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Detoxication by biodegradation of endocrine disrupters using plants

Research Project

Project/Area Number 15550140
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionRikkyo(St.Paul's)University

Principal Investigator

HORIUCHI C.Akira  Rikkyo (St.Paul's)University, Department of Chemistry, Professor, 理学部, 教授 (60062650)

Co-Investigator(Kenkyū-buntansha) KATO Nakahide  Rikkyo(St.Paul's)University, Department of Chemistry, Lecturer, 理学部, 講師 (00142547)
NAKAMURA Kaoru  Kyoto University, Institute for Chemical Research, Associate Professor, 化学研究所, 助教授 (10101239)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2005: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2004: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2003: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsBiodegradation / Bisphenol A(BPA) / Tetrachlorobisphenol A / Bio-catalyst / Cyanidioschyzon merolae 10D / Spirulina subsalsa NIES-39 / Biosynthesis / Green Chemistry / Tetrachlorobisphenol A / Spirulina subsalsa NIES-39 / Cyanidios chyzonmerolae 10D / 分解中間体 / α-ヒドロキシ誘導体 / α-ジケトン / 環境にやさしいもの作り / Bisphenol A (BPA) / Tetrachlorobisphenol A (TCBPA) / Chlorophenol (CP) / Dichlorodiphenyltrichloroethane (DDT) / Synechococcus elongates PCC7942 / 環境汚染物質 / ラン藻(シアノバクテリア)(Synechococcus elongates PCC7942) / ナタ豆(Canavalia gladiata) / 沖縄モズク フリー盤状体(Cladosiphon okamuranus) / ムレスズメ培養細胞(Caragana chamlagu) / 源始紅藻シアニディオシゾン
Research Abstract

Biodegradation of endocrine disruptors (bisphenol A (BPA), tetrachlorobisphenol A (TCBPA), tetrabromobisphenol A (TBBPA), and 2-,3- and 4-chlorophenol etc.) was studied with bio-catalysts (Synechococcus elongates PCC7942, Canavalia gladiata, Rhizophora slylosa, Alpinia speciosa, Cladosiphon okamuranus, Synechococcus elongates PCC7942, Cyanidioschyzon merolae 10D, and Spirulina subsalsa NIES-39 etc.).
It is possible from this work todraw the following conclusions :
1.A high initial concentration (100 ppm) of chlorophenols in aqueous solution was degraded by Synechococcus elongates PCC7942 under illumination for 14 days. It was found that S. elongates PCC 7942 degraded 2-chlorophenol at 54% and tetrachlorophenol A (TCBPA) at 38%.
2 It was found that an initial TCBPA concentration of 40 ppm in aqueous solution was degraded by Cyanidioschyzon merolae 10D for 5 days.
3.It was found that Spirulina subsalsa NIES-39 is useful for "Degradation of endocrine disruptors" and "Biosynthesis toward green chemistry".

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (58 results)

All 2006 2005 2004 2003 Other

All Journal Article (44 results) Book (1 results) Patent(Industrial Property Rights) (6 results) Publications (7 results)

  • [Journal Article] Reduction of various ketone by red alga2006

    • Author(s)
      T.Utsukihara, O.Misumi, N.Kato, T.Kuroiwa, C.A.Horiuchi
    • Journal Title

      Tetrahedron Asymmetry 17

      Pages: 1179-1185

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A convenient and efficient one-pot synthesis of 3-acetylisoxazoles by the use of iron(III) salts2005

    • Author(s)
      K.Itoh, H.Sakamaki, N.Nakazato, A.Horiuchi, E.Horn, C.A.Horiuchi
    • Journal Title

      Synthesis 2005・20

      Pages: 3541-3548

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Tumor-specific cytotoxic activity of polyphenols, terpenoids, ketones and other synthetic compounds2005

    • Author(s)
      H.Sakagami, C.A.Horiuchi, et al.
    • Journal Title

      Tumor-specific cytotoxic activity of polyphenols, terpenoids, ketones and other synthetic compounds 2005

      Pages: 133-176

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] One-pot synthesis of 3-benzoyl-and 3-acetyl-1,2,4-oxadiazole derivatives using iron(III) nitrate2005

