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Development of Formable Ultra High-strength TRIP-aided Steel Sheets and Hydrogen Embrittlement Performance

Research Project

Project/Area Number 15560624
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionShinshu University

Principal Investigator

SUGIMOTO Koh-ichi  Shinshu University, Faculty of Engineering, Professor, 工学部, 教授 (50094272)

Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2004: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2003: ¥2,300,000 (Direct Cost: ¥2,300,000)
Keywordsultra high-strength steel / TRIP-aided steel / retained austenite / formability / hydrogen embrittlement / delayed fracture / bainitic ferrite / warm forming / 低合金TRIP鋼
Research Abstract

In order to develop formable ultra high-strength TRIP-aided sheet steels with bainitic ferrite matrix (TBF steels), the effects of heat treatment conditions and alloying element on microstructure, retained austenite characteristics, tensile properties and formability of the TBF steels have been examined. In addition, hydrogen embrittlement performance of the steels was investigated. The main results are summarized as follows.
(1)Complex additions of 0.02-0.05%Nb and 0.1-0.2%Mo to 0.2%C-1.5%Si-1.5%Mn TBF steel improved the balance of ductility and stretch-flangeability, accompanied with increase in tensile strength by 1100-200MPa due to fine NbMoC precipitates. This was caused by that prior austenitic grain and lath structure were refined and retained austenite stability was highly maintained. The complex additions also raised optimum austempering temperature to 450-500℃ which corresponds to hot-dip galvanizing temperature.
(2)Total elongation of the TBF steel was considerably improved by warm forming of 50-100℃ and 200-300℃. This was associated with strain-induced martensite or bainite transformation of retained austenite and/or dynamic aging.
(3)Complex additions of 0.02%Nb and 0.1%Mo to 0.2%C-1.5%Si-1.5%Mn TBF steel achieved far high delayed fracture strength. This was caused by that retained austenite films and fine NbMoC precipitates trapped most of solute hydrogen and resultantly suppressed grain boundary fracture or cleavage fracture.
(4)Commercial 980 and 1470MPa grade 0.2-0.25%C-1.5Si-Mn-NbMMo TBF steel sheets were produced on continuous annealing line of a certain company. It was certified that the sheets have a good stretch-flangeability and high hydrogen embrittlement resistance.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (45 results)

All 2005 2004 Other

All Journal Article (19 results) Patent(Industrial Property Rights) (20 results) Publications (6 results)

  • [Journal Article] 超高強度低合金TRIP型ベイニテイックフェライト鋼板の温間成形性2005

    • Author(s)
      杉本公一, 宋 星武, 坂口淳也, 長坂明彦, 鹿島高弘
    • Journal Title

      鉄と鋼 91・3

      Pages: 278-284

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ultra High Strength C-Si-Mn-Nb-Mo TRIP-Aided Sheet Steels2005

    • Author(s)
      Koh-ichi Sugimoto, Toshiki Muramatsu, Shun-ichi Hashimoto, Yoh-ichi Mukai
    • Journal Title

      Proc.of MS&T'05

      Pages: 1-10

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Warm Formability of Ultra High-Strength Low Alloy TRIP-Aided Sheet Steels with Bainitic Ferrite Matrix2005

    • Author(s)
      K.Sugimoto, S.Song, J.Sakaguchi, A.Nagasaka, T.Kashima
    • Journal Title

      Tetsu-to-Hagane Vol.91, No.2

      Pages: 278-284

    • NAID

      110001457838

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ultra High Strength C-Si-Mn-Nb-Mo TRIP-Aided Sheet Steels2005

    • Author(s)
      K.Sugimoto, T.Muramatsu, S.Hashimoto, Y.Mukai
    • Journal Title

      Proc.of MS&T'05

      Pages: 1-10

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Development of 980-1470MPa Grade Low Alloy TRIP-Aided Sheet Steels for Automotive Applications2005

    • Author(s)
      K.Sugimoto, T.Muramatsu, Y.Mukai, S.Hashimoto
    • Journal Title

      Proc.of ICTP 2005

      Pages: 1-8

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 超高強度低合金TRIP型ベイニティックフェライト鋼板の温間成形性2005

    • Author(s)
      杉本公一, 宋 星武, 坂口 淳, 長坂明彦, 鹿島高弘
    • Journal Title

      鉄と鋼 91,2

      Pages: 278-284

    • NAID

      110001457838

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 1000-1800MPa級超高強度低合金TRIP鋼の遅れ破壊特性2005

    • Author(s)
      北條智彦, 杉本公一, 向井陽一, 赤水 宏, 池田周之
    • Journal Title

      CAMP-ISIJ 18,3

      Pages: 554-554

    • NAID

      10014481318

    • Related Report
      2004 Annual Research Report
  • [Journal Article] C-Si-Mn系TRIP型ベイニティックフェライト鋼の諸特性に及ぼすNb-Mo複合添加の影響2005

