      Organometallics 22・9

      Pages: 1863-1867

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Novel Zerovalent Ruthenium η^6-Arene Complexes via Direct Displacement of a 1,3,5-Cyclooctatriene Ligand by Arenes2003

    • Author(s)
      Yasuyuki Ura, Masashi Shiotsuki, Kazuo Sadaoka, Toshiaki Suzuki, Teruyuki Kondo, Take-aki Mitsudo
    • Journal Title

      Organometallics Vol.22, No.9

      Pages: 1863-1867

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ruthenium-Catalyzed [2+2+2] Cycloaddition of Three Different Alkynes

    • Author(s)
      Yasuyuki Ura, Yoshitaka Sato, Hiroshi Tsujita, Teruyuki Kondo, Misako Imachi, Take-aki Mitsudo
    • Journal Title

      Journal of Molecular Catalysis A : Chemical Vol.239, No.1-2

      Pages: 166-171

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Ruthenium in Organic Synthesis (Chapter 5 : Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates)2004

    • Author(s)
      Teruyuki Kondo
    • Publisher
      Wiley-VCH
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Ruthenium in Organic Synthesis (Chapter 11 : Ruthenium-Catalyzed Reactions with CO and CO_2)2004

    • Author(s)
      Take-aki Mitsudo
    • Publisher
      Wiley-VCH
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 有機合成のための触媒反応1032004

    • Author(s)
      近藤輝幸
    • Publisher
      東京化学同人
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 第5版 実験化学講座21(有機遷移金属化合物・超分子錯体)2004

    • Author(s)
      近藤輝幸
    • Publisher
      丸善(株)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates, (Chapter5),"Ruthenium in Organic Synthesis", pp129-151(New York, Shun-ichi Murahashi(Ed.))2004

    • Author(s)
      Teruyuki Kondo
    • Total Pages
      23
    • Publisher
      Wiley-VCH
    • Related Report
      2004 Annual Research Report
  • [Book] 第5版「実験化学講座21(有機遷移金属化合物・超分子錯体)」7章2節、pp206-227((社)日本化学会編)2004

    • Author(s)
      近藤輝幸
    • Total Pages
      22
    • Publisher
      丸善(株)
    • Related Report
      2004 Annual Research Report
  • [Book] 有機金属反応剤ハンドブック-^3Li から ^<83>Bi まで2003

    • Author(s)
      光藤武明
    • Publisher
      化学同人
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 2-アルキリデンテトラヒドロフラン誘導体及びその製造方法2005

    • Inventor(s)
      光藤武明, 浦 康之, 近藤輝幸, 和田健司, 辻田 寛
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Number
      2005-243027
    • Filing Date
      2005-08-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] エナミド及びその製造方法2005

    • Inventor(s)
      光藤武明, 浦 康之, 近藤輝幸, 和田健司, 辻田 寛
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Number
      2005-247842
    • Filing Date
      2005-08-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] エナミド及びその製造方法2005

    • Inventor(s)
      光藤 武明, 浦 康之, 近藤 輝幸, 和田 健司, 辻田 寛
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Number
      2005-247842
    • Filing Date
      2005-08-29
    • Related Report
      2005 Annual Research Report
  • [Publications] Yasuyuki Ura: "Synthesis and Structures of Novel Zerovalent Ruthenium p-Quinone Complexes and a Bimetallic p-Biquinone Complex"Organometallics. 22・1. 77-82 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masashi Shiotsuki: "Synthesis and Structure of Novel Zerovalent Ruthenium Complexes with Three Pyridine Ligands or Tridentate Pyridyl Ligands"Organometallics. 22・6. 1332-1339 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yasuyuki Ura: "Synthesis of Novel Zerovalent Ruthenium η^6-Arene Complexes via direct Displacement of a 1,3,5-Cyclooctatriene Ligand by Arenes"Organometallics. 22・9. 1863-1867 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Teruyuki Kondo: "Ruthenium Complex-Catalyzed Oxidative Cyclization of 4-Penten-1-ols"Chemistry Letters. 32・1. 24-25 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Teruyuki Kondo: "Ruthenium-Catalyzed Addition of Sulfenamides to Alkynes Leading to Selective Synthesis of Polyfunctional Alkenes"Tetrahedron Letters. 45・7. 1469-1471 (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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