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Charge ordering and metal-insulator transition in mixed-valence transition metal oxcides

Research Project

Project/Area Number 15540332
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionChiba University

Principal Investigator

OHAMA Tetsuo  Chiba University, Graduate school of science and technology, associate professor, 大学院・自然科学研究科, 助教授 (80345008)

Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2004: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2003: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsNMR / electron correlation / magnetic structure / metal-insulator transition / 磁気秩序 / 軌道状態
Research Abstract

Developement of NMR spectrometer
In this research, we need an NMR spectrometer with wide band width to observe the resonance in magnetically ordered states. We developed a spectrometer for 5 to 220MHz.
Charge ordering in vanadates
We studied the spin dynamics in the uniform state in a charge ordering system α'-NaV_2O_5. We observed low-dimensional behavior in the nuclear relaxation ; it agrees with our expectation from the crystal structure. The further understanding of this behavior and effects of charge fluctuation is a future problem.
Ferromagnetism in vanadates
In order to study the orbital and spin states and the magnetic excitations in insulating magnetic ordered states on frustrated lattices, we studied a vanadates with the pyrochlore structure Lu_2V_2O_7. We observed NMR spectra for Lu and V sites in the ferromagnetic state to investigate the orbital state. The experiments and the data analysis are in progress.
Antiferromagnetism in f-electron systems
In order to study magnetic ordering in metals and its relation with metal-insulator transition, we studied a metallic antiferromagnet UNiGa_5. We analyzed NMR spectra for the ligand Ga sites in the antiferromagnetic and paramagnetic phases and determined the quadrupole parameters and the internal fields at the Ga sites.
We proposed a new NMR analysis of magnetic structures with magnetic space group and the representation analysis of magnetic structure and applied it to UNiGa_5 (published in Phys.Rev.B).

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (9 results)

All 2005 2004 2003

All Journal Article (9 results)

  • [Journal Article] NMR analysis of the magnetic structure of UNiGa_52005

    • Author(s)
      T.Ohama
    • Journal Title

      Phys.Rev.B 71-79

      Pages: 94408-94408

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Observation of lattice dimerization in spin-singlet low temperature phase of NaTiSi_2O_62005

    • Author(s)
      E.Ninomiya
    • Journal Title

      Physica B 329-333

      Pages: 884-884

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Low-temperature zigzag charge ordering structure of α'-NaV_2O_52005

    • Author(s)
      H.Sawa
    • Journal Title

      Physica B 329-333

      Pages: 878-878

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Magnetic excitations in the high-temperature phase of α'-NaV_2O_52005

    • Author(s)
      T.Ohama
    • Journal Title

      Physica B 329-333

      Pages: 934-934

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] NMR analysis of the magnetic structure of UNiGa_52005

    • Author(s)
      T.Ohama, M.Hirano, S.Noguchi
    • Journal Title

      Physical Review B 71・9

      Pages: 94408-94408

    • Related Report
      2004 Annual Research Report
  • [Journal Article] NMR analysis of the magentic structure of UniGa_52004

    • Author(s)
      T.Ohama
    • Journal Title

      Phys.Rev.B 71

      Pages: 94408-94408

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Observation of lattice dimerization in spin-singlet low temperature phase of NaTiSi_2O_62003

    • Author(s)
      E.Ninomiya
    • Journal Title

      Physica B 329-333

      Pages: 884-884

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Low-temperature zigzag charge ordering structure of α'-NaV_2O_52003

    • Author(s)
      H.Sawa
    • Journal Title

      Physica B 329-333

      Pages: 878-878

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Magnetic excitations in the high-temperature phase of α'-NaV_2O_52003

    • Author(s)
      T.Ohama
    • Journal Title

      Physica B 329-333

      Pages: 934-934

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary

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Published: 2003-04-01   Modified: 2020-05-15  

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