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Synthetic Study of Polymer Complex Thin Membrane which penetrates small organic molecules and Separates, Concentrates, Identifies, and Recovers Heavy Metal ions

Research Project

Project/Area Number 15550104
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionToyama University

Principal Investigator

AIZAWA Sen-ichi  Toyama University, Engineering, Associate professor, 工学部, 助教授 (60231099)

Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2004: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 2003: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsPolymer Complex Thin Membrane / Optical Activity / Heavy metal ions / Peptide Bridging / 高分子錯体薄膜 / 光学活性
Research Abstract

Carboxylate groups in the Rh(III) terminals of Rh(III)-Co(III)-Rh(III) trinuclear complex, Δ_<LLL>Δ_<LLL>-[Co-{Rh(L-cys-N,S)_3}_2]^<3-> were successfully bridged with 1,9-diaminononane using N-hydroxysuccinimide and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride in water. The monoanionic peptide-bridged trinuclear complex was separated and purified by column chromatography, and then isolated. The structure was determined by ^<31>C NMR, UV-vis, and CD spectra. The peptide-bridged reaction also proceeded by using 1,12-diminododecane instead of 1,9-diaminononane. The peptide-bridged polymer complex was prepared under a similar reaction conditions. It was confirmed that the thiolato sulfur atoms in the polymer complex can bridge and release some metal ions.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (17 results)

All 2005 2004 Other

All Journal Article (12 results) Book (2 results) Publications (3 results)

  • [Journal Article] Mechanistic Studies on Monodentate-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Platinum(II) Complexes with Tris[2-(diphenylphosphino) ethyl]phosphine2005

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Inorganica Chimica Acta 358・7

      Pages: 2319-2326

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Mechanistic Studies on Monodentate-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Platinum(II) Complexes with Tris[2-(diphenylphosphino)ethyl]phosphine2005

    • Author(s)
      S.Aizawa, T.Kobayashi, T.Kawamoto
    • Journal Title

      Inorg.Chim.Acta 358-7

      Pages: 2319-2326

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Mechanistic Studies on Monodentate-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Platinum(II) Complexes with Tris[2-(diphenylphosphino)ethyl]-phosphine2005

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Inorgenic Chimica Acta 358・7

      Pages: 2319-2326

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Rapid Equilibrium between Trigonal-bipyramidal and Square-pyramidal Geometries of 1-Popanethiolato Platinum(II) Complex with Tris[2-(diphenylphosphino)ethyl]phosphine2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Chemistry Letters 33・4

      Pages: 384-385

    • NAID

      10012846833

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Stepwise Selective Oxidation of Tris(2-(diphenylphosphino)ethyl)phosphine on Thiolato Palladium(II) Complexes2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Inorganica Chimica Acta 357・7

      Pages: 2191-2194

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phasphine-bridging Reaction2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Chemistry Letters 33・10

      Pages: 1286-1287

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Rapid Equilibrium between Trigonal-Bipyramidal and Square-Pyramidal Geometries of 1-Popanethiolato Platinum(II) Complex with Tris(2-(diphenylphosphino)-ethyl)phosphine2004

    • Author(s)
      S.Aizawa, T.Kobayashi
    • Journal Title

      Chem.Lett. 33-4

      Pages: 384-385

    • NAID

      10012846833

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Stepwise Selective Oxidation of Tris(2-(diphenylphosphino)ethyl)phosphine on Thiolato Palladium(II) Complexes2004

    • Author(s)
      S.Aizawa, T.Kawamoto, K.Saito
    • Journal Title

      Inorg.Chim.Acta 357-7

      Pages: 2191-2194

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phosphine-bridging Reaction2004

    • Author(s)
      S.Aizawa, T.Kawamoto, K.Saito
    • Journal Title

      Chem.Lett. 33-10

      Pages: 1286-1287

    • NAID

      10013658223

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Rapid Equilibrium between Trigonal-bipyramidal and Square-pyramidal Geometries of 1-propanethiolato Platinum(II) Complex with Tris[2-(diphenylphosphino)-ethyl] phosphine2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Chemistry Letters 33・4

      Pages: 384-385

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Stepwise Selective Oxidation of Tris(2-(diphenylphosphino)ethyl)-phosphine on Thiolato Palladium(II) Complexes2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Inorganica Chimica Acta 357・7

      Pages: 2191-2194

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phosphine-bridging Reaction2004

    • Author(s)
      Sen-ichi Aizawa
    • Journal Title

      Chemistry Letters 33・10

      Pages: 1286-1287

    • NAID

      10013658223

    • Related Report
      2004 Annual Research Report
  • [Book] 第5版 実験化学講座22巻 金属錯体・クラスター2004

    • Author(s)
      金森寛, 會澤宣一
    • Total Pages
      8
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] 第5版 実験化学講座 22巻 金属錯体・クラスター2004

    • Author(s)
      金森 寛
    • Total Pages
      8
    • Publisher
      丸善
    • Related Report
      2004 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Stepwise Selective Oxidation of Tris(2-(diphenylphosphino)ethyl)-phosphine on Thiolato Palladium(II) Complexes"Inorganica Chimica Acta. (in press).

    • Related Report
      2003 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Rapid Equilibrium between Trigonal-bipyramidal and Square-pyramidal Geometries of 1-popanethiolato Platinum(II) Complex with Tris[2-(diphenylphosphino)ethyl]phosphine"Chemistry Letters. 33・4. 384-385 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 金森 寛: "第5版 実験化学講座22巻 金属錯体・クラスター"丸善(印刷中).

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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