    • Author(s)
      K.Itoh, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      Synthesis 2005・12

      Pages: 1935-1938

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A new synthesis of cis-diol from alkene using iodine-ammonium cerium(IV) nitrate2005

    • Author(s)
      C.A.Horiuchi, et al.
    • Journal Title

      Snthesis 2005・17

      Pages: 2861-2864

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photo-irradiation of α-halo carbonyl compounds : a novel synthesis of α-hydroxy- and α,α'-dihydoroxyketones2005

    • Author(s)
      W.Chai, A.Takeda, M.Hara, S.-J.Ji, C.A.Horiuchi
    • Journal Title

      Tetrahedron 61

      Pages: 2453-2463

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biodegradation of Bisphenol A by Fungi2005

    • Author(s)
      W.Chai, Y.Handa, M.Suzuki, M.Saito, N.Kato, C.A.Horiuchi
    • Journal Title

      Appl. Biochem. Bioeng 120

      Pages: 175-182

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Crystal structure of cis-dichlorobis(5-methylisoxazole) platinum(II), PtCl_2(C_4H_5NO)_22005

    • Author(s)
      E.Horn, A.Horiuchi, M.Yamanaka, M.Murakami, C.A.Horiuchi
    • Journal Title

      Z. Kristallogr. NCS 220

      Pages: 239-240

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Crystal structure of dichlorobis(3,5-dimethylisoxazolato) palladium(II), PdCl_2(C_5H_7NO)_22005

    • Author(s)
      A.Horiuchi, E.Horn, K.Itoh, T.Nakahodo, M.Watabe, T.T.Takahashi, C.A.Horiuchi
    • Journal Title

      Z. Kristallogr. NCS 220

      Pages: 27-28

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Reaction of Olefins using Cerium(IV) Sulfate Tetrahydrate (CS) in Carbonyl Compounds-H_2O2005

    • Author(s)
      K.Itoh, T.Ueki, H.Mikami, W.Chai, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      Applied Organomet. Chem. 19

      Pages: 830-833

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biocatalytic asymmetric reduction of 3-acetylisoxazoles2005

    • Author(s)
      K.Itoh, H.Sakamaki, K.Nakamura, C.A.Horiuchi
    • Journal Title

      Tetrahedron Asymmetry 16

      Pages: 1403-1408

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biotransformation of valencene by culutured cells of Gynostemma pentaphyllum2005

    • Author(s)
      H.Sakamaki, K.Itoh, T.Taniai, S.Kitanaka, Y.Takagi, W.Chai, C.A.Horiuchi
    • Journal Title

      J. Mol. Catal. B. 32

      Pages: 103-106

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 有機金属錯体、金属塩を利用する合成反応から生体触媒に至るまで2005

    • Author(s)
      堀内 昭
    • Journal Title

      バイオインダストリー 23

      Pages: 371-378

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] One-pot synthesis of 3-benzoyl-and 3-acetyl-1,2,4-oxadiazole derivatives using iron(III) nitrate2005

    • Author(s)
      K.Itoh, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      Synthesis, 2005 12

      Pages: 1935-1938

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A new synthesis of cis-diol from alkene using iodine-ammonium cerium(IV) nitrate2005

    • Author(s)
      C.A.Horiuchi, et al.
    • Journal Title

      Synthesis, 2005 17

      Pages: 2861-2864

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photo-irradiation of α-halo-carbonyl compounds : a novel synthesis of α-hydroxy-and α,α'-dihydroxyketones2005

    • Author(s)
      W.Chai, A.Takeda, M.Hara, S.-J.Ji, C.A.Horiuchi
    • Journal Title

      Tetrahedron 61

      Pages: 2453-2463

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biodegradation of Bisphenol A by Fungi2005

    • Author(s)
      W.Chai, Y.Handa, M.Suzuki, M.Saito, N.Kato, C.A.Horiuchi
    • Journal Title

      Appl.Biochem.Bioeng. 120

      Pages: 175-182

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] CRC Handbook of Organic Photochemistry & Photobiology, 2^<nd> Edition2005

    • Author(s)
      C.A.Horiuchi, S.-J.Ji
    • Journal Title

      CRC Press LLC

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] One-pot synthesis of 3-benzoyl- and 3-acetyl-1,2,4-oxadiazole derivatives using iron(III) nitrate2005

