| Project/Area Number |
15360481
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Recycling engineering
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| Research Institution | Tohoku University |
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Principal Investigator |
YOSHIOKA Toshiaki Tohoku University, Graduate School of Environmental Studies, Professor, 大学院・環境科学研究科, 教授 (30241532)
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| Co-Investigator(Kenkyū-buntansha) |
MIZOGUCHI Tadaaki Tohoku University, Environment Conservation Center, Professor, 環境保全センター, 教授 (00005430)
MIZUNO Osamu Tohoku University, Environment Conservation Center, Research Associate, 環境保全センター, 助手 (90271882)
NAKAMURA Osamu Tohoku University, Environment Conservation Center, Research Associate, 環境保全センター, 助手 (00400466)
内田 美穂 東北大学, 大学院・環境科学研究科, 助手 (10292236)
奥脇 昭嗣 東北大学, 大学院・環境科学研究科, 教授 (70005320)
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| Project Period (FY) |
2003 – 2005
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| Project Status |
Completed (Fiscal Year 2005)
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| Budget Amount *help |
¥13,600,000 (Direct Cost: ¥13,600,000)
Fiscal Year 2005: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2004: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2003: ¥7,800,000 (Direct Cost: ¥7,800,000)
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| Keywords | waste plastics / substitution for Reducing agent / control of carbon dioxide emission / recycling / 合成ガス / フィードストックリサイクル |
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| Research Abstract |
We performed a basic research on the use of waste plastics aiming the reduction of carbon dioxide emission of current 10 million tons a year from the metal industry. This year, we investigated the reduction of chromium employing solid carbonaceous fuels obtained from the dechlorination of waste plastics. We examined also the production of syngas (carbon monoxide and hydrogen) from PET, which can not be converted into oil by pyrolysis. All these processes were used to investigate their effect on the carbon dioxide reduction. Mixtures of powdered dechlorinated waste plastics, chromium slag and silicon sand were used as input material. These materials were heated in an alumina boat from room temperature to the process temperature. After that, the sexivalent chromium dissolution test was carried out with hydrochloric acid as an eluent. The yield of syngas (carbon monoxide and hydrogen) obtained by steam reforming of PET in the presence of calcium hydroxide and nickel oxide was determined. The results were compared with the use of coal in order to evaluate the effect of the substitution of fossil fuels by waste plastics and the resulting carbon dioxide reduction. After heating at 1000 ℃ in oxygen atmosphere, 1.6 % of sexivalent chromium was leached out of the sample but, after heating between 600 ℃ and 1000 ℃ in helium atmosphere, just 0.5 % was leached. These results show the possibility to substitute oil coke by dechlorinated waste plastics during the chromium slag treatment. One main product of syngas obtained from PET and PC by the pyrolysis in the presence of calcium hydroxide and nickel oxide, carbon monoxide can be used as reduction agent in the production of several metals, e.g. steel. The other main product of syngas, hydrogen is an important energy source in future technologies.
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