• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Corrosion Control for Internal Structure of Nuclear Reactor Based on Radiation Induced Surface Activation Phenomenon

Research Project

Project/Area Number 15360503
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionTokyo University of Marine Science and Technology

Principal Investigator

TOMOJI Takamasa  Tokyo University of Marine Science and Technology, Faculty of Marine Technology, Professor, 海洋工学部, 教授 (20134851)

Co-Investigator(Kenkyū-buntansha) MOTODA Shinichi  Tokyo University of Marine Science and Technology, Faculty of Marine Technology, Associate professor, 海洋工学部, 助教授 (10190969)
HAZUKU Tatsuya  Tokyo University of Marine Science and Technology, Faculty of Marine Technology, Associate professor, 海洋工学部, 助教授 (60334554)
UEMATSU Susumu  National Maritime Research Institute, Advanced Maritime Transport Technology Department, Senior Researcher, 輸送高度化研究領域, 上席研究員
OKAMOTO Koji  The University of Tokyo, Dept.Quantum Engineering & Systems Science, Professor, 大学院・工学系研究科, 教授 (80204030)
FURUYA Masahiro  Central Research Institute of Electric Power Industry, Nuclear Technology Research Laboratory, Senior Researcher, 原子力技術研究所, 主任研究員 (80371342)
Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥13,300,000 (Direct Cost: ¥13,300,000)
Fiscal Year 2004: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 2003: ¥7,300,000 (Direct Cost: ¥7,300,000)
KeywordsCorrosion / Radiation / Surface / Activation / Nuclear / Reactor / Metal / Oxide
Research Abstract

When a semiconductor film is irradiated by γ-ray, excited electrons are transferred to a base metal in contact with the film, resulting in a drop of corrosion potential. This study proposes a corrosion mitigation method based on radiation induced surface activation(RISA) phenomena by supplying γ-rays from outside the material, or based on a self-excited methodology activating the film and/or the base metal. The results of the study revealed that electrons in the oxide film were activated by γ-ray irradiation and transferred from the oxide to the adjacent base metal. This made the corrosion potential of the metal less noble through a process in which the radiation induced a surface activation phenomenon, even in Zirconium oxide (ZrO_2) films which had large band gap energies. The mitigating method for the corrosion of metals was developed by utilizing this effect. The method involved external γ-rays irradiation introduced by activation of oxide films and/or base metals corrosion potential of ZrO_2 coated SUS304L was shifted down to the range between 90 mV and 300 mV vs. SSE by γ-ray irradiation. The corrosion potential was further shifted down to 600 mV when a CoCr intermediate layer was inserted between the ZrO_2 spray coating film and the SUS304L base metal. Iron specimens with a spray coating film of TiO_2,ZrO_2, and Al_2O_3 were immersed in a 3 wt% sodium chloride aqueous solution. Pitting and general corrosion were suppressed on all three specimens irradiated with γ-rays.
These results clearly show that the corrosion potential of stainless steel could be less noble up to a level of -600 mV vs. SSE with this methodology and these processes would have a remarkable effect in mitigating the corrosion of stainless steels used in internal structures of nuclear reactors.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (20 results)

All 2005 2004 Other

All Journal Article (13 results) Patent(Industrial Property Rights) (1 results) Publications (6 results)

  • [Journal Article] RI放射線源を用いた放射線誘起表面活性防食2005

    • Author(s)
      中村大輔
    • Journal Title

      日本原子力学会2005年春の年会要旨集 第III分冊

      Pages: 564-564

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 放射線誘起表面活性を利用した防食2005

    • Author(s)
      古谷正裕
    • Journal Title

      マリンエンジニアリング論文集 第40巻第4号(掲載予定)

    • NAID

      10017481742

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Corrosion Control by Radiation Induced Surface Activation2005

    • Author(s)
      Daisuke Nakamura
    • Journal Title

      2005 Annual Meeting of the Atomic Energy Society of Japan(III)

      Pages: 564-564

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Corrosion Control on the Basis of Radiation Induced Surface Activation2005

    • Author(s)
      Masahiro Furuya
    • Journal Title

      Journal of The Japan Institution of Marine Engineering Vol.40, No.4

    • NAID

      10013593335

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 放射線源を用いた放射線誘起表面活性防食2005

    • Author(s)
      中村大輔, 元田慎一, 波津久達也, 賞雅寛而, 古谷正裕, 岡本孝司, 植松進
    • Journal Title

      日本原子力学会2005年春の年会要旨集 第I分冊

      Pages: 561-561

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 放射線誘起表面活性によるセラミック被覆材の腐食電位低下2005