    • Author(s)
      K.Itoh, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      Synthesis 2005・12

      Pages: 1935-1938

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A new synthesis of cis-diol from alkene using iodine-ammonium cerium(IV) nitrate2005

    • Author(s)
      C.A.Horiuchi, et al.
    • Journal Title

      Synthesis 2005・17

      Pages: 2861-2864

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Photo-irradiation of α-halo carbonyl compounds : a novel synthesis of α-hydroxy-and α,α'-dihydroxyketones2005

    • Author(s)
      W.Chai, A.Takeda, M.Hara, S.-J.Ji, C.A.Horiuchi
    • Journal Title

      Tetrahedron 61・

      Pages: 2453-2463

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Biodegradation of Bisphenol A by Fungi2005

    • Author(s)
      W.Chai, Y.Handa, M.Suzuki, M.Saito, N.Kato, C.A.Horiuchi
    • Journal Title

      Appl.Biochem.Bioeng 120

      Pages: 175-182

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Biodegradation of Bisphenol A by Fungi2005

    • Author(s)
      Wen Chai, Yuichi Handa, Masako Suzuki, Michihiko Saito, Nakahide Kato, C.Akira Horiuchi
    • Journal Title

      Applied Biochem.Biotechnol. 120(3)(in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A new synthesis of cis-diol from alkene using iodine-ammonium cerium (IV) nitrate2005

    • Author(s)
      C.Akira Horiuchi et al.
    • Journal Title

      Synthesis 2005(in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reaction of olefins using cerium (IV) sulfate tetrahydrate (CS) in carbonyl compounds-H_2O2005

    • Author(s)
      K.Itoh, T.Ueki, H.Mikami, W.Chai, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      Applied Organomet.Chem. (in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Photo-irradiation of α-halo carbonyl compounds : a novel synthesis of a-hydroxy- and α,α'-dihydroxyketone2005

    • Author(s)
      Wen Chai, Akihiro Takeda, Makoto Hara, Shun-Jun Ji, C.Akira Horiuchi
    • Journal Title

      Tetrahedron 61

      Pages: 2453-2463

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reduction of (+)-and (-)-camphorquinones by cyanobacteria2004

    • Author(s)
      T.Utsukihara, W.Chai, N.Kato, K.Nakamura, C.A.Horiuchi
    • Journal Title

      J. Mol. Catal. B. 31

      Pages: 19-24

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] An Efficient Gadolinium Metallocene-Based Catalyst for the Synthesis of Isoprene Rubber with Perfect 1,4-Cis Microstructure and Marked Reactivity Difference between Lanthanide Metallocenes toward Dienes As Probed by Butadiene-Isoprene Copolymerization Catalysis2004

    • Author(s)
      S.Kaita, Y.Doi, K.Kaneko, C.A.Horiuchi, Y.Wakatsuki
    • Journal Title

      Macromolecules 37

      Pages: 5860-5862

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] The Biotransformation of (±)-α-ionone and β-ionone by culutured cells of Caragana chamlagu2004

    • Author(s)
      H.Sakamaki, K.Itoh, W.Chai, Y.Hayashida, S.Kitanaka, C.A.Horiuchi
    • Journal Title

      J. Mol. Catal. B. 27

      Pages: 177-181

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Formation of isoxazole derivatives via nitrile oxide using ammonium cerium nitrate (CAN) : A novel one-pot synthesis of 3-acetyl-and 3-benzoylisoxazole derivatives2004

    • Author(s)
      K.Itoh, C.A.Horiuchi
    • Journal Title

      Tetrahedron 60

      Pages: 1671-1681

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] The Biocatalytic Oxidation of Thujopsene by Plant Cultured-cells2004

    • Author(s)
      W.Chai, Y.Hayashida, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      J. Mol. Catal. B. 27

      Pages: 55-60

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Oxidative Synthesis of αβ-Unsaturated Ketone from α-Iodo Ketone Using Peracid2004

    • Author(s)
      S.-J.Ji, M.Matsushita, C.A.Horiuchi
    • Journal Title

      Synthesis 2004

      Pages: 202-204

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Reduction of (+)- and (-)-camphorquinones by cyanobacteria2004

