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Alloy Design and Microstructural Control in Ni-based Multi-Intermetallic In-situ Composite Materials

Research Project

Project/Area Number 15360373
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionOsaka Prefecture University

Principal Investigator

TAKASUGI Takayuki  Osaka Prefecture University, Graduate School of Engineering, Department of Materials Science, Professor, 工学研究科, 教授 (20108567)

Co-Investigator(Kenkyū-buntansha) KANENO Yasuyuki  Osaka Prefecture University, Graduate School of Engineering Department of Materials Science, Research Associate, 工学研究科, 助手 (50214482)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥15,500,000 (Direct Cost: ¥15,500,000)
Fiscal Year 2005: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 2004: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2003: ¥11,100,000 (Direct Cost: ¥11,100,000)
KeywordsIntermetallic compound / Superalloy / Microstructural stability / Thermal stability / Multi-phase alloy / Ni_3Al / Geometrically close packed phase / Ni_3V / Ni_3T / Ni_3Ti / Ni3Al / Ni3Ti / Ni3V
Research Abstract

Using Ni_3Al-Ni_3Nb-Ni_3Ti, Ni_3Al-Ni_3Ti-Ni_3V, Ni_3Al-Ni_3Nb-Ni_3V and Ni_3Si-Ni_3Nb-Ni_3Ti pseudo-ternary alloy systems, the development of multi-intermetallic in-situ composite materials as a candidate of new high-temperature structural materials was performed on alloy design and microstructure control. The following results were obtained from the present study.
(1)It was found dual multi-phase microstructure composed of L1_2 and D0_<22> phases was developed in Ni_3Al-Ni_3Ti-Ni_3V and Ni_3Al-Ni_3Nb-Ni_3V pseudo-ternary alloy systems, and had extremely fine microstructure and highly coherent interface structures not only between the upper- and lower-multi-phase microstructures but also between the constituent phases.
(2)In Ni_3Si-Ni_3Nb-Ni_3Ti pseudo-ternary alloy system, the precipitation phenomenon due to the solubility change by temperature between two constituent phases, L1_2 and D0_<24> was found to occur and consequently the precipitation strengthening was applicable to the present alloy system.
(3)The Ni_3Al-Ni_3Ti-Ni_3V and Ni_3Al-Ni_3Nb-Ni_3V pseudo-ternary alloys displayed the positive temperature dependence of the flow strength and also extremely high high-temperature strength accompanied with reasonable tensile ductility over a wide range of temperatures. In addition, the creep rate and creep rupture life were identical to or superior to those of the most superalloys or advanced superalloys.
(4)For the Ni_3Al-Ni_3Ti-Ni_3V pseudo-ternary alloys, fabrication process such as conventional melting, hot-forging and unidirectional solidification processes were found to be applicable, consequently resulting in the mass production, reliability and low-cost.
(5)It was shown that the developed multi-intermetallic in-situ composite materials are strongly promising as new high-temperature structural materials.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (38 results)

All 2006 2005 2004 Other

All Journal Article (30 results) Patent(Industrial Property Rights) (5 results) Publications (3 results)

  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Nb-Ni_3V Pseudo-Ternary Alloy System2006

    • Author(s)
      W.Soga
    • Journal Title

      Intermetallics 14,2

      Pages: 170-179

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Further Investigation on Phase Relation and Microstructures in Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System2006

    • Author(s)
      K.Ohira
    • Journal Title

      Intermetallics 14,4

      Pages: 367-376

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close-Packed Ni_3X (X:Al,Ti and V) Type Structures - I. Microstructures and Their Stabilities2006

    • Author(s)
      Y.Nunomura
    • Journal Title

      Acta Materialia 54,3

      Pages: 851-860

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close-Packed Ni3X (X:Al,Ti and V) Type Structures - II. Mechanical Properties2006

    • Author(s)
      S.Shibuya
    • Journal Title

      Acta Materialia 54,3

      Pages: 861-870

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Mechanical Properties of Dual Multi-Phase Single-Crystal Intermetallic Alloy Composed of Geometrically Close packed Ni3X (X:Al and V) Type Structures2006

