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Properties of ultralow reflectance Si formed by surface structure chemical transfer method

Research Project

Project/Area Number 15H01997
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural physics
Research InstitutionOsaka University

Principal Investigator

Kobayashi Hikaru  大阪大学, 産業科学研究所, 教授 (90195800)

Co-Investigator(Kenkyū-buntansha) 松本 健俊  大阪大学, 産業科学研究所, 准教授 (20390643)
今村 健太郎  大阪大学, 産業科学研究所, 助教 (60591302)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,380,000 (Direct Cost: ¥32,600,000、Indirect Cost: ¥9,780,000)
Fiscal Year 2017: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Fiscal Year 2016: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2015: ¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
Keywordsシリコンナノクリスタル層 / 屈折率勾配 / 太陽電池 / graded band-gap構造 / ナノ材料 / 表面・界面物性 / 表面パッシベーション / 反射率 / 結晶シリコン / シリコンナノクリスタル / ネットワーク構造 / 屈折率 / 化学的転写法 / 傾斜構造 / マイクロ、ナノデバイス / 傾斜材料
Outline of Final Research Achievements

The valence band energy of a nanocrsytalline Si layer shows a downward shift with the surface structure chemical transfer treatment time, and the energy shift reaches ~0.4eV at maximum. The conduction band energy, on the other hand, is shifted upward by ~0.2eV at maximum. The conduction band of the nanocrystalline Si layer after formation of pn-junction is almost flat. These results show that the nanocrystalline Si layer possesses the grade band-gap structure, leading to effective separation of photo-generated electron hole pairs in the nanocrystalline Si layer, and thus preventing surface recombination.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (37 results)

All 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (14 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 14 results) Presentation (18 results) (of which Int'l Joint Research: 13 results,  Invited: 8 results) Remarks (2 results)

  • [Int'l Joint Research] スロバキア科学アカデミー(スロバキア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Zilina大学(スロバキア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Slovac Academy of Science/Zilina University(スロバキア)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Improvement of conversion efficiency of silicon solar cells by submicron-textured rear reflector obtained by metal-assisted chemical etching2017

    • Author(s)
      D. Irishika, Y. Onitsuka, K. Imamura, and H. Kobayashi
    • Journal Title

      Solar RRL

      Volume: 1 Issue: 7

    • DOI

      10.1002/solr.201700061

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface nanocrystalline Si structure for highly efficient crystalline Si solar cells2017

    • Author(s)
      K. Imamura, D. Irishika, and H. Kobayashi
    • Journal Title

      Prog. Photovolt.

      Volume: 25 Issue: 5 Pages: 358-366

    • DOI

      10.1002/pip.2867

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of ultra-low reflectivity for nanocrystalline Si/crystalline Si structure formed by surface structure chemical transfer method2017

    • Author(s)
      K. Imamura, D. Irishika, and H. Kobayashi
    • Journal Title

      J. Appl. Phys.

      Volume: 121 Issue: 1

    • DOI

      10.1063/1.4973531

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ight trapping of crystalline Si solar cells by use of nanocrystalline Si layer plus pyramidal texture2017

    • Author(s)
      K. Imamura, T. Nonaka, Y. Onitsuka, D. Irishika, H. Kobayashi
    • Journal Title

      Applied Surface Science

      Volume: 395 Pages: 50-55

    • DOI

      10.1016/j.apsusc.2016.04.132

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regarding the optical properties of porous layers prepared on Si substrates2017

    • Author(s)
      E. Pincik, R. Brunner, H. Kobayashi, P. Vojtek, Z. Zabudla, M. Mikula, J. Gregus and M. Kucera
    • Journal Title

      J. Energy Power Eng.

      Volume: 11 Issue: 11 Pages: 687-692

    • DOI

      10.17265/1934-8975/2017.11.002

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] About complex refractive index of black Si2017

    • Author(s)
      E. Pincik, R. Brunner, H. Kobayashi, and M. Mikula
    • Journal Title

      J. Elect. Eng.

      Volume: 68 Issue: 7 Pages: 81-83

    • DOI

      10.1515/jee-2017-0063

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Properties of nanocrystalline Si layers embedded in structure of solar cell2017

