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Study of Novel Functions of Boron-Doped Nanographene Materials

Research Project

Project/Area Number 15H02163
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionNagoya University

Principal Investigator

Yamaguchi Shigehiro  名古屋大学, 物質科学国際研究センター(WPI), 教授 (60260618)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥41,990,000 (Direct Cost: ¥32,300,000、Indirect Cost: ¥9,690,000)
Fiscal Year 2017: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2016: ¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywordsホウ素 / グラフェン / 半導体特性 / 蛍光 / 有機エレクトロニクス / π電子系 / トランジスタ
Outline of Final Research Achievements

Incorporation of tri-coordinate boron atoms into a graphene skeleton produces various fascinating properties and functions. Aiming at the precise understanding the inherent properties of the boron-doped graphenes, we have synthesized various types of boron-containing nanographene materials as the model systems and studied their structures, properties, and functions. We have explored photoreactivity of the boron-containing pi-systems and their chemisorption properties leading to sensory applications. We have also achieved the solution-processed preparation of their thin films for organic field-effect transistors (FETs). A highly stabilized organic pi radical has been also synthesized, which showed amibiopolar carrier-transporting properties in a single crystal FET.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (52 results)

All 2018 2017 2016 2015

All Journal Article (10 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 10 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (42 results) (of which Int'l Joint Research: 13 results,  Invited: 24 results)

  • [Journal Article] Near infrared two-photon-excited and -emissive dyes based on a strapped excited-state intramolecular proton-transfer (ESIPT) scaffold2018

    • Author(s)
      N. Suzuki, K. Suda, D. Yokogawa, H. Kitoh-Nishioka, S. Irle, A. Ando, L. M. Abegao, K. Kamada, A. Fukazawa, and S. Yamaguchi
    • Journal Title

      Chem. Sci.

      Volume: 9 Issue: 10 Pages: 2666-2673

    • DOI

      10.1039/c8sc00066b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Boron-Stabilized Planar Neutral π-Radicals with Well-Balanced Ambipolar Charge-Transport Properties2017

    • Author(s)
      Kushida Tomokatsu、Shirai Shusuke、Ando Naoki、Okamoto Toshihiro、Ishii Hiroyuki、Matsui Hiroyuki、Yamagishi Masakazu、Uemura Takafumi、Tsurumi Junto、Watanabe Shun、Takeya Jun、Yamaguchi Shigehiro
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 41 Pages: 14336-14339

    • DOI

      10.1021/jacs.7b05471

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Antiaromatic Dithieno-1,2-dihydro-1,2-diborin Splits Diatomic Hydrogen2017

    • Author(s)
      Araki Takafumi、Hirai Masato、Wakamiya Atsushi、Piers Warren E.、Yamaguchi Shigehiro
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 12 Pages: 1714-1717

    • DOI

      10.1246/cl.170812

    • NAID

      130006243211

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Photochemical Intramolecular C-H Addition of Dimesityl(hetero)arylboranes through a [1,6]-Sigmatropic Rearrangement2017

    • Author(s)
      Ando Naoki、Fukazawa Aiko、Kushida Tomokatsu、Shiota Yoshihito、Itoyama Shuhei、Yoshizawa Kazunari、Matsui Yasunori、Kuramoto Yutaro、Ikeda Hiroshi、Yamaguchi Shigehiro
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 40 Pages: 12210-12214

    • DOI

      10.1002/anie.201706929

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Dots Embedded in Graphene Nanoribbons by Chemical Substitution2017

    • Author(s)
      Eduard Carbonell-Sanroma, Pedro Brandimarte, Richard Balog, Martina Corso, Shigeki Kawai, Aran Garcia-Lekue, Shohei Saito, Shigehiro Yamaguchi, Ernst Meyer, Daniel Sanchez-Portal, Jose Ignacio Pascual
    • Journal Title

      Nano Lett.

      Volume: 17 Issue: 1 Pages: 50-56

    • DOI

      10.1021/acs.nanolett.6b03148

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Steric Shielding vs Structural Constraint in a Boron-Containing Polycyclic Aromatic Hydrocarbon2017

    • Author(s)
      V. M. Hertz, N. Ando, M. Hirai, M. Bolte, H.-W. Lerner, S. Yamaguchi, M. Wagner
    • Journal Title

      Organometallics

      Volume: ASAP Issue: 14 Pages: 2512-2519

    • DOI

      10.1021/acs.organomet.6b00800

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A Soluble Dynamic Complex Strategy for the Solution-Processed Fabrication of Organic Thin-Film Transistors of a Boron-Containing Polycyclic Aromatic Hydrocarbon2016

    • Author(s)
      Kyohei Matsuo, Shohei Saito, Shigehiro Yamaguchi
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 39 Pages: 11984-11988

    • DOI

      10.1002/anie.201605221

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron Doped Nanographene: Lewis Acidity, Redox Properties, and Battery Electrode Performance2016

    • Author(s)
      Shinichiro Osumi, Shohei Saito, Chuandong Dou, Kyohei Matsuo, Keita Kume, Hirofumi Yoshikawa, Kunio Awaga and Shigehiro Yamaguchi
    • Journal Title

      Chem. Sci.