    • Author(s)
      宮野征巳, 小野昇一, 菱田護, 安永龍哉, 藤沢匡介, 賞雅寛而
    • Journal Title

      日本原子力学会2005年春の年会要旨集 第I分冊

      Pages: 562-562

    • NAID

      130007026511

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation(RISA)(2) Development of Corrosion Control Method2004

    • Author(s)
      Masahiro Furuya
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety (NUTHOS-6)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation (RISA)(3) Durability and Mechanical Properties of Spray Coatings2004

    • Author(s)
      David T.Yasunaga
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety (NUTHOS-6)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation(RISA) (2)Development of Corrosion Control Method2004

    • Author(s)
      Masahiro Furuya
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety(NUTHOS-6) N6P352

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation(RISA) (3)Durability and Mechanical Properties of Spray Coatings2004

    • Author(s)
      David T.Yasunaga
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety(NUTHOS-6) N6P354

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation (RISA) (2) Development of Corrosion Control Method2004

    • Author(s)
      M.Furuya, H.Kawamura, T.Matsumura, T.Takamasa, K.Okamoto, D.Hiroishi, N.Sekimura, S.Uematsu, T.Yasunaga, K.Fujisawa, J.Shimojo
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety (NUTHOS-6)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Innovative Nuclear Technologies Based on Radiation Induced Surface Activation (RISA) (3) Durability and Mechanical Properties of Spray Coatings2004

    • Author(s)
      D.T.Yasunaga, J.Shimojo, M.Furuya, S.Uematsu, N.Sekimura, T.Takamasa
    • Journal Title

      Proc.6th International Conference on Nuclear Thermal Hydraulics, Operations and Safety (NUTHOS-6)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 放射線誘起表面活性を利用した防食法の開発

    • Author(s)
      古谷正裕, 賞雅寛而, 岡本孝司, 安永龍哉, 植松進
    • Journal Title

      マリンエンジニアリング学会誌 (投稿中)

    • NAID

      10008836251

    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 防食性に優れた機能性被膜の形成法2005

    • Inventor(s)
      賞雅 寛而, 波津久 達也, 植松 進, 岡本 孝司, 古谷 正裕, 阿部 弘亨, 関村 直人, 三島 嘉一郎, 安永 龍哉, 藤沢 匡介, 千草 剛, 下条 純, 小野 昇一, 中村 秀夫, 柴本 泰照, 師岡 慎一, 秋葉 美幸, 鹿野 文寿
    • Industrial Property Rights Holder
      東京海洋大学, (独)海上技術安全研究所, 東京大学, (財)電力中央研究所, 京都大学, (株)神戸製鋼所, (財)産業創造研究所, 日本原子力研究所, (株)東芝
    • Industrial Property Number
      2005-042377
    • Filing Date
      2005-02-18
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] 古谷正裕: "放射線誘起表面活性による防食技術と水素製造"日本原子力学会2004年春の年会要旨集. 第I分冊. 2 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 藤沢匡介, 師岡慎一, 菱田護, 古谷正裕, 植松進, 中村秀夫, 三島嘉一郎, 関村直人, 岡本孝司, 賞雅寛而: "放射線誘起表面活性効果による高性能原子炉に関する技術開発(1)-全体計画-"日本原子力学会2004年春の年会要旨集. 第II分冊. 287 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 安永龍哉, 下条純, 古谷正裕, 植松進, 関村直人, 賞雅寛而: "放射線誘起表面活性効果による高性能原子炉に関する技術開発(2)-溶射皮膜の特性と耐久性-"日本原子力学会2004年春の年会要旨集. 第II分冊. 288 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 小野昇一, 宮野征巳, 菱田護, 安永龍哉, 古谷正裕, 賞雅寛而: "放射線誘起表面活性効果による高性能原子炉に関する技術開発(3)-高温水中における腐食電位低下効果-"日本原子力学会2004年春の年会要旨集. 第II分冊. 289 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 賞雅 寛而, 古谷 正裕, 岡本 孝司, 植松 進, 安永 龍哉: "放射線誘起表面活性(RISA)について"日本防錆技術協会溶射部会講演会「RISA・溶射皮膜の海水防食特性」. 1-33 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 賞雅 寛而, 岡本 孝司, 三島 嘉一郎, 古谷 正裕: "放射線誘起表面活性現象の発見とその利用"日本原子力産業会議放射線利用研究会3グループ合同研究会照射利用グループ講演資料. 25-45 (2003)

    • Related Report
      2003 Annual Research Report

URL: 

Published: 2003-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi