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Fabrication of new type of organic semiconductors.

Research Project

Project/Area Number 15550162
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionTOKAI University (2005)
Hiroshima University (2003-2004)

Principal Investigator

KUNUGI Yoshihito  Tokai University, Engineering, Associate Professor, 工学部, 助教授 (90243518)

Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2005: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2004: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2003: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsOrganic semiconductors / Mobility / Organic devices / 有機FET / 移動度 / 有機EL
Research Abstract

New type of organic semiconductors such as (1) chalcogene containing π-conjugated compounds and (2) δ-π conjugated compounds were synthesized and applied for the organic devices (organic transistors, organic EL, etc.). For example, organic field-effect transistors (OFETs) using chalcogene-containing semiconductors as active layers have been successfully fabricated. I have found that a series of dichalcogenophenones perform as good p-type transistors. In particular, diphenyl-benzodiselenophene demonstrates a remarkably high FET performance with field-effect mobility of 0.17 cm^2/Vs and on/off current ratio of 10^5. Further investigation is underway for the similar fused selenophene compounds. I have proposed new PL imaging method using δ-π conjugated compounds. This is quite unique and simple process for the organic EL devices.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (34 results)

All 2006 2005 2004 2003 Other

All Journal Article (30 results) Publications (4 results)

  • [Journal Article] Synthesis of Silecon-Bridged Oligothiophenes and Applications to Thin Film Transistors2006

    • Author(s)
      D.-H.Kim
    • Journal Title

      Chemistry Letters 35

      Pages: 266-267

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of π-Conjugated Oligomers Containing Dithienosiloles Units2006

    • Author(s)
      D.-H.Kim
    • Journal Title

      Organometallics 25

      Pages: 1511-1516

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,7-Diphenyl[1]benzoselenopheno[3,2-b][1]benzoselenophene as a Stable Organic Semiconductor for a High-Performance Field-Effect Transistor2006

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 128

      Pages: 3044-3050

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Silicon-Bridged Oligothiophenes and Applications to Thin Film Transistors2006

    • Author(s)
      D.-H.Kim
    • Journal Title

      Chemistry Letters 35

      Pages: 266-267

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] 2,7-Diphenyl[1]benzoselenopheno[3,2-b][1]-benzoselenophene as a Stable Organic Semiconductor for a High-Performance Field-Effect Transistor2006

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 128

      Pages: 3044-3050

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,7-Diphenyl[1]benzoselenopheno[3,2-b][1]benzoselenophene as a Stable Organic Semiconductor for a High-Performance Field-Effect Transistor2006

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 128(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis of Oligomers Having a Pendant Dithienosiloles Unit and Their Applications to EL Device Materials2005

    • Author(s)
      K.-H.Lee
    • Journal Title

      Journal of Organometallic Chemistry 690

      Pages: 333-337

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Preparation of Poly (silylene-p-phenylene)s Containing a Pendant Fluorophor and Their Applications to PL Imaging2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Macromolecules 38

      Pages: 730-735

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,6-Diarylnaphtho[1,8-bc : 5,40b'c']dithophene as New High-Performance Semiconductors for Organic Field-effect Transistors2005

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 3605-3612

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Single-Crystal Field-Effect Transistors based on an Organic Selenium-Containing Semiconductor2005

    • Author(s)
      R.Zeiz
    • Journal Title

      Japanese Journal of Applied Physics 44

      Pages: 3712-3714

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Sonogashira-coupling of Diethynylsilane and Dibromoarene in Wet Solvent for the Formation of Poly[(ethynylenearyrene)-co-(disthynylenesilylenearylene)]2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Journal of Organometallic Chemistry 690

      Pages: 3951-3956

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis of Organosilanylene-Oligothenylene Alternate Polymers and Their Applications to EL Device and FET Materials2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Organometallics 24

      Pages: 4494-4496

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preparation of Polymers Containging Fe(0)-coordinated 2,5-diethynylsilole Units2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Inorganica Chimica Acta 358

      Pages: 4156-4162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preparation of Poly(silylene-p-phenylene)s Containing a Pendant Fluorophor and Their Applications to PL Imaging2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Macromolecules 38

      Pages: 730-735

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] 2,6-Diarylnaphtho[1,8-bc:5,4-b'c']-dithophene as New High-Performance Semiconductors for Organic Field-effect Transistors2005