    • Author(s)
      S. Jurecka, K. Imamura, T. Matsumoto, and H. Kobayashi
    • Journal Title

      J. Elect. Eng.

      Volume: 68 Issue: 7 Pages: 48-52

    • DOI

      10.1515/jee-2017-0055

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Investigation of deep defects in nanocrystalline-Si/Si interfaces using acoustic spectroscopy2017

    • Author(s)
      P. Bury, S. Hardon, H. Kobayashi, and K. Imamura
    • Journal Title

      J. Elect. Eng.

      Volume: 68 Issue: 7 Pages: 43-47

    • DOI

      10.1515/jee-2017-0054

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multifractal analysis and optical properties of nanostructured silicon layers2017

    • Author(s)
      S. Jurecka, T. Matsumoto, K. Imamura, H. Kobayashi
    • Journal Title

      Applied Surface Science

      Volume: 395 Pages: 150-156

    • DOI

      10.1016/j.apsusc.2016.04.059

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] About the optical properties of oxidized black silicon structures2017

    • Author(s)
      E. Pincik, R. Brunner, H. Kobayashi, M. Mikula, M. Kucera, P. Svec Jr., J. Gregus;, P. Vojtek, Z. Zabria, K. Imamura, M. Zahoran
    • Journal Title

      Applied Surface Science

      Volume: 395 Pages: 185-194

    • DOI

      10.1016/j.apsusc.2016.05.035

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrathin SiO2 layer formed by the nitric acid oxidation of Si (NAOS) method to improve the thermal-SiO2/Si interface for crystalline Si solar cells2017

    • Author(s)
      T. Matsumoto, H. Nakajima, D. Irishika, T. Nonaka, K. Imamura, H. Kobayashi
    • Journal Title

      Applied Surface Science

      Volume: 395 Pages: 56-60

    • DOI

      10.1016/j.apsusc.2016.06.001

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The photoluminescence of multicolor silicon2016

    • Author(s)
      E. Pincik, R. Brunner, H. Kobayashi, M. Mikula, P. Vojtek, J. Gregus, Z. Zabudla, K. Imamura, P. Svec, Jr.
    • Journal Title

      J. Chin. Adv. Mater. Soc.

      Volume: in press Issue: 2 Pages: 158-171

    • DOI

      10.1080/22243682.2016.1151374

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultralow Reflectivity and Light Trapping for Crystalline Si Solar Cells by Use of Surface Structure Chemical Transfer Method on Pyramidal Textured Surfaces2015

    • Author(s)
      K. Imamura, T. Nonaka, D. Irishika, H. Kobayashi
    • Journal Title

      ECS Solid State Lett.

      Volume: 4 Issue: 12 Pages: Q63-Q65

    • DOI

      10.1149/2.0091512ssl

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultralow reflectivity surfaces by formation of nanocrystalline Si layer for crystalline Si solar cells2015

    • Author(s)
      D. Irishika, K. Imamura, H. Kobayashi
    • Journal Title

      Sol. Energ. Mat. Sol. C.

      Volume: 141 Pages: 1-6

    • DOI

      10.1016/j.solmat.2015.06.005

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] High conversion efficiency black Si solar cells formed by use of surface structure chemical transfer (SSCT) method2017

    • Author(s)
      Hikaru Kobayashi
    • Organizer
      Progress in Applied Surface, Interface and Thin Film Science 2017 (SURFINT-SREN V)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Achievement of 20% conversion efficiency from simple structure crystalline Si solar cells fabricated by use of surface structure chemical transfer method2017

    • Author(s)
      Hikaru Kobayashi
    • Organizer
      Taiwan Vacuum Society 2017 (TVS-2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly efficient black Si solar cells fabricated by use of surface structure chemical transfer method2017

    • Author(s)
      Hikaru Kobayashi
    • Organizer
      Collaborative Conference on Materials Research (CCMR 2017), International Convention Center (ICC)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication and application of Si nanocrystals and nanopowder for energy devices2017

    • Author(s)
      Hikaru Kobayashi
    • Organizer
      EMN Meeting on Surface and interface
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電気化学的手法による4H-SiC基板の超平坦化とそのメカニズム2016

