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Height Control of Metallic Nanoislands by Quantum Confinement

Research Project

Project/Area Number 15360018
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIRAYAMA Hiroyuki  Tokyo Institute of Technology, Interdisciplinary Graduate School of Science & Engineering, Professor, 大学院・総合理工学研究科, 教授 (60271582)

Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥14,400,000 (Direct Cost: ¥14,400,000)
Fiscal Year 2005: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2004: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2003: ¥11,500,000 (Direct Cost: ¥11,500,000)
Keywordsquantum confinement / surfaces & interfaces / nanostructures / optical second harmonic generation / scanning tunneling microscope / surface electronic states / ナノ島 / 銀 / シリコン表面 / 光第二高調波発
Research Abstract

We studied the nucleation of flat-top, nano Ag islands of a uniform height at clean Si(111)7x7 and H-terminated Si(111) surfaces. At these surfaces, Ag islands of atomically flat-top grow. In the Ag islands, the sp-band electrons are confined along surface normal direction, between the Ag island surface and Ag/Si interface to reveal quantum well states. In this study, we elucidated the relation between the height and the quantized electronic states of the confined electrons along surface normal direction using optical second harmonic generation (SHG) intensity oscillation and scanning tunneling microscope (STM)/ scanning tunneling spectroscopy (STS). We also calculated the quantum well states numerically by two-band model. The calculation agreed well with the experimental results.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (19 results)

All 2006 2005 2004 2003 Other

All Journal Article (15 results) Book (2 results) Publications (2 results)

  • [Journal Article] Size Control of Nano-structures by Quantum Confinement2006

    • Author(s)
      H.Hirayama
    • Journal Title

      Chapter 7 of Nano-Materials Research Toward Application (ed. H.Hosono & Y.Mishima) (Elsevier Science Publisher) (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Resonant Optical Second Harmonic Generation From Quantum Well states in Ag Films on Si(111)7x7 Surfaces2005

    • Author(s)
      M.Watai, H.Hirayama
    • Journal Title

      Physical Review B 72

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Resonant optical second-harmonic generation from Quantum well states in Ag films on Si(111)7x7 surfaces2005

    • Author(s)
      M.Watai, H.Hirayama
    • Journal Title

      Physical Review B72

      Pages: 85435-85435

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Two-photon resonance in optical second harmonic generation From quantum well states in ultra-thin Ag films grown on Si(111) surfaces2005

    • Author(s)
      H.Hirayama, M.Watai
    • Journal Title

      Surface Science (accepted)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Confinement of One-Dimensional Electrons in Dimer Row Segments at Ge/Si(001) Surfaces2004

    • Author(s)
      H.Hirayama
    • Journal Title

      Science & Technology of Advanced Materials 5

      Pages: 517-520

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Si表面の電子定在波2004

    • Author(s)
      平山 博之
    • Journal Title

      日本学術振興会なのプローブテクノロジー第167委員会第36回研究会報告

      Pages: 6-10

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Confinement of One-Dimensional Electrons in dimer Row Segments at Ge/Si(001) Surfaces2004

    • Author(s)
      H.Hirayama
    • Journal Title

      Science & Technology of Advanced Materials vol.5

      Pages: 517-520

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Confinement of one-dimensional electrons in dimmer row segments at Ge/Si(001) surfaces2004

    • Author(s)
      H.Hirayama
    • Journal Title

      Science & Technology of Advanced Materials 5

      Pages: 517-520

    • Related Report
      2004 Annual Research Report
  • [Journal Article] シリコン表面における電子定在波2004

    • Author(s)
      平山 博之
    • Journal Title

      日本学術振興会第167委員会 第36回研究会資料

      Pages: 6-10

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Change of Optical Second Harmonic Generation Intensity during Ag Deposition on Si(111)7x7 and Si(111)√<3>x√<3>-Ag Surfaces2003

    • Author(s)
      H.Hirayama, A.Yamasaki, T.Kwawata
    • Journal Title

      Surface Science 532-535

      Pages: 922-927

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Change of Optical Second Harmonic Generation Intensity during Ag Deposition on Si(111)7x7 and Si(111)【square root】3x【square root】3-Ag surfaces2003

    • Author(s)
      H.Hirayama, A.Yamasaki, T.Kawata
    • Journal Title

      Surface Science vol.532-535

      Pages: 922-927

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Barrier Height Imaging of Si(111)3x1-Ag reconstructed surfaces

    • Author(s)
      T.Furuhashi, Y.Ohshima, H.Hirayama
    • Journal Title

      Applied Surface Science (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Two-photon Resonance in Optical Second Harmonic Generation from Quantum Well States in Ultra-thin Ag Films grown on Si(111) Surfaces

    • Author(s)
      H.Hirayama, M.Watai
    • Journal Title

      Surface Science (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Barrier Height Imaging of Si(111)3x1-Ag reconstructed surfaces

    • Author(s)
      T.Furuhashi, Y.Ohshima, H.Hirayama
    • Journal Title

      Applied Surface Science (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Two-photon Resonance in Optical Second Harmonic Generation from Quantum Well States in Ultra-thin Ag Films grown on Si(111) Surfaces

    • Author(s)
      H.Hirayama, M.Watai
    • Journal Title

      Surface Science (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Nano-materials research toward applications2006

    • Author(s)
      H.Hirayama et al.
    • Publisher
      Elsevier Science Publisher(印刷中)
    • Related Report
      2005 Annual Research Report
  • [Book] Size Control of Nano-structures by Quantum Confinement (Chapter 7 of "Nano-Materials Research Toward Applications" ed. H.Hosono & Y.Mishima)

    • Author(s)
      H.Hirayama
    • Publisher
      Elsevier Science Publisher(印刷中)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] H.Hirayama, A.Yamazaki, T.Kawata: "Changes of optical second harmonic generation intensity during Ag deposition on Si(111)7x7 and Si(111)√3x√3-AG surfaces"Surface Science. 532-535. 922-927 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Hirayama: "Confinement of One-Dimensional Electrons in Dimer Row Segments at Ge/Si(001) Surfaces"Science & Technology of Advanced Materials. 5(印刷中). (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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