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 3605-3612

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,6-Diarylnaphtho[1,8-bc : 5,4-b'c']dithophene as New High-Performance Semiconductors for Organic Field-effect Transistors2005

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 127

      Pages: 3605-3612

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis of Organosilanylene-Oligothenylene Altermate Polymers and Their Applications to EL Device and FET Materials2005

    • Author(s)
      J.Ohshita
    • Journal Title

      Organometallics 24

      Pages: 4494-4496

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis of Novel Spiro-Condensed Dithienosiloles and the Application to Organic FET2004

    • Author(s)
      J.Ohshita
    • Journal Title

      Chemistry Letters 33

      Pages: 892-893

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Vapor Deposited Films of Quinoidal Biselenophene and Bithiophene Derivatives as Active Layers of n-Channel Organic Field-effect Transistors2004

    • Author(s)
      Y.Kunugi
    • Journal Title

      Journal of Materials Chemistry 14

      Pages: 1367-1369

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,60Diphenylbenzo[1,2-b : 4,5-b']dichalcogenophenones : A New Class of High-performance Semiconductors for Organic Field effect Transistors2004

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 126

      Pages: 5084-5085

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] An Ambipolar Organic Field-effect Transistor Using Oligothiophene Incorporated with Two[60]Fullerenes2004

    • Author(s)
      Y.Kunugi
    • Journal Title

      Journal of Materials Chemistry 14

      Pages: 2840-2841

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Synthesis of Novel Spiro-Condensed Dithien osiloles and the Application to Organic FET2004

    • Author(s)
      J.Ohshita
    • Journal Title

      Chemistry Letters 33

      Pages: 892-893

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Vapor Deposited Films of Quinoidal Bisele nophene and Bithiophene Derivatives as Active Layers of n-Channel Organic Field-effect Transistors2004

    • Author(s)
      Y.Kunugi
    • Journal Title

      Journal of Materials Chemistry 14

      Pages: 1367-1369

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 2,6-Diphenylbenzo[1,2-b:4,5-b']dichalcogen ophenones : A New Class of High-performance Semiconductors for Organic Field effect Transistors2004

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 126

      Pages: 5084-5085

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] An Ambipolar Organic Field-effect Transistor Using Oligothiophene Incorporated with Two [60]Fullerences2004

    • Author(s)
      Y.Kunugi
    • Journal Title

      Journal of Materials Chemistry 14

      Pages: 2840-2841

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Vapor Deposited Films of Quinoidal Biselenophene and Bithiophene Derivatives as Active Lavers of n-Channel Organic Field-effect Transistors2004

    • Author(s)
      Y.Kunugi
    • Journal Title

      Journal of Materials Chemistry 14

      Pages: 1367-1369

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 2,6-Diphenylbenzo[1,2-b:4,5-b']dichalcogenophenones : A New Class of High-performanc Semiconductors for Organic Field-effect Transistor2004

    • Author(s)
      K.Takimiya
    • Journal Title

      Journal of the American Chemical Society 126

      Pages: 5084-5085

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Influece of π-conjugation length on mobilities of charge carriers in conducting polymers2003

    • Author(s)
      Y.Harima
    • Journal Title

      Journal of Materials Chemistry 13

      Pages: 1298-1305

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hole-transporting properties of organosilanylene-diethynylpyrene and diethystlanthracene alternating polymers. Applications to patterning of light-emitting images2003

    • Author(s)
      J.Ohshita
    • Journal Title

      Journal of Organometallic Chemistry 678

      Pages: 33-38

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hole-transporting properties of organosilanylene- diethynylpyrene and diethyntlanthracene alternating polymers. Applications to patterning of light-emitting images2003

    • Author(s)
      J.Ohshita
    • Journal Title

      Journal of Organometallic Chemistry 678

      Pages: 33-38

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] Y.Kunugi: "Organic field-effect transistor using oligoselenophene as an active layer"Chemistry of Materials. 15. 6-7 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Ohshita: "Synthesis of organosilanylene-pentathienylene alternating polymers and their application to the hole-transporting materials in double-layer EL devices"Journal of Organometallic Chemistry. 665. 29-32 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Harima: "Influece of π-conjugation length on mobilities of charge carriers in conducting polymers"Journal of Materials Chemistry. 13. 1298-1305 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Ohshita: "Hole-transporting properties of organosilanylene-diethynylpyrene and diethyntlanthracene alternating polymers. Applications to patterning of light-emitting images"Journal of Organometallic Chemistry. 678. 33-38 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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