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PIEZOELECTRIC EFFECT OF PUE FILMS CONTROLLED BY CARBON NANOTUBES (CNTs) AND ITS ACTUATION MECHANISM

Research Project

Project/Area Number 15360177
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNARA NATIONAL COLLEGE OF TECHNOLOGY

Principal Investigator

KYOKANE Jun  NARA NATIONAL COLLEGE OF TECHNOLOGY, ELECTRICAL ENGINEERING, PROFESSOR, 電気工学科, 教授 (50043469)

Co-Investigator(Kenkyū-buntansha) HAYAKAWA Yasuhiro  NARA NATIONAL COLLEGE OF TECHNOLOGY, CONTROLL ENGINEERING, ASOCIATE PROFESSOR, 電子制御工学科, 助教授 (50180956)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 2005: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2004: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2003: ¥3,400,000 (Direct Cost: ¥3,400,000)
Keywordspolyurethane elastomer films / electrostriction effect / actuators / monomorph type / carbon nanotube (CNT) and its derivatives / control of morphology / space charge measurement / piezoelectric effect / PUEアクチュエータ / 空間電化測定 / 分子構造性御 / ユニモルフ型アクチュエータ / 空間電荷
Research Abstract

The results of this research are summarized as follows.
1.We proposed their application to moving devices such as an actuator without ionic solvents using the electrostriction effect of polyurethane elastomer (PUE) films.
2.The actuators are of monomorph type fabricated by PUE film and metal electrodes evaporated at same thickness (200nm) on the both film surfaces.
3.Since these actuators work at high voltages more than 1 KV, we controlled the molecular structure of the film by doping carbon nanotubes (CNTs) derivative into PUE so that the actuators could operate under a lower voltage.
4.The bending displacement of the CNTs-doped PUE actuator varied with the square of the electric field. All samples of PUE actuator bent in the direction of the cathode electrode independent of the metal materials. They exhibited a polarity effect.
5.The bends of these actuators were larger than normal actuators by doping CNTs and its operating voltage took place at 300 V. Moreover, the bending displacement strongly depends on the number of hydroxyl groups of CNTs.
6.The induced forces of the CNTs-doped actuator increased in proportion to applied voltage, and significantly depended on film thickness. The actuator with a film thickness of 200 μm had the strongest force and could lift up to a load of 700 mg.
7.In order to clear the bending mechanism of actuators, we measured the space charges of the various kinds of PUE films (normal, fullerenol and CNTs-doped films) by using the pulsed electro-acoustic method.
8.We have found that molecule chains are attracted each other by electric force due to the positive and negative charges at cathode electrode from measurement of space charge based on the polar groups of molecular chain. As a result, it was concluded that the all PUE film actuators always bend in the direction of cathode electrode.
9.These PUE films also appeared the piezoelectric effect.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (35 results)

All 2005 2004 2003 Other

All Journal Article (27 results) Book (2 results) Publications (6 results)

  • [Journal Article] Space Charge Characteristics of Fullerenol and Carbon Nanotube Doped Polyurethane Elastomer (PUE) Actuators.2005

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, M.Fukuma
    • Journal Title

      Proceeding of 2005 International Symposium on Electrical Insulating Materials (ISEIM 2005) A4-9

      Pages: 255-258

    • NAID

      110006226502

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Polyurethane Elastomer (PUE) Actuators.2005

    • Author(s)
      N.Tsujimoto, M.Ishida, J.Kyokane, M.Fukuma
    • Journal Title

      Journal of the Society of Electrical Materials Engineering Vol.14

      Pages: 273-276

    • NAID

      120006881687

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Development of a Hybrid Element by using Sponge Core Soft Rubber Actuator.2005

    • Author(s)
      Y Hayakawa, S. R. Pandian
    • Journal Title

      Proceeding of 2005 IEEE International Conference on Robotics and Automation

      Pages: 540-540

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Basic Characteristics of a Pneumatic Sponge Core Soft Rubber Actuator and Application to a Body Protection System2005

    • Author(s)
      Y.Hayakawa, S.Hirota
    • Journal Title

      Proceeding of the 8th International Symposium on Fluid Control, Measurement and Visualization 13-2

      Pages: 258-259

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] PUEソフトアクチュエターの低電界駆動化2005

    • Author(s)
      石田 守, 京兼 純, 福間真澄
    • Journal Title

      電子情報通信学会技術研究報告 0ME2005-59

      Pages: 35-38

    • NAID

      110004046098

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] PUE ソフトアクチュエターの低電界駆動化と空間電荷測定2005

