Fabrication of Porous Silicon Carbide for Environmental Use based on Free Energy Theory
| Project/Area Number |
15560592
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
TANAKA Hidehiko National Institute for Materials Science, Advanced Materials Laboratory, Director, 物質研究所, ディレクター (40343868)
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| Co-Investigator(Kenkyū-buntansha) |
HIROSAKI Naoko National Institute for Materials Science, Advanced Materials Laboratory, Senior Researcher, 物質研究所, 主席研究員 (80343838)
NISHIMURA Toshiyuki National Institute for Materials Science, Advanced Materials Laboratory, Senior Researcher, 物質研究所, 主幹研究員 (50354428)
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| Project Period (FY) |
2003 – 2005
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| Project Status |
Completed (Fiscal Year 2005)
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| Budget Amount *help |
¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2005: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2004: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2003: ¥1,200,000 (Direct Cost: ¥1,200,000)
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| Keywords | Environmental use / Porous materials / Silicon carbide / Sintering and grain growth rates / Diffusion / New free energy theory / 理論 / 自由エネルギー / 粒成長 / 速度式 / フィルター / 表面エネルギー / 過剰自由エネルギー / 物質の速度式 / 粒子の変形 / 結晶転移エネルギー / 粒界エネルギー / 金属ホウ化物 |
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| Research Abstract |
We developed silicon carbide porous materials in order to apply to environmental use. We noticed that grain growth of fine powder made possible to fabricate porous materials.
First, we reorganized that sintering and grain growth theory in the fabrication of ceramics was important as basic science. Therefore, we proposed free energy theory for material transport. In the theory, a rate of diffusion was proportional to excess free energy, a diffusion constant and a geometry factor. The theory was totally different from traditional sintering and grain growth established so far. We could analyze from this theory the role of surface energy and other free energies on the material transport.
Second, we investigate new compounds that accelerated diffusion constant and found Al-B-C compounds. The compounds decreased sintering and grain growth temperatures, and also enabled us to use a sophisticated hot isostatic pressing (HIP) resulting in fabricating completely dense silicon carbide.
Third, we studied silicon carbide and metal boride composites, and characterized grain growth and densification behavior. Some of metal borides elongated SiC particles.
Finally, from these results, we tried to make porous material utilizing transformation induced material transport and diffusion accelerated grain growth. We used two types of silicon carbides different in crystal structure and used the Al-B-C additives that we already found. The raw powders behaved initial grain growth accelerated by surface energy and then final large grain growth due to crystal transformation. We succeeded in fabrication of strong porous silicon carbide materials having about 50% porosity and 100 MP strength that are suitable environmental use.
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Report
(4 results)
Research Products
(15 results)
