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Development of Microscopic Analysis Method of Organic Solar Cells

Research Project

Project/Area Number 15H02023
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionUniversity of Tsukuba

Principal Investigator

Takeuchi Osamu  筑波大学, 数理物質系, 准教授 (20361321)

Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥42,120,000 (Direct Cost: ¥32,400,000、Indirect Cost: ¥9,720,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2016: ¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2015: ¥23,140,000 (Direct Cost: ¥17,800,000、Indirect Cost: ¥5,340,000)
Keywords走査プローブ顕微鏡 / 太陽電池 / 走査トンネル顕微鏡 / 有機太陽電池 / 有機LED / 有機薄膜太陽電池 / 光電変換
Outline of Final Research Achievements

A microscopic measurement technique that can visualize the nanometer-scale distribution of local conversion performance in highly non-uniform organic solar cell devices was developed, where a scanning tunneling microscope (STM) is used to locally collect the photocarriers that were generated in an illuminated solar cell. The developed technique, light-modulated STM (LM-STM) allows us to acquire local I-V characteristics of solar cells as well as their illumination intensity dependence. It was pointed out that, compared to the macroscopic device I-V characteristics, the acquired local I-V characteristics are generally much more strongly affected by the inner resistance of the device materials and a guideline how to extract the local carrier generation rate and photovoltage from such local I-V characteristics is given. A new type of pulse-laser-assisted time-resolved STM system was developed to measure the local carrier life time in a solar cell device.

Academic Significance and Societal Importance of the Research Achievements

製造の省力化・省コスト化のため、最新の太陽電池はアモルファスや多結晶のような不均一構造を持つことが多く、デバイス内には高性能な部分と低性能な部分とが混在している。局所性能を測定可能な顕微鏡はそのような複雑なデバイスの動作を理解し、さらなる高効率化を目指すために特に有用である。本研究は光変調トンネル分光法により局所性能を評価可能であることを示しただけでなく、得られる結果をどのように解釈すれば局所性能を決める重要な物理パラメータを取り出せるかという指標を与えるものである。また光キャリア寿命という別のパラメータを計測するための時間分解トンネル顕微鏡の開発も行った。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (30 results)

All 2019 2018 2017 2016 2015 Other

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 3 results) Presentation (23 results) (of which Int'l Joint Research: 13 results,  Invited: 1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Externally triggerable optical pump-probe scanning tunneling microscopy2019

    • Author(s)
      Hiroyuki Mogi, Wang Zihan, Kikuchi Ryusei, Cheul-hyun Yoon, Shoji Yoshida, Osamu Takeuchi, and Hidemi Shigekawa
    • Journal Title

      Appl. Phys. Express

      Volume: 12、2 Issue: 2 Pages: 025005-025005

    • DOI

      10.7567/1882-0786/aaf8b2

    • NAID

      210000135565

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] New delay time modulation sequence for optical-pump-probe STM with minimized light intensity fluctuation2019

    • Author(s)
      Osamu Takeuchi, Hiroyuki Mogi, Zi-han Wang, Atsushi Taninaka, Shoji Yoshida, and Hidemi Shigekawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local Performance Evaluation of Organic Solar Cell Using Scanning Tunneling Microscopy (STM)2017

    • Author(s)
      Osamu Takeuchi, Takahiro Ochiai, Shoji Yoshida and Hidemi Shigekawa
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 60 Issue: 10 Pages: 381-387

    • DOI

      10.3131/jvsj2.60.381

    • NAID

      130006195451

    • ISSN
      1882-2398, 1882-4749
    • Related Report
      2017 Annual Research Report
    • Open Access
  • [Journal Article] Dependence of the Device Performance of Polymer Solar Cells on the Insertion of Metal Nanoparticle Layers at the Electron-collecting Electrodes2017

    • Author(s)
      MARUMOTO Kazuhiro、KOSUGA Atsushi、LIU Dong、TAKEUCHI Osamu、SHIGEKAWA Hidemi
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 5 Pages: 272-275

