| Project/Area Number |
15360431
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Okayama University |
|---|
Principal Investigator |
MUTO Akinori Okayama University, GRADUATE SCHOOL OF NATURAL SCIENCE AND TECHNOLOGY, ASSOCIATE PROFESSOR (00174243)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
SAKATA Yusaku OKAYAMA UNIVERSITY, Professor Emeritus (70032951)
HIRAI Takayuki OSAKA UNIVERSITY, RESEARCH CENTER FOR SOLAR ENERGY CHEMISTRY, PROFESSOR (80208800)
BHASKAR Thallada (T Bhaskar / THALLADA Bhaskar) 岡山大学, 大学院・自然科学研究科, 助手 (40359881)
|
|---|
| Project Period (FY) |
2003 – 2006
|
| Project Status |
Completed (Fiscal Year 2006)
|
| Budget Amount *help |
¥10,700,000 (Direct Cost: ¥10,700,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2005: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2004: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2003: ¥6,400,000 (Direct Cost: ¥6,400,000)
|
|---|
| Keywords | TITANIUM PHOSPHATE / ADSORPTION / PHOTOCATALYST / METHYLENE BLUE / RUTHENIUM / POROUS CARBON / REACTION KINETIC ANALYSIS / BLACK LIGHT / バンドギャップ / 界面活性剤 / 無機紫外線遮蔽材 / Ru触媒 / 複合材料 |
|---|
| Research Abstract |
A COMPOSITE OF TITANIUM PHOSPHATE-POROUS CARBON WAS PREPARED FROM AMINO PHOSPHATE CHELATE RESIN BY ADSORBING TI(IV) AND CARBONIZATION AT 773 K AND 873 K. THE COMPOSITE HAD POTENTIAL FOR ADSORPTION AND DECOMPOSITION OF ORGANIC COMPOUNDS IN WATER. REMOVAL OF METHYLENE BLUE IN THE AQUEOUS SOLUTION WAS CONDUCTED BY A BATCH TEST WITH IRRADIATION OF BLACK LIGHT. PLATINUM WAS ADDED INTO THE COMPOSITE AS PROMOTOR. CRYSTALLINE TIP2O7 AND METALLIC PT WERE FOUND IN THE COMPOSITE. THE DIAMETERS OF THESE CRYSTALLINE PARTICLES WERE LESS THAN 30 NM. PT PROMOTED GASIFICATION OF THE POLYMER CHAIN OF THE CHELATE RESIN.
THE REMOVAL RATE OF METHYLENE BLUE WAS INCREASED BY CO-EXISTING PT. THE REMOVAL RATE CONSTANT K WAS EXPRESSED BY FIRST ORDER KINETICS. THE REMOVAL RATE CONSTANT PER WEIGHT OF TI IN THE COMPOSITE K' WAS ALMOST CONSTANT EVEN THOUGH PT CONTENT WAS INCREASED.
|