    • Author(s)
      石田 守, 京兼 純, 福間真澄
    • Journal Title

      第6回計測自動制御学会システムインテグレーショソ部門講演会 1HZ-2

      Pages: 131-131

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Polyurethane Elastomer (PUE) Actuators2005

    • Author(s)
      N.Tsujimoto, M.Ishida, J.Kyokane, M.Fukuma
    • Journal Title

      Journal of the Society Electrical Materials Engineering Vol.14

      Pages: 273-276

    • NAID

      120006881687

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Fullerenol and Carbon Nanotube Doped Polyurethane Elastomer Actuators2005

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, M.Fukuma
    • Journal Title

      International Symposium on Electrical Insulating Materials ((ISEIM 2005), Kitakyushu, Japan)

      Pages: 255-258

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Polyurethane Elastomer Actuators2005

    • Author(s)
      N.Tsujimoto, M.Ishida, J.Kyokane, M.Fukuma
    • Journal Title

      The 4th International Conference on Electrical and Electronic Material Engineering ((ICEME 2005), Osaka, Japan)

      Pages: 273-276

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of a Hybrid Element by using Sponge Core Soft Rubber Actuator.2005

    • Author(s)
      Y.Hayakawa, S.R.Randian
    • Journal Title

      Proceeding of 2005 IEEE International Conference on Robotics and Automation

      Pages: 540-540

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Basic Characteristics of a Pneumatic Sponge Core Soft Rubber Actuator and Application to a Body Protection System.2005

    • Author(s)
      Y.Hayakawa, S.Hirota
    • Journal Title

      Proceeding of the 8th International Symposium on Fluid Control, Measurement and Visualization 13-2

      Pages: 258-259

    • Related Report
      2005 Annual Research Report
  • [Journal Article] PUEソフトアクチュエターの低電界駆動化2005

    • Author(s)
      石田 守, 京兼 純, 福間真澄
    • Journal Title

      電子情報通信学会技術研究報告 OME2005-59

      Pages: 35-38

    • NAID

      110004046098

    • Related Report
      2005 Annual Research Report
  • [Journal Article] PUEソフトアクチュエターの低電界駆動化と空間電荷測定2005

    • Author(s)
      石田 守, 京兼 純, 福間真澄
    • Journal Title

      第6回計測自動制御学会システムインテグレーション部門講演会 1H2-2

      Pages: 131-131

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Actuator Using Electrostriction Effect of Fullerenol-Doped Polyurethane Elastomer (PUE) Films2004

    • Author(s)
      J.Kyokane, K.Tsujimoto, T.Ueda, M.Fukuma
    • Journal Title

      IEICE Transactions on Electronics Vol.E87-C

      Pages: 136-141

    • NAID

      110003214829

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Fullerenol and Carbon Nanotube-Doped Polyurethane Elastomer (PUE) Actuators2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, M.Fukuma
    • Journal Title

      IEICE Transactions on Electronics Vol.E87-C

      Pages: 2125-2128

    • NAID

      110006226502

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Actuator Using Electrostriction Effect of Carbon Nanotubes (CNTs)-Doped Polyurethane Elastomer Films2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, Y.Yanagisawa, T.Ueda, M.Fukuma
    • Journal Title

      The 3rd International Symposium on Organic Molecular Electronics ((ISOME 2004), Kyoto, Japan)

      Pages: 73-73

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Actuator Using Electrostriction Effect of Fullerenol-doped Polyurethane Elastomer Films2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, T.Ueda, M.Fukuma
    • Journal Title

      The Second International Conference on Artificial Muscles-Development to Biomimetic System Engineering- (Osaka, Japan)

      Pages: 55-58

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Actuation Mechanism on CNTs doped Polyurethane Elastomer Films2004

    • Author(s)
      N.Tsujimoto, J.Kyokane, Y.Yanagisawa, M.Fukuma
    • Journal Title

      International Symposium on Organic and Inorganic Electronic Materials and Related Nano-technology (Niigata, Japan)

      Pages: 155-155

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] SPACE CHARGE CHARACTERISTICS OF FULLERENOL AND CARBON NANOTUBE DOPED POLYURETHAN ELASTOMER ACTUATORS2004

    • Author(s)
      N.Tsujimoto, M.Ishida, J.Kyokane, M.Fukuma
    • Journal Title

      The 6th International Conference on Nano-Molecular Electronics ((ICNME 2004), Kobe, Japan)

      Pages: 174-175

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Actuation Mechanism on CNTs doped Polyurethane Elastomer Films2004