    • Author(s)
      T.Utsikihara, W.Chai, N.Kato, K.Nakamura, C.A.Horiuchi
    • Journal Title

      J.Mol.Catal.B. 31

      Pages: 19-24

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] The Biotransformation of (±)-α-ionone and β-ionone by culutured cells of Caragana chamlagu2004

    • Author(s)
      H.Sakamaki, K.Itoh, W.Chai, Y.Hayashida, S.Kitanaka, C.A.Horiuchi
    • Journal Title

      J.Mol.Catal.B. 27

      Pages: 177-181

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] The Biocatalytic Oxidation of Thujopsene by Plant Cultured-cells2004

    • Author(s)
      W.Chai, Y.Hayashida, H.Sakamaki, C.A.Horiuchi
    • Journal Title

      J.Mol.Catal.B. 27

      Pages: 55-60

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] An Efficient Gadolinium Metallocene-Based Catalyst for the Synthesis of Isoprene Rubber with Perfect 1,4-Cis Microstructure and Marked Reactivity Difference between Lanthanide Metallocenes toward Dienes As Probed by Butadiene Isoprene Copolymerization Catalysis2004

    • Author(s)
      S.Kaita, Y.Doi, K.Kaneko, C.A.Horiuchi, Y.Wakatsuki
    • Journal Title

      Macromolecules 37

      Pages: 5860-5862

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reduction of (+)- and (-)-camphorquinones by cyanobacteria2004

    • Author(s)
      T.Utsukihara, W.Chai, N.Kato, N.Nakamura, C.A.Horiuchi
    • Journal Title

      J.Mol.Cat.B : Enzymatic 31

      Pages: 19-24

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A novel synthesis of α-hydroxy- and α,α'-dihydroxyketone from α-iodo- and α,α'-diiod ketone using photoirradiation2003

    • Author(s)
      C.A.Horiuchi, A.Takeda, W.Chai, S.-J Ji, T.T.Takahashi
    • Journal Title

      Tetrahedron Lett. 44

      Pages: 9307-9311

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Esterification of alkene with Cerium(IV) sulfare in carboxylic acid2003

    • Author(s)
      C.A.Horiuchi, T.Fukushima, N.Furuta, W.Chai, S.-J.Ji, Y.Saito, C.Hashimoto, T.T.Takahashi, T.Sugiyama, A.Muto, Y.Sakata, S.Nozaki
    • Journal Title

      J. Chem. Research,(S) 2003

      Pages: 270-272

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Nickel- and Plladium-Catalyzed Olefin Polymerization under High Pressures2003

    • Author(s)
      N.Suzuki, J.Yu, Y.Masubuchi, A.Horiuchi, Y.Wakatsuki
    • Journal Title

      J. Polymer Sci. Part A 41

      Pages: 293-302

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ultimately Specific 1,4-cis Polymerization of 1,3-Butadiene with a Novel Gadolinium Catalyst2003

    • Author(s)
      S.Kaita, Z.Hou, M.Nishiura, Y.Doi, J.Kurazumi, C.A.Horiuchi, Y.Wakatsuki
    • Journal Title

      Maclomol. Rapid Commun 24

      Pages: 180-184

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biodegradation of Bisphenol A using the Cell Suspension Culture of Caragana chamlagu2003

    • Author(s)
      W.Chai, H.Sakamaki, S.Kitanaka, M.Saito, C.A.Horiuchi
    • Journal Title

      Biosci. Biotechnol. Biochem. 67

      Pages: 218-220

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Biotransformation of Cycloalkanediones by Caragana chamlagu2003

    • Author(s)
      W.Chai, H.Sakamaki, S.kitanaka, C.A.Horiuchi
    • Journal Title

      Bull. Chem. Soc. Jpn. 76

      Pages: 177-182

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A novel synthesis of α-hydroxy- and α,α'-dihydroxyketone from α-iodo-and α,α'-diiodo ketone using photoirradiation2003

    • Author(s)
      C.Akira Horiuchi, Akinori Takeda, Wen Chai, Sun-Jun Ji, T.Tomoyoshi Takahashi
    • Journal Title