    • Author(s)
      S.Shibuya
    • Journal Title

      Intermetallic 15(In press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of Multi-Phase Intermetallic Alloys Composed of Ni_3X-Type Structures2006

    • Author(s)
      T.Takasugi
    • Journal Title

      Interface Phenomena (In press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Evolution of Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close Packed Ni_3X (X:Al and V) Type Structures2006

    • Author(s)
      S.Shibuya
    • Journal Title

      Intermetallics 15(In press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Nb-Ni_3V Pseudo-Ternary Alloy System2006

    • Author(s)
      W.Soga, Y.Kaneno, T.Takasugi
    • Journal Title

      Intermetallics 14, No.2

      Pages: 170-179

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Further Investigation on Phase Relation and Microstructures in Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System2006

    • Author(s)
      K.Ohira, Y.Kaneno, H.Tsuda, T.Takasugi
    • Journal Title

      Intermetallics 14, No.4

      Pages: 367-376

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close-Packed Ni_3X (X : Al, Ti and V) Type Structures - I. Microstructures and Their Stabilities2006

    • Author(s)
      Y.Nunomura, Y.Kaneno, H.Tsuda, T.Takasugi
    • Journal Title

      Acta Materialia 54, No.3

      Pages: 851-860

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close-Packed Ni_3X (X : Al, Ti and V) Type Structures - II. Mechanical Properties2006

    • Author(s)
      S.Shibuya, Y.Kaneno, M.Yoshida, T.Takasugi
    • Journal Title

      Acta Materialia 54, No.3

      Pages: 861-870

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Mechanical Properties of Dual Multi-Phase Single-Crystal Intermetallic Alloy Composed of Geometrically Close packed Ni_3X (X : Al and V) Type Structures2006

    • Author(s)
      S.Shibuya, Y.Kaneno, M.Yoshida, T.Shishido, T.Takasugi
    • Journal Title

      Intermetallics 15(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of Multi-Phase Intermetallic Alloys Composed of Ni_3X-Type Structures2006

    • Author(s)
      T.Takasugi, Y.Kaneno
    • Journal Title

      Interface Phenomena (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructures and Mechanical Properties in Ni_3Si-Ni_3Ti-Ni_3Nb-Based Multi-Intermetallic Alloys2005

    • Author(s)
      T.Takasugi
    • Journal Title

      MRS Symp.Proc.Publications 842

      Pages: 291-296

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Microstructure, Mechanical Property and Oxidation Property in Ni_3Si-Ni_3Ti-Ni_3Nb Multi-Phase Intermetallic Alloys2005

    • Author(s)
      K.Ohira
    • Journal Title

      Material Science and Engineering A 399,1-2

      Pages: 332-343

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructures and Mechanical Properties in Ni_3Si-Ni_3Ti-Ni_3Nb-Based Multi-Intermetallic Alloys Integrative and Interdisciplinary Aspects of Intermetallics2005

    • Author(s)
      T.Takasugi, K.Ohira, Y.Kaneno
    • Journal Title

      MRS Symp.Proc.Publications 842

      Pages: 291-296

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructure, Mechanical Property and Oxidation Property in Ni_3Si-Ni_3Ti-Ni_3Nb Multi-Phase Intermetallic Alloys2005

    • Author(s)
      K.Ohira, Y.Kaneno, T.Takasugi
    • Journal Title

      Material Science and Engineering A 399, No.1-2

      Pages: 332-343

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructure, mechanical property and oxidation property in Ni_3Si-Ni_3Ti-Ni_3Nb multi-phase intermetallic alloys2005

    • Author(s)
      K.Ohira
    • Journal Title

      Material Science and Engineering A 399・1-2

      Pages: 332-343

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Nb-Ni_3V Pseudo-Ternary Alloy System2005

    • Author(s)
      W.Soga
    • Journal Title

      Intermetallics 14・2

      Pages: 170-179

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Further Investigation on Phase Relation and Microstructures in Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System2005

    • Author(s)
      K.Ohira
    • Journal Title

      Intermetallics 14・4

      Pages: 367-376

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dual Multi-phase intermetallic alloys composed of geometrically close-packed Ni_3X (X : Al, Ti and V) type structures - I. Microstructures and their stabilities2005