      Volume: 7 Issue: 1 Pages: 219-227

    • DOI

      10.1039/c5sc02246k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Planarized 9-Phenylanthracene: A Simple Electron-Donating Building Block for Fluorescent Materials2016

    • Author(s)
      H. Iwahara, T. Kushida, S. Yamaguchi
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 6 Pages: 1124-1127

    • DOI

      10.1039/c5cc08259e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomically-Controlled Substitutional Boron-Doping of Graphene Nanoribbons2015

    • Author(s)
      S. Kawai, S. Saito, S. Osumi, S. Yamaguchi, A. S. Foster, P. Spijker, E. Meyer
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 8098-8098

    • DOI

      10.1038/ncomms9098

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Design Strategy for pi-Electron Materials Based on Structural Constraint2018

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      Core-to-core Joint Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design Strategy for pi-Electron Materials Based on Weak/tight Structural Constraint2018

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      Goethe-Universitat Frankfurt
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photostability of D-π-A Type Organoboron Fluorophores2017

    • Author(s)
      Masato ITO, Naoya SUZUKI, Shigehiro YAMAGUCHI
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ジベンゾアザボリンにおける構造固定化の物性に及ぼす効果2017

    • Author(s)
      安藤 幹規, 大城 宗一郎, 山口 茂弘
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 光・電子機能性分子で拓く未来2017

    • Author(s)
      山口茂弘
    • Organizer
      The 1st ABiS Symposium
    • Place of Presentation
      自然科学研究機構
    • Year and Date
      2017-02-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Main Group Strategy toward Useful pi-Electron Materials2017

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      Xi`an Jiatong University
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光機能性分子で拓く未来2017

    • Author(s)
      山口茂弘
    • Organizer
      日本大学生物資源科学部 大学院特別講義
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 構造固定により拓く典型元素π電子系の機能2017

    • Author(s)
      山口茂弘
    • Organizer
      新学術領域研究「感応性化学種」取りまとめシンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Properties of Pyridyl-Substituted Planarized Triphenylboranes2017

    • Author(s)
      Masayoshi Mori, Shigehiro Yamaguchi
    • Organizer
      17th International Symposium on Novel Aromatic Compounds (ISNA-17)
    • Related Report
      2017 Annual Research Report
  • [Presentation] NIR Emissive π-Conjugated Oligomers and Polymers Containing a Strapped-ESIPT Unit2017

    • Author(s)
      Naoya Suzuki, Masayuki Wakioka, Fumiyuki Ozawa, Shigehiro Yamaguchi
    • Organizer
      17th International Symposium on Novel Aromatic Compounds (ISNA-17)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Chemistry of Boron-doped Polycyclic Aromatic Hydrocarbons2017

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      16th International Meeting on Boron Chemistry (IMEBORON 16)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Main Group Strategy for Functional pi-Electron Materials2017

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      Gordon Research Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光・電子機能性分子の物性追求により拓く未来2017

    • Author(s)
      山口茂弘
    • Organizer
      平成29年度有機合成セミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Structurally Constrained Functional pi-Electron Materials2017

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      International Symposium of Materials Horizons
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Main Group-Containing pi-Electron Materials with Structural Constraint2017

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      100th Canadian Chemistry Conference and Exhibition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ピリジル置換平面固定トリフェニルボランの合成と物性2016

    • Author(s)
      森 正義,山口茂弘
    • Organizer
      第43回有機典型元素化学討論会
    • Place of Presentation
      仙台市民会館
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] キサンテン色素への三配位ホウ素の導入と元素効果の解明2016

    • Author(s)
      早乙女広樹,安藤直紀,相田祐介,山口茂弘
    • Organizer
      第43回有機典型元素化学討論会
    • Place of Presentation
      仙台市民会館
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] デザインで拓く発光性有機分子の未来技術2016

    • Author(s)
      山口茂弘
    • Organizer
      豊田工業大学講演会
    • Place of Presentation
      豊田工業大学
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 光・電子機能性分子で拓く未来2016

    • Author(s)
      山口茂弘
    • Organizer
      第42回反応と合成の進歩シンポジウム
    • Place of Presentation
      清水, 静岡
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] π電子系の機能追求のための分子デザイン2016

    • Author(s)
      山口茂弘
    • Organizer
      新学術領域「π造形科学」,第3回公開シンポジウム
    • Place of Presentation
      東北大学
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 蛍光性π電子系のデザインと物性追求2016

