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Local structure changes and structural transformations of melt, glass and gel under the Earth's mantle conditions.

Research Project

Project/Area Number 15540460
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionKumamoto University (2004)
Osaka University (2003)

Principal Investigator

YOSHIASA Akira  Kumamoto University, Faculty of Science, Professor, 理学部, 教授 (00191536)

Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2004: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2003: ¥2,800,000 (Direct Cost: ¥2,800,000)
Keywordsin situ experiments / the Earth's mantle conditions / local structure of melt / local structure of glass / local structure of gel / transformation of disordered phases / pressure dependences of coordination environments / EXAFS method / 優体の構造
Research Abstract

Using a large-volume high-pressure apparatus, phases of crystals, melts, glasses and gel in the system of some germanates, fluorides, halogenides and silicates have been compressed up to 15 GPa at 300-1500K. The local structure changes around the specific kind of atom have been investigated by an in situ XAFS(x-ray absorption fine structure) method using synchrotron radiation. The structures have also been characterized by means of diffraction and spectroscopic methods. Dynamical atomic motion for each atom in these phases has been studied by determined Debye-Waller factors. The atomic effective pair potentials, the phonon energies and Gruneisen parameters have been estimated in this study. For example, the coordination number of Ge in GeO2 glass changes from four to six between 8 and 10 GPa. In contrast to the case for the glass, the coordination environment around Ge in GeO2 gel gradually increases over a pressure range from 2 to 12 GPa. Liquid germinate consisting of tetrahedrally coordinated Ge contracts with increasing pressure without significant changes in the local structure up to 2.5 GPa at 1300 K and then shows an abrupt fourfold-to-sixfold coordination change around 3 GPa. The coordination change is completed below 4 GPa where upon a high-density liquid consisting of octahedrally coordinated Ge becomes stable. By analogy with this liquid germanate, it is expected that a sharp transition occurs in liquid silicate at a higher pressure. Geophysical implications derived from this study will be discussed with detailed data of our studies.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (27 results)

All 2005 2004 2003 Other

All Journal Article (19 results) Patent(Industrial Property Rights) (2 results) Publications (6 results)

  • [Journal Article] Electrical conductivities and conduction mechanisms of perovskite-type Na_<1-x>K_xMgF_3 (x=0, 0.1, 1) and KZnF_32005

    • Author(s)
      A.Yoshiasa, D.Sakamoto他
    • Journal Title

      Z.anorg.allg.Chem. 631

      Pages: 502-506

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrical conductivities and conduction mechanisms of perovskite-type Na_<1-x>K_xMgF_3(x=0,0.1,1) and KZnF_32005

    • Author(s)
      A.Yoshiasa, D.Sakamoto, et al.
    • Journal Title

      Z.anorg.allg.Chem. 631

      Pages: 502-506

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrical conductivities and conduction mechanisms of perovskite-type Na_<1-z>K_xMgF_3 (x=0,0.1,1) and KZnF_3.2005

    • Author(s)
      A.Yoshiasa, D.Sakamoto他
    • Journal Title

      Z.anorg.allg.Chem. 631

      Pages: 502-506

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid alkali-GeO22004

    • Author(s)
      O.Ohtaka, H.Arima, A.Yoshiasa 他
    • Journal Title

      Phys.Rev.Lett 92

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Graphite-hexagonal diamond transition and surviving compressed graphite.2004

    • Author(s)
      A.Yoshiasa, A.Nakatsuka他
    • Journal Title

      Applied Mineralogy : Developments in Science and Technology, Sao Paulo : ICAM2004 (ed. by M.Pecchioet al.)

      Pages: 93-96

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Oxygen-deficient strontium cobaltate, SrCoO_<2.64>.2004

    • Author(s)
      A.Nakastuka, A.Yoshiasa, H.Takei
    • Journal Title

      Acta Cryst C 60

      Pages: 159-160

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Single crystal x-ray diffraction study of the vanadate garnet Ca_2NaZn_2V_3O_<12>2004

    • Author(s)
      A.Nakatsuka, A.Yoshiasa他
    • Journal Title

      Material.Res.Bull. 39

      Pages: 949-956

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Graphite-hexagonal diamond transition and surviving compressed graphite.2004

    • Author(s)
      A.Yoshiasa, A.Nakatsuka, M.Okube, H.Okudera
    • Journal Title

      Applied Mineralogy : Developments in Science and technology(ed.by M.Pecchio et al.)(Sao Paulo : ICAM2004)