    • Author(s)
      赤井智喜,今村健太郎,小林光
    • Organizer
      第36回表面科学学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] 化学的転写法により形成した極低反射Si表面の光学特性と、高効率太陽電池への応用2016

    • Author(s)
      今村健太郎,入鹿大地,鬼塚裕也,小林光
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 化学的転写法による極低反射表面と裏面ナノ構造を用いた結晶Si太陽電池の変換効率向上2016

    • Author(s)
      鬼塚裕也,入鹿大地,今村健太郎,小林光
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ultra-low reflectivity surfaces with nano-structured Si layer2015

    • Author(s)
      Y. Onitsuka, K. Imamura, H. Kobayashi
    • Organizer
      The 19th SANKEN International Symposium, The 14th SANKEN Nanotechnology International Symposium
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府、吹田市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ulta-low reflectivity polycrystalline Si surfaces by formation of nanocrystalline Si layer and achievement of high efficiency crystalline Si solar cells2015

    • Author(s)
      D. Irishika, K. Imamura, H. Kobayashi
    • Organizer
      The 19th SANKEN International Symposium, The 14th SANKEN Nanotechnology International Symposium
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府、吹田市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Si surface control for achieving high conversion efficiencies of crystalline Si solar cells2015

    • Author(s)
      H. Kobayashi, D. Irishika, T. Nonaka, K. Imamura
    • Organizer
      Progress in applied surface, interface and thin film science 2015
    • Place of Presentation
      Italy
    • Year and Date
      2015-11-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 18.9% efficiency crystalline Si solar cells with simple structure fabricated by surface2015

    • Author(s)
      H. Kobayashi
    • Organizer
      ACTSEA-2015
    • Place of Presentation
      Taiwan
    • Year and Date
      2015-11-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 化学的転写法により形成した極低反射率をもつSiナノクリスタル層/Si構造の光学特性2015

    • Author(s)
      今村健太郎,入鹿大地,野中啓章,小林光
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府、吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 化学的転写法で作製したナノクリスタルSi層に対する表面パッシベーションと結晶Si太陽電池の高効率化2015

    • Author(s)
      野中啓章,入鹿大地,今村 健太郎,小林 光
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県、名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ultra‐low reflectivity crystalline Si surfaces fabricated by use of SSCT method and application to high efficiency Si solar cells2015

    • Author(s)
      K. Imamura, D. Irishika, T. Nonaka, H. Kobayashi
    • Organizer
      1st International Conference on Applied Surface Science
    • Place of Presentation
      China
    • Year and Date
      2015-07-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ultralow reflectivity crystalline Si surfaces by formation of nanocrystalline Si layer and application to polycrystalline Si solar cells2015

    • Author(s)
      D. Irishika, K. Imamura, H. Kobayashi
    • Organizer
      1st International Conference on Applied Surface Science
    • Place of Presentation
      China
    • Year and Date
      2015-07-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of ultra‐low reflectivity Si solar cells with light trapping effect to achieve a high conversion efficiency2015

    • Author(s)
      T. Nonaka, D. Irishika, K. Imamura, H. Kobayashi
    • Organizer
      1st International Conference on Applied Surface Science
    • Place of Presentation
      China
    • Year and Date
      2015-07-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chemical methods for improvement of performance of crystalline Si solar cells2015

    • Author(s)
      H. Kobayashi
    • Organizer
      2015 Symposium for Eco Multi-Functional Nano Materials & ISO/TC 107 Workshop
    • Place of Presentation
      Korea
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Improvement of crystalline solar cell characteristics by formation of ultralow reflectivity surface using surface structure chemical transfer method2015

    • Author(s)
      H. Kobayashi
    • Organizer
      The 5th Asia-Africa Sustainable Energy Forum and Jointly with 7th International Workshop on Sahara Solar Breeder
    • Place of Presentation
      筑波大学筑波キャンパス(茨城県、つくば市)
    • Year and Date
      2015-05-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 大阪大学 産業科学研究所 小林研究室

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/fcm/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] シリコン太陽電池の研究

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/fcm/research-PV.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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