      Tetrahedron Lett. 44

      Pages: 9307-9311

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] CRC Handbook of Organic Photochemistry & Photobiology, 2^<nd> Edition56; "Photochemical Reactions of α-Halocyclic Ketones and Related Systems2003

    • Author(s)
      C.A.Horiuchi, S.-J.Ji(分担)
    • Publisher
      CRC Press LLC
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 1,2,4-オキサジアゾール誘導体の製造方法2005

    • Inventor(s)
      堀内昭他2名
    • Industrial Property Rights Holder
      立教学院
    • Industrial Property Number
      2005-142692
    • Filing Date
      2005-05-16
    • Acquisition Date
      2006-02-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] Method for manufacturing isoxazole derivative2005

    • Inventor(s)
      堀内昭他7名
    • Industrial Property Rights Holder
      立教学院
    • Filing Date
      2005-10-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] イソオキサゾール誘導体又はジヒドロイソオキサゾール誘導体の製造方法2005

    • Inventor(s)
      堀内昭他5名
    • Industrial Property Rights Holder
      立教学院
    • Filing Date
      2005-05-16
    • Acquisition Date
      2006-04-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] ビスフェノールAの完全分解方法2004

    • Inventor(s)
      堀内昭他4名
    • Industrial Property Rights Holder
      特願 2002-264604(特開 2004-97115)
    • Filing Date
      2004-09-10
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 2-ヒドロキシケトンの製造方法

    • Inventor(s)
      堀内昭他3名
    • Industrial Property Rights Holder
      特願-2005-132861
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 塩化鉄(III)+NO2ガスを利用するイソオキサゾールの製造方法

    • Inventor(s)
      堀内昭他5名
    • Industrial Property Rights Holder
      特願-2005-132862
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] H.Sakamaki, K.Itoh, W.Chai, Y.Hayashida, S.Kitanaka, C.A Horiuchi: "The Biotransformation of (±)-α-ionone and β-ionone by culotured cells of Caragana chamlagu"J.Mol.Catal.B.Enzymatic. 27(4-6). 177-181 (2004)

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      2003 Annual Research Report
  • [Publications] K.Itoh, C.A.Horiuchi: "Formation of isoxazole derivatives via nitrile oxide using ammonium cerium nitrate (CAN) : A novel one-pot synthesis of 3-acetyl- and 3-benzoylisoxazole derivatives"Tetrahedron. 60(7). 1671-1681 (2004)

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  • [Publications] Wen Chai, Yumiko Hayashida, Hiroshi Sakamaki, C.Akira Horiuchi: "The Biocatalytic Oxidation of Thujopsene by Plant Cultured-cells"J.Mol.Catal.B.Enzymatic. 27(2). 55-60 (2004)

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      2003 Annual Research Report
  • [Publications] Shun-Jun Ji, Masatoshi Matsushita, C.Akira Horiuchi: "Oxidative Synthesis of α,β-Unsaturated Ketone from α-Iodo Ketone Using Peracid"Synthesis. 2004(2). 202-204 (2004)

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      2003 Annual Research Report
  • [Publications] C.Akira Horiuchi, Akihiro Takeda, Wen Chai, Shun-Jun Ji, T.Tomoyoshi Takahashi: "A novel synthesis of α-hydroxy- and α,α'-dihydroxyketone from α-iodo and α,α'-diiodo ketone using photoirradiation"Tetrahedron Lett.. 44(52). 9307-9311 (2003)

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      2003 Annual Research Report
  • [Publications] C.A.Horiuchi, T.Fukushima, N.Furuta, W.Chai, S.-J.Ji, Y.Saito, et al.: "Esterification of alkene with Cerium(IV) sulfate in carboxylic acid"J.Chem.Research (S). 2003(5). 270-272 (2003)

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      2003 Annual Research Report
  • [Publications] Ed.by W.Horspool, C.A.Horiuchi (Chapter 56): ""CRC Handbook of Organic Photochemistry & Photobiology, 2^<nd>d Edition" CRC Press LLC (2003.10), Chapter 56 ; "Photochemical Reactions of α-Halocyclic Ketones and Related Systems"."CRC Press. 56-1-56-23 (2003)

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      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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