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Preparation and Structural Analysis of Nanocomposites of Bacterial Cellulose and Native Inorganic Material

Research Project

Project/Area Number 15510101
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKyoto University

Principal Investigator

HIRAI Asako  Kyoto University, Institute for Chemical Research, Assistant Professor, 化学研究所, 助手 (20156623)

Co-Investigator(Kenkyū-buntansha) HORII Fumitaka  Kyoto University, Institute for Chemical Research, Professor, 化学研究所, 教授 (70124758)
TSUJI Masaki  Kyoto University, Institute for Chemical Research, Associate Professor, 化学研究所, 助教授 (60172003)
DONKAI Nobuo  Niigata Women's College, Department of Human Life and Environmental Science, Professor, 生活科学科, 教授 (90237181)
Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 2004: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2003: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywordscellulose / imogolite / nanocomposite / lipuid crystal / TEM / SEM / Polarizing Optical Microscopy / X-ray Diffraction Analysis / 電子顕微鏡 / 光学顕微鏡 / ナノチューブ / 高結晶性ミクロフィブリル
Research Abstract

To fabricate an environmentally friendly and new material, nanocomposites composed of cellulose microfibrils and imogolite nanotubes were prepared, and their structure and properties were investigated. First, tunicate cellulose was used as a cellulose sample. Tunicate cellulose microfibrils prepared by sulfuric acid treatment were rodlike in appearance, 1.9 μm long and 25 nm wide on the average. Raw materials of imogolite gel films were collected from a pumice bed at Murasakino, Kitakami-shi, Iwate-ken. Purified imogolite nanotubes with an outer diameter of 2.5 nm were estimated at 0.18 μm long on the average. Liquid crystal structures of the mixtures of tunicate cellulose microfibrils/imogolite nanotubes with different weight ratios in the aqueous solution of acetic acid (pH=3) were studied by polarizing optical microscopy and SEM. The texture of liquid crystal of imogolite showed a chiral nematic fingerprint pattern, while that of cellulose microfibrils gave cross-hatch pattern. All the textures of liquid crystals of the mixtures with different weight ratios were different from either texture of a single component of imogolite or cellulose microfibrils. The structure of nanocomposite films prepared from respective liquid crystalline phases of the mixtures was investigated by X-ray diffraction analysis and FT-JR. The storage modulus, E', at room temperature was 9.6,11,13,15 GPa for cellulose, 5/5,4/6, and 3/7 nanocomposites films, respectively. The values of E' were insensitive to the temperature above 25℃ for the 5/5 nanocomposite and cellulose films. The 5/5 nanocomposite film was broken at 290℃, while the cellulose film was broken at 250℃. The thermal properties were improved by adding imogolite. On the basis of the results of tunicate/imogolite nanocomposites, a study of bacterial cellulose/imogolite nanocomposites is in progress.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (14 results)

All 2005 2004 Other

All Journal Article (12 results) Publications (2 results)

  • [Journal Article] セルロースミクロフィブリルとイモゴライトナノチューブとのナノコンポジットが作る液晶状態の構造2005

    • Author(s)
      平井諒子
    • Journal Title

      Polymer Preprints, Japan 54

      Pages: 720-720

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Magnetic Alignment of the Chiral Nematic Phase of a Cellulose Microfibril Suspension2005

    • Author(s)
      Fumiko Kimura
    • Journal Title

      Langmuir 21

      Pages: 2034-2037

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Liquid Crystal Structure of Nanocomposites of Cellulose Microfibrils and Imogolite Nanotubes2005

    • Author(s)
      Asako Hirai
    • Journal Title

      Polymer Preprints, Japan Vol.54, No.1

      Pages: 61-61

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Magnetic Alignment of the Chiral Nematic Phase of a Cellulose Microfibril Suspension2005

    • Author(s)
      Fumiko Kimura
    • Journal Title

      Langmuir Vol.21

      Pages: 2034-2037

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Magnetic Alignment of the Chiral Nematic Phase of a Cellulose Microfibril Suspension2005

    • Author(s)
      Fumiko Kimura
    • Journal Title

      Langmuir 21, No.5

      Pages: 2034-2037

    • Related Report
      2004 Annual Research Report
  • [Journal Article] セルロースミクロフィブリルとイモゴライトナノチューブとのナノコンポジットが作る液晶状態の構造2005

    • Author(s)
      平井 諒子
    • Journal Title

      第54回高分子学会年次大会 (発表予定)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 高結晶性セルロースミクロフィブリルとイモゴライトからなるナノコンポジットの創製2004

    • Author(s)
      生野雅也
    • Journal Title

      Polymer Preprints, Japan 53

      Pages: 940-940

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 高結晶性セルロースミクロフィブリルとイモゴライトナノチューブの水混合系の相挙動2004

    • Author(s)
      生野雅也
    • Journal Title

      Preprints of 11^<th> Annual Meeting of the Cellulose Society of Japan

      Pages: 85-86

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] セルロースミクロフィブリルとイモゴライトナノチューブの水混合系の相挙動とナノコンポジットの創製2004

    • Author(s)
      生野雅也
    • Journal Title

      Polymer Preprints, Japan 53

      Pages: 3373-3373

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Preparation of Nanocomposites Composed of Highly Crystalline Microfibrils and Imogolite2004

    • Author(s)
      Masaya Ikuno
    • Journal Title

      Polymer Preprints, Japan Vol.53, No.1

      Pages: 49-49

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Phase Behavior of Aqueous Mixture of Highly Crystalline Cellulose Microfibrils and Imogolite Nanotubes2004

    • Author(s)
      Masaya Ikuno
    • Journal Title

      Preprints of 11^<th> Annual Meeting of The Cellulose Society of Japan

      Pages: 85-86

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Phase Behavior of Aqueous Mixture of Cellulose Microfibrils and Imogolite Nanotubes and Preparation of Nanocomposites2004

    • Author(s)
      Masaya Ikuno
    • Journal Title

      Polymer Preprints, Japan Vol.53, No.2

      Pages: 3373-3373

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] 生野雅也 ほか4名: "高結晶性セルロースミクロフィブリルとイモゴライトからなるナノコンポジットの創製"第53回高分子学会年次大会. (発表予定). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 生野雅也 ほか4名: "高結晶性セルロースミクロフィブリルとイモゴライトナノチューブの水混合系の相挙動"セルロース学会第11回年次大会. (発表予定). (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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