    • Author(s)
      Y.Nunomura
    • Journal Title

      Acta Materialia 54・3

      Pages: 851-860

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dual Multi-phase intermetallic alloys composed of geometrically close-packed Ni_3X (X : Al, Ti and V) type structures - II. Mechanical properties2005

    • Author(s)
      S.Shibuya
    • Journal Title

      Acta Materialia 54・3

      Pages: 861-870

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System2004

    • Author(s)
      K.Tomihisa
    • Journal Title

      Intermetallics 12,2

      Pages: 317-325

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Ti-Ni_3V Pseudo-Ternary Alloy System2004

    • Author(s)
      Y.Nunomura
    • Journal Title

      Intermetallics 12,4

      Pages: 389-399

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructures, Mechanical Property and Chemical Property in Ni_3Al-Ni_3Ti-Ni_3Nb-based Multi-Intermetallic Alloys2004

    • Author(s)
      K.Ohira
    • Journal Title

      J.Materials Science 39,7

      Pages: 2295-2301

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System2004

    • Author(s)
      K.Tomihisa, Y.Kaneno, T.Takasugi
    • Journal Title

      Intermetallics 12, No.3

      Pages: 317-325

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Ti-Ni_3V Pseudo-Ternary Alloy System2004

    • Author(s)
      Y.Nunomura, Y.Kaneno, H.Tsuda, T.Takasugi
    • Journal Title

      Intermetallics 12, No.4

      Pages: 389-399

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructures, Mechanical Property and Chemical Property in Ni_3Al-Ni_3Ti-Ni_3Nb-based Multi-Intermetallic Alloys2004

    • Author(s)
      K.Ohira, Y.Kaneno, T.Takasugi
    • Journal Title

      J.Materials Science 39, No.7

      Pages: 2295-2301

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructures, Mechanical Properties and Chemical properties in Ni_3Al-Ni_3Ti-Ni_3Nb-based multi-intermetallic alloys2004

    • Author(s)
      K.Ohira
    • Journal Title

      J.Materials Science 39・7

      Pages: 2295-2301

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Evolution of Dual Multi-Phase Intermetallic Alloys Composed of Geometrically Close Packed Ni_3X (X : Al and V) Type Structures

    • Author(s)
      S.Shibuya, Y.Kaneno, H.Tsuda, T.Takasugi
    • Journal Title

      Intermetallics (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許2006

    • Inventor(s)
      高杉 隆幸, 金野 泰幸
    • Industrial Property Rights Holder
      大阪府立大学
    • Filing Date
      2006-02-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許2006

    • Inventor(s)
      高杉 隆幸, 金野 泰幸
    • Industrial Property Rights Holder
      大阪府立大学
    • Filing Date
      2006-01-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 特許2006

    • Inventor(s)
      高杉 隆幸, 金野 泰幸
    • Industrial Property Rights Holder
      大阪府立大学
    • Filing Date
      2006-03-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 2重複相組織かななるV及Nbを含有するNi_3Al基金間化合物及びその製造法、耐熱構造材料2006

    • Inventor(s)
      高杉 隆幸, 金野 泰幸
    • Industrial Property Rights Holder
      公立法人大阪府立大学
    • Filing Date
      2006-01-30
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 2重複相組織かななるTiびNbを含有するNi_3Al基金属間化合物及びその製造法、耐熱構造材料2005

    • Inventor(s)
      高杉 隆幸, 金野 泰幸
    • Industrial Property Rights Holder
      公立法人大阪府立大学
    • Filing Date
      2005-03-25
    • Related Report
      2005 Annual Research Report
  • [Publications] K.Tomihisa: "Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Si-Ni_3Ti-Ni_3Nb Pseudo-Ternary Alloy System"Intermetallics. 12,3. 317-325 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nunomura: "Phase Relation and Microstructure in Multi-Phase Intermetallic Alloys based on Ni_3Al-Ni_3Ti-Ni_3V Pseudo-Ternary Alloy System"Intermetallics. 12,4. 389-399 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Ohira: "Microstructures, Mechanical Properties and Chemical properties in Ni_3Al-Ni_3Ti-Ni_3-based multi-intermetallic alloys"J.Materials Science. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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