    • DOI

      10.5796/electrochemistry.85.272

    • NAID

      130005645813

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 光ポンププローブSTM:光強度を変化させない遅延時間変調法2019

    • Author(s)
      武内修,Zi-Han Wang, 茂木裕幸,Cheul Hyun Yoon, 谷中淳,吉田昭二,重川秀実
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光STM による太陽電池評価におけるトンネル接合特性2019

    • Author(s)
      篠原 和貴,腰地 空, 鈴木 彩,武内 修,谷中 淳,吉田 昭二,重川 秀実
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Nanoscale characterization of MDMO-PPV:PCBM Solar Cells by photo-assisted STM2018

    • Author(s)
      K. Shinohara, S. Koshiji, T. Matsui, A. Suzuki, A. Taninaka, S. Yoshida, O. Takeuchi, and H. Shigekawa
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14) & 26th International Colloquium on Scanning Probe Microscopy (ICSPM26)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Application of Light-Modulated Scanning Tunneling Spectroscopy (LM-STS) to Pentacene-based Organic Solar Cells2018

    • Author(s)
      S. Koshiji, K. Shinohara, T. Matsui, A. Suzuki, A. Taninaka, S. Yoshida, O. Takeuchi, and H. Shigekawa
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14) & 26th International Colloquium on Scanning Probe Microscopy (ICSPM26)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MDMO-PPV:PCBM薄膜太陽電池の光STM2018

    • Author(s)
      武内 修, 五味 晃, 大橋 ファーゼルルラハマーン, 篠原 和貴, 腰地 空, 谷中 淳, 吉田 昭二, 重川 秀実
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] バルクヘテロ有機薄膜太陽電池のSTMによる評価2017

    • Author(s)
      武内 修、村尾 啓士朗、落合 貴大、大橋 ファーゼルルラハマーン、篠原 和貴、安田 剛、吉田 昭二、重川 秀実
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Local Characterization of Organic Solar Cells by STM2017

    • Author(s)
      O. Takeuchi, T. Ochiai, K. Shinohara, A. Gomi, F. Ohashi, A. Taninaka, S. Yoshida and H. Shigekawa
    • Organizer
      25th International Colloquium on Scanning Probe Microscopy (ICSPM25)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Light emission from organic thin film solar cell measured by STM-LES2017

    • Author(s)
      A. Gomi, F. Ohashi, K. Shinohara, T. Yasuda, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      25th International Colloquium on Scanning Probe Microscopy (ICSPM25)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] STM Emission Spectroscopy on Organic Solar Cell2017

    • Author(s)
      F. Ohashi, A. Gomi, K. Shinohara, S. Yoshida, A. Taninaka, O. Takeuchi and H. Shigekawa
    • Organizer
      25th International Colloquium on Scanning Probe Microscopy (ICSPM25)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoscale Evaluation of Organic Solar Cells by Light-Modulated Scanning Tunneling Microscopy2017

    • Author(s)
      Kazutaka Shinohara, Atsushi Taninaka, Shoji Yoshida, Osamu Takeuchi and Hidemi Shigekawa
    • Organizer
      25th International Colloquium on Scanning Probe Microscopy (ICSPM25)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of MoS2 nanowire in Mo1-xWxS2 alloy monolayer studied by STM2016

    • Author(s)
      H. Mogi, S. Yoshida, Y. Kobayashi, Y. Miyata, O. Takeuchi and H. Shigekawa
    • Organizer
      24th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ハワイコンベンションセンター(Hawaii, USA)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transient Dynamics of Low-dimensional TMDs Observed by Multi-probe Optical Pump-probe Scanning Tunneling Microscopy2016

    • Author(s)
      Z.H. Wang, H. Mogi, T. Banba, S. Yoshida, Y. Miyata, O. Takeuchi and H. Shigekawa
    • Organizer
      24th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ハワイコンベンションセンター(Hawaii, USA)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Characterization of Opto-electronic and Reverse Opto-electronic Conversion Efficiencies of Organic Solar Cells by STM2016

