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Ultra high efficiency organic-inorganic hybrid light emitting device

Research Project

Project/Area Number 15H02203
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionYamagata University

Principal Investigator

Kido Junji  山形大学, 大学院有機材料システム研究科, 教授 (50214838)

Co-Investigator(Kenkyū-buntansha) 千葉 貴之  山形大学, 有機材料システム研究推進本部, 研究員 (20751811)
夫 勇進  山形大学, 大学院有機材料システム研究科, 准教授 (00350489)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥44,070,000 (Direct Cost: ¥33,900,000、Indirect Cost: ¥10,170,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥33,670,000 (Direct Cost: ¥25