      Pages: 93-96

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Single crystal x-ray diffraction study of the vanadate garnet Ca_2NaZn_2V_3O_<12>2004

    • Author(s)
      A.Nakatsuka, K.Iishi, Y.Ikuta, A.Yoshiasa
    • Journal Title

      Material.Res.Bull. 39

      Pages: 949-956

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid alkali-Geo2.2004

    • Author(s)
      O.Ohtaka, H.Arima, H.Fukui, W.Utsumi, Y.Katayama, A.Yoshiasa
    • Journal Title

      Phys.Rev.Lett. 92

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid alkali-GeO2.2004

    • Author(s)
      O.Ohtaka, H.Arima, A.Yoshiasa他
    • Journal Title

      Phys.Rev.Lett 92

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Graphite-hexagonal diamond transition and surviving compressed graphite.2004

    • Author(s)
      A.Yoshiasa, A.Nakatsuka他
    • Journal Title

      Applied Mineralogy : Developments in Science and Technology, Sao Paulo : ICAM2004 (ed.by M.Pecchio et al.)

      Pages: 93-96

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Oxygen-deficient strontium cobaltate, SrCoO_<2.64->2004

    • Author(s)
      A.Nakastuka, A.Yoshiasa, H.Takei
    • Journal Title

      Acta Cryst C 60

      Pages: 159-160

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid germanate2003

    • Author(s)
      O.Ohtaka, A.Yoshiasa他
    • Journal Title

      GEOCHIMICA ET COSMOCHIMICA ACTA 67(18)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Vanadate garnet, Ca2NaMg2V3O122003

    • Author(s)
      A.Nakatsuka, Y.Ikuta, a.Yoshiasa, K.Iishi
    • Journal Title

      Acta Cryst.C 59

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] LiMnVO4.2003

    • Author(s)
      M.Sugawara, A.Yoshiasa, T.Yamanaka, H.Takei
    • Journal Title

      Acta Cryst E 59

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Detailed structures of hexagonal diamond(lonsdaleite) and wurtzite type BN2003

    • Author(s)
      A.Yoshiasa, Y.Murai, O.Ohtaka, T.Katsura
    • Journal Title

      Jpn.J.Appl.Phys. 42

      Pages: 1964-1704

    • NAID

      130004530549

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid germanate2003

    • Author(s)
      Ohtaka O, Arima H, Fukui H, Utsumi W, Katayama Y, Yoshiasa A
    • Journal Title

      GEOCHIMICA ET COSMOCHIMICA ACTA 67(18)(Suppl.)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure-induced polymorphic phase transition in liquid germinate2003

    • Author(s)
      O.Ohtaka, A.Yoshiasa他
    • Journal Title

      GEOCHIMICA ET COSMOCHIMTCA ACTA 67(18)

    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] x線吸収分光による温度・圧力同時測定方法2005

    • Inventor(s)
      吉朝 朗
    • Industrial Property Rights Holder
      原研
    • Industrial Property Number
      2004-122734
    • Filing Date
      2005-04-19
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] x線吸収分光による温度・圧力同時測定方法2004

    • Inventor(s)
      吉朝 朗
    • Industrial Property Rights Holder
      原研
    • Industrial Property Number
      2004-122734
    • Filing Date
      2004-04-19
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] O.Ohtaka, A.Yoshiasa他: "Pressure-induced polymorphic phase transition in liquid alkali-GeO2"Phys.Rev.Lett.. (accepted).

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Yoshiasa, M.Okube 他: "XAFS study of A-site-deficient La0. 63Ti0. 92Nb0. 0803 perovskite"Physica Scripta. (accepted).

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Okube, A.Yoshiasa他: "XAFS study of the perovskite-type proton conductor SrZr0. 9Yb0. 103-d"Physica Scripta. (accepted).

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Nakatsuka, A.Yoshiasa 他: "vanadate garnet, Ca2NaMg2V3O12"Acta Cryst.. C59. i133-i135 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Okudera, A.Yoshiasa, 他: "Determination of crystallographic space group and atomic arrangements in oxide-ion-conducting Nd_<9.33>(SiO_4)_6O_2"Z.Kristallogr.. 219. 29-31 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Yoshiasa 他: "Detailed structures of hexagonal diamond (lonsdaleite) and wurtzite type BN"Jpn.J.Appl.Phys.. 42. 1694-1704 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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