    • Author(s)
      村松俊紀, 杉本公一, 橋本俊一, 向井陽一, 池田周之
    • Journal Title

      CAMP-ISIJ 18,3

      Pages: 555-555

    • NAID

      10014481322

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 超高強度低合金TRIP鋼の水素脆性2004

    • Author(s)
      北條智彦, 宋 星武, 杉本公一, 池田周之
    • Journal Title

      鉄と鋼 90・3

      Pages: 177-182

    • NAID

      110001457688

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Hydrogen Embrittlement of Ultra High Strength Low Alloy TRIP-Aided Steels2004

    • Author(s)
      T.Hojo, K.Sugimoto, Y.Mukai, S.Ikeda
    • Journal Title

      Second Int.Conf.of Advanced Structural Steels(ICASS 2004)

      Pages: 638-641

    • NAID

      110001457688

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ultra High-Strength Low-Alloy TRIP-Aided Sheet Steels with Bainitic Ferrite Matrix2004

    • Author(s)
      K.Sugimoto, S.Hashimoto, S.Ikeda
    • Journal Title

      Int.Conf.on Advanced High-Strength Sheet Steels for Auto motive Applications Proceedings (AHSSS Proceedings)

      Pages: 63-70

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Ductility of 0.1-0.6C-1.5Si-1.5Mn Ultra High-strength Low-alloy TRIP-aided Sheet Steels with Bainitic Ferrite Matrix2004

    • Author(s)
      K.Sugimoto, M.Tsunezawa, T.Hojo, S.Ikeda
    • Journal Title

      ISIJ International 44・9

      Pages: 1608-1614

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Development of 980-147OMPa Grade Low Alloy TRIP-Aided Sheet Steels for Automotive Applications2004

    • Author(s)
      Koh-ichi Sugimoto, Toshiki Muramatsu, Yoh-ichi Mukai, Shun-ichi Hashimoto
    • Journal Title

      Proc.of ICTP 2005

      Pages: 1-8

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Hydrogen Embrittlement of Ultra High-Strenhth Low Alloy TRIP-Aided Steels2004

    • Author(s)
      T.Hojo, S.Song, K.Sugimoto, S.Ikeda
    • Journal Title

      Tetsu-to-Hagane Vol.90, No.3

      Pages: 177-182

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Hydrogen Embrittlement of Ultra High Strength Low Alloy TRIP-Aided Steel2004

    • Author(s)
      T.Hojo, K.Sugimoto, Y.Mukai, S.Ikeda
    • Journal Title

      ICASS 2004

      Pages: 638-641

    • NAID

      110001457688

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ultra High-Strength Low-Alloy TRIP-Aided Sheet Steels with Bainitic Ferrite Matrix2004

    • Author(s)
      K.Sugimoto, S.Hashimoto, S.Ikeda
    • Journal Title

      AHSSS Proceedings

      Pages: 63-70

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ductility of 0.1-0.6C-1.5Si-1.5Mn Ultra High-strength Low-alloy TRIP-aided Sheet Steels with Bainitic Ferrite Matrix2004

    • Author(s)
      K.Sugimoto, M.Tsunezawa, T.Hojo, S.Ikeda
    • Journal Title

      ISIJ International Vol.44, No.9

      Pages: 1608-1614

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ductility of 0.1-0.6C-1.5Si-1.5Mn Ultra High-strength Low-alloy TRIP-aided Sheet Steels with Bainitic Ferrite Matrix2004

    • Author(s)
      K.Sugimoto, M.Tsunezawa, T.H.Hojo, S.Ikeda
    • Journal Title

      ISIJ International 44,9

      Pages: 1608-1614

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 超高強度低合金TRIP鋼の遅れ破壊特性2004

    • Author(s)
      村瀬朋久, 北條智彦, 杉本公一, 向井陽一
    • Journal Title

      日本金属学会・日本鉄鋼協会北陸信越支部平成16年度連合講演会概要集

      Pages: 110-110

    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 耐水素脆化特性に優れた超高強度鋼板及びその製造方法2005

    • Inventor(s)
      向井 陽一, 赤水宏, 池田 周之, 槇井 浩一(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-003075
    • Filing Date
      2005-01-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] Ultra-high Strength Steel Sheet Having Excellent Hydrogen Embrittlement Resistance, and Method for Manufacturing The Same2005

    • Inventor(s)
      Hiroshi Akamizu, Shushi Ikeda, Koichi Makii, Yoichi Mukai, Koichi Sugimoto
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Filing Date
      2005-01-09
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] Ultra-high Strength Steel Sheet Having Excellent Hydrogen Embrittlement Resistance, and Method for Manufacturing The Same2005

    • Inventor(s)
      Hiroshi Akamizu, Shushi Ikeda, Koichi Makii, Yoichi Mukai, Koichi Sugimoto
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Filing Date
      2005-01-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化感受性に優れた超高強度ボルト2005

    • Inventor(s)
      池田 周之, 湯瀬 文雄(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-021501
    • Filing Date
      2005-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化感受性に優れた高強度ばね用鋼2005