    • Author(s)
      N.Tsujimoto, J.Kyokane, Y.Yanagisawa, M.Fukuma
    • Journal Title

      International Conference on the Science and Technology of Synthetic Metals ((ICSM 2004), Wollongong, Australia) Tues-P160

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Space Charge Characteristics of Fullerenol- and Carbon Nanotube-Doped Polyurethane Elastomer (PUE) Actuators2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, M.Fukuma
    • Journal Title

      IEICE Transactions on Electronics Vol.E87-C

      Pages: 2125-2128

    • NAID

      110006226502

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Actuator Using Electrostriction Effect of Carbon Nanotube (CNTs) Doped Polyurethane Elastomer Films2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, Y.Yanagisawa, M.Fukuma
    • Journal Title

      The 3rd International Symposium on Organic Molecular Electronics (ISOME 2004) OD12

      Pages: 73-73

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Actuator Using Electrostriction Effect of Fullerenol-Doped Polyurethane Elastomer (PUE) Films2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, Y.Yanagisawa, T.Ueda
    • Journal Title

      The Second Conference on Artificial Muscles -Biomimetic System Engineering-

      Pages: 54-57

    • NAID

      110003214829

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Actuation Mechanism of Carbon Nanotubes (CNTs)-Doped Polyurethane Elastomer (PUE) Films2004

    • Author(s)
      J.Kyokane, N.Tsujimoto, M.Ishida, Y.Yanagisawa, T.Ueda
    • Journal Title

      The International Coference on the Science and Technology of Synthetic Metals (ICSM 2004) ME23P

      Pages: 146-146

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Actuation Mechanism on CNTs-Doped Polyurethane Elastomer (PUE) Films2004

    • Author(s)
      N.Tsujimoto, J.Kyokane, M.Ishida, M.Fukuma
    • Journal Title

      The International Symposium on Organic and Inorganic Electronic Materials and Related Materials (EM-NANO'04) P-67

      Pages: 155-155

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Space Charge Characteristics of Fullerenol and (CNTs)-Doped Polyurethane Elastomer (PUE) Actuators2004

    • Author(s)
      N.Tsujimoto, J.Kyokane, M.Ishida, M.Fukuma
    • Journal Title

      The 6th International Conference on Nano-Molecular Electronics (ICNME 2004) PA-27

      Pages: 174-175

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Actuator Mechanism and Piezoelectric Effect of Fullerenol doped Polyurethane Elastomer (PUE)2003

    • Author(s)
      Y.Nakama, K.Tokugi, J.Kyokane, T.Ueda, K.Yoshino
    • Journal Title

      Synthetic Metals Vol.135-136

      Pages: 749-750

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 「研究成果報告書概要(和文)」より2005

    • Author(s)
      京兼純(分担執筆)(第3版)
    • Total Pages
      830
    • Publisher
      高分子学会く朝倉書店)
    • Related Report
      2005 Final Research Report Summary
  • [Book] 高分子辞典(第3版)2005

    • Author(s)
      京兼 純(分担執筆)
    • Total Pages
      830
    • Publisher
      高分子学会(朝倉書店)
    • Related Report
      2005 Annual Research Report
  • [Publications] J.Kyokane, K.Tsujimoto, T.Ueda, Y.Yanagisawa, M.Fukuma: "Actuator Using Electrostriction Effect of Fullerenol-Doped Polyurethane Elastomer (PUE) Films"IEICE Transactions on Electronics. Vol.E87-C. 136-141 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 京兼 純, 柳沢佑輝, 辻本直生, 上田 敦, 福間真澄: "PUEフイルムの電歪効果と静電アクチュエータの開発"平成15年電気関係学会開西支部連合大会シンポジウム. S4-5. S21 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 京兼 純, 柳沢佑輝, 辻本直生, 上田 敦, 福間真澄: "CNT添加PUEフイルムのアクチュエション機構"平成15年電気関係学会関西支部連合大会. G7-24. G152 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 柳沢佑輝, 京兼 純: "低電界駆動型PUEアクチュエータの開発"第2回21世紀連合シンポジウム-科学技術と人間-. III-0-16. 215-216 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 辻本直生, 柳沢佑輝, 京兼 純, 上田 敦, 福間真澄: "CNT添加PUEフイルムのアクチュエション機構(II)"平成16年電気学会全国大会. 2-113. 124 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 京兼 純, 辻本直生, 柳沢佑輝, 上田 敦, 福間真澄: "CNT添加PUEフイルムのアクチュエション機構と空間電荷特性(II)"第51回春季応用物理学関係連合講演会. 30p-ZW-4. 1424 (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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