Control of nanostructure of biomaterials and utilization of biomass with supercritical fluid process
Project/Area Number |
15580302
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Boundary agriculture
|
Research Institution | Niigata University of Pharmacy and Applied Life Sciences |
Principal Investigator |
FUJII Tomoyuki Niigata University of Pharmacy and Applied Life Sciences, Faculty of Applied Life Sciences, Dept.of Food Science, Professor, 応用生命科学部, 教授 (40228953)
|
Co-Investigator(Kenkyū-buntansha) |
TAKAGI Masamichi Niigata University of Pharmacy and Applied Life Sciences, Faculty of Applied Life Sciences, Dept.of Applied Life Sciences, Professor, 応用生命科学部, 教授 (50018339)
|
Project Period (FY) |
2003 – 2004
|
Project Status |
Completed (Fiscal Year 2004)
|
Budget Amount *help |
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2004: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2003: ¥1,700,000 (Direct Cost: ¥1,700,000)
|
Keywords | supercritical fluid / subcriticak water / biomass / hot-compressed water treatment / activation volume / オリゴ糖 |
Research Abstract |
Soluble starch was treated with hot-compressed-water at the temperature range of 160-210 C using a continuous-flow reactor. Apart of the sample was converted to reducing oligosaccharides by hydrolysis with the hot-compressed- water. At 160-190 C the hydrolysis reaction occurred with the hot-compressed-water depending on a retention time. Over 200 C the behavior of generation of reducing oligosaccharides was found to be observed a maximum with increase of the retention time. From the results both hydrolysis reaction and resolution of a saccharide body occurred in the reaction mixture. The activation volumes of hydrolysis reaction at the range of 160-170 C were about 350 mL/mol. On the other hand, those at the range of 180-210 C were the values of 30-85 mL/mol. It was thought that the mechanism of hydrolysis reaction was different depending on the reaction temperature.
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Report
(3 results)
Research Products
(7 results)