    • Inventor(s)
      池田 周之, 湯瀬 文雄(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-021502
    • Filing Date
      2005-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 伸び及び伸びフランジ性に優れた低降伏比高強度冷延およびめっき鋼板並びにその製造方法2005

    • Inventor(s)
      池田 周之, 赤水 宏, 槇井 浩一, 向井 陽一(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-021858
    • Filing Date
      2005-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] High Strength and Low Yield Ratio Cold Rolled Steel Sheet and Method of Manufacturing The Same2005

    • Inventor(s)
      Shushi Ikeda, Hiroshi Akamizu, Koichi Makii, Yoichi Mukai, Koichi Sugimoto
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Filing Date
      2005-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] High Strength and Low Yield Ratio Cold Rolled Steel Sheet and Method of Manufacturing The Same2005

    • Inventor(s)
      Shushi Ikeda, Hiroshi Akamizu, Koichi Makii, Yoichi Mukai, Koichi Sugimoto
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Filing Date
      2005-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 強度と加工性のバランスに優れた高強度冷延鋼板およびめっき鋼板2005

    • Inventor(s)
      鹿島 高弘, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-098952
    • Filing Date
      2005-03-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 均一伸びに優れた高強度冷延鋼板およびその製造方法2005

    • Inventor(s)
      赤水 宏, 向井 陽一, 池田 周之(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2005-098953
    • Filing Date
      2005-03-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 伸びおよび伸びフランジ性に優れた低降伏比高強度冷延鋼板およびめっき鋼板並びにその製造方法2005

    • Inventor(s)
      杉本 公一, 池田 周之, 赤水 宏, 横井 浩一, 向井 陽一
    • Industrial Property Rights Holder
      (株)信州TLO神戸製鋼所
    • Industrial Property Number
      2005-021858
    • Filing Date
      2005-01-28
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 耐水素脆化特性に優れた超高強度鋼板,及びその製造方法2004

    • Inventor(s)
      赤水 宏, 池田 周之, 槇井 浩一, 向井 陽一(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 杉本 公一
    • Industrial Property Number
      2004-004727
    • Filing Date
      2004-01-09
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 伸びおよび伸びフランジ性に優れた低降伏比高強度冷延鋼板およびめっき鋼板並びにその製造方法2004

    • Inventor(s)
      池田 周之, 赤水 宏, 槇井 浩一, 向井 陽一(神戸製鋼), 杉本 公一
    • Industrial Property Rights Holder
      神戸製鋼, 杉本 公一
    • Industrial Property Number
      2004-019701
    • Filing Date
      2004-01-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 成形性に優れた高強度冷延鋼板及びめっき鋼板2004

    • Inventor(s)
      池田 周之, 向井 陽一, 赤水 宏, 槇井 浩一, (神戸製鋼), 杉本 公一, 橋本俊一(CBMMアジア)
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-126916
    • Filing Date
      2004-04-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381230
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381231
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381232
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性及び加工性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381243
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性及び加工性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381244
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 耐水素脆化特性及び加工性に優れた超高強度薄鋼板2004

    • Inventor(s)
      池田 周之, 湯瀬 文雄, 衣笠 潤一郎, 向井 陽一, 赤水 宏(神戸製鋼), 杉本 公一, 北條 智彦
    • Industrial Property Rights Holder
      神戸製鋼, 信州大学
    • Industrial Property Number
      2004-381245
    • Filing Date
      2004-12-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] 北條智彦, 宋 星武, 杉本公一, 池田周之: "超高強度低合金TRIP鋼の水素脆性"鉄と鋼. Vol.90, No.3. 177-182 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Sugimoto, A.Hayakawa, S.Hashimoto, S.Ikeda: "Development of High Strength Low Alloy TRIP-Aided Steels with Ultra Fine Grain"Mater.Sci., Forum. Vols.426-432. 1469-1474 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Sugimoto, S.Hashimoto, S.Ikeda: "Ultra High-Strength Low-Alloy TRIP-Aided Sheet Steels with Bainitic Ferrite Matrix, June 6-9, 2004"Proc.of Int.Conf.on Advanced High-Strength Sheet Steels for Automotive Applications, Cororado, USA. (発表予定). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Hojo, K.Sugimoto, Y.Mukai, S.Ikeda: "Hydrogen Embrittlement of Ultra High Strength Low Alloy TRIP-Aided Steels"Second Int.Conf.of Advanced Structural Steels (ICASS 2004), April 14-16,2004, Shanghai, China. (発表予定). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 北條智彦, 宋 星武, 二タ村朝比古, 杉本公一, 池田周之, 黛 正巳: "超高強度低合金TRIP鋼の靭性に及ぼす水素の影響"M&M2003材料力学部門講演会講演論文集. No.03-11. 793-794 (2004)

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      2003 Annual Research Report
  • [Publications] 杉本公一, 経澤道高, 長坂明彦, 橋本俊一, 池田周之, 向井陽一: "Nb-Mo添加TRIP型ベイニティックフェライト鋼板の成形性"CAMP-ISIJ. Vol.17, No.3. 500 (2004)

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      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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