    • Author(s)
      山口茂弘
    • Organizer
      日本学術振興会創造機能化学第116委員会
    • Place of Presentation
      東京
    • Year and Date
      2016-10-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] 光る分子が拓く未来2016

    • Author(s)
      山口茂弘
    • Organizer
      国際有機化学財団特別セミナー,大分高校生講演会
    • Place of Presentation
      大分
    • Year and Date
      2016-10-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 局所温度計測を可能にする有機蛍光色素含有高分子ナノ粒子の創成2016

    • Author(s)
      千田樹絵子,名倉和彦,多喜正泰,山口茂弘
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 蛍光性π電子系のデザインと機能追求2016

    • Author(s)
      山口茂弘
    • Organizer
      第65回高分子討論会「融合マテリアル学が切り拓く新機能材料の創成」
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 光・電子機能分子の物性追求により拓く未来2016

    • Author(s)
      山口茂弘
    • Organizer
      近大若手シンポジウム「光による物質・エネルギー変換の最前線」
    • Place of Presentation
      近畿大学
    • Year and Date
      2016-09-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ボラフルオレセインの合成と光物性2016

    • Author(s)
      早乙女広樹,安藤直紀,相田祐介,山口茂弘
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Chemistry of Boron-doped Nanographenes2016

    • Author(s)
      S.Yamaguchi
    • Organizer
      BORAM 2016
    • Place of Presentation
      Kingston, Canada
    • Year and Date
      2016-06-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 励起状態の構造制御にもとづいた蛍光ナノ温度計の開発2016

    • Author(s)
      千田樹絵子,名倉和彦,多喜正泰,山口茂弘
    • Organizer
      統合物質創製化学研究推進機構キックオフシンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2016-06-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分子の光が拓く未来2016

    • Author(s)
      山口茂弘
    • Organizer
      第26回名古屋大学理学懇話会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2016-06-04
    • Related Report
      2016 Annual Research Report
  • [Presentation] 典型元素化学が拓く未来分子材料2016

    • Author(s)
      山口茂弘
    • Organizer
      JACI-GSC シンポジウム
    • Place of Presentation
      神戸
    • Year and Date
      2016-06-02
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Main Group Strategy for Photo- and Electro-Functional Materials2016

    • Author(s)
      S. Yamaguchi
    • Organizer
      Sino-German Main Group Chemistry Symposium
    • Place of Presentation
      Beijing, China
    • Year and Date
      2016-04-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 典型元素の活用と構造固定に基づいた光・電子機能性π電子系の創出2016

    • Author(s)
      山口茂弘
    • Organizer
      日本化学会第96春季年会2016
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 平面固定9-フェニルアントラセンを基本骨格に用いたディスコチック液晶の創製2016

    • Author(s)
      岩原秀明,吉尾正史,加藤隆史,山口茂弘
    • Organizer
      日本化学会第96春季年会2016
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Chemistry of boron-doped nanographenes2015

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 平面固定B-フェニルジベンゾボレピンの合成と基礎物性2015

    • Author(s)
      安藤直紀,櫛田知克,山口茂弘
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] ホウ素で安定化した平面固定トリチルラジカルの安定性と光物性2015

    • Author(s)
      早乙女広樹,謝 永発,櫛田知克,山口茂弘
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光・電子機能性分子のユニークなデザイン2015

    • Author(s)
      山口茂弘
    • Organizer
      第32回有機合成化学セミナー
    • Place of Presentation
      静岡
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Main Group Strategy for Photo- and Electronic Functions2015

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      The 14th International Symposium on Inorganic Ring Systems (IRIS-14)
    • Place of Presentation
      Regensburg, Germany
    • Year and Date
      2015-07-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Boron-Embedded Polycyclic pi-Conjugated Systems as Solution Processable Organic Semiconductor2015

    • Author(s)
      Kyohei Matsuo, Shohei Saito, Shigehiro Yamaguchi
    • Organizer
      16th International Symposium on Novel Aromatic Compounds (ISNA-16)
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ユニークな光:電子機能性分子を求めて2015

    • Author(s)
      山口茂弘
    • Organizer
      東京工業大学
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-06-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Some Fluorescent Molecules Containing Main Group Elements2015

    • Author(s)
      Shigehiro Yamaguchi
    • Organizer
      The 2nd International AIE Symposium
    • Place of Presentation
      Guangzhou, China
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光・電子機能性分子のユニークなデザイン2015

    • Author(s)
      山口茂弘
    • Organizer
      有機合成化学講演会「合成有機化学のフロンティア」
    • Place of Presentation
      福岡
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Invited

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Published: 2015-04-16   Modified: 2019-03-29  

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