    • Author(s)
      K. Murao, T. Ochiai, T. Yasuda, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      24th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ハワイコンベンションセンター(Hawaii, USA)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Scanning tunneling potentiometry on FIB-deposited PtC pattern by using multi-probe STM2016

    • Author(s)
      T. Bamba, H. Mogi, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      24th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ハワイコンベンションセンター(Hawaii, USA)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ultrafast Carrier Dynamics in MoS2 Probed by Time-resolved Multi-probe Scanning Tunneling Microscopy2016

    • Author(s)
      Z.H. Wang, H. Mogi, T. Banba, S. Yoshida, Y. Miyata, O. Takeuchi and H. Shigekawa
    • Organizer
      物性研短期研究会「走査トンネル顕微鏡による物性研究の現状と展望」
    • Place of Presentation
      東京大学・物性研究所(千葉県柏市)
    • Year and Date
      2016-10-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] ransient Dynamics of MoS2 Observed by Multi-probe Optical Pump-probe Scanning Tunneling Microscopy2016

    • Author(s)
      Z.H. Wang, H. Mogi, T. Banba, S. Yoshida, Y. Miyata, O. Takeuchi and H. Shigekawa
    • Organizer
      日本表面科学会関東支部 第4回関東支部セミナー
    • Place of Presentation
      東京大学理学部・化学館(東京都文京区)
    • Year and Date
      2016-10-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオンビーム誘起堆積法により作成したPt配線の多探針STP測定2016

    • Author(s)
      茂木 裕幸,番場 隆文,武内 修,重川 秀実
    • Organizer
      日本表面科学会関東支部 第4回関東支部セミナー
    • Place of Presentation
      東京大学理学部・化学館(東京都文京区)
    • Year and Date
      2016-10-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] 時間分解走査トンネル顕微鏡の開発と展望2016

    • Author(s)
      吉田 昭二, Zi-han Wang, 武内 修, 重川 秀実
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] イオンビーム誘起堆積法により作成したPt配線の局所電位測定2016

    • Author(s)
      茂木 裕幸,番場 隆文,武内 修,重川 秀実
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] LM-STSを用いた有機薄膜太陽電池の局所特性評価2016

    • Author(s)
      五味晃,武内 修,重川 秀実
    • Organizer
      第11回有機デバイス院生研究会
    • Place of Presentation
      千葉大学 西千葉キャンパス(千葉県千葉市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effect of tip thermal expansion in laser combined STM2015

    • Author(s)
      M. Shigeno, Z. H. Wang, T. Kishi, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      23rd International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ヒルトンニセコビレッジホテル, 北海道虻田郡ニセコ町
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spatial Distribution of P3HT:PCBM Organic Photo Voltaic Propety Using Multistep LM-STS2015

    • Author(s)
      Y. Kobayash, T. Ochiai, T. Yasuda, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      23rd International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ヒルトンニセコビレッジホテル, 北海道虻田郡ニセコ町
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoscale Polarimetry with STM Light Emission on P3HT:PCBM Solar Cell2015

    • Author(s)
      K. Murao, K. Naito, T. Ochiai, T. Yasuda, S. Yoshida, O. Takeuchi and H. Shigekawa
    • Organizer
      23rd International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      ヒルトンニセコビレッジホテル, 北海道虻田郡ニセコ町
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 重川研究室(筑波大学数理物質系)

    • URL

      https://dora.bk.tsukuba.ac.jp/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 筑波大学数理物質系 重川・武内研究室

    • URL

      http://dora.bk.tsukuba.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 光出力システム、測定システム、光学的ポンプ・プローブ走査トンネル顕微鏡システム、演算器、プログラム2018

    • Inventor(s)
      重川秀実、武内修、汪子涵
    • Industrial Property Rights Holder
      重川秀実、武内修、汪子涵
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-233878
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2015-04-16   Modified: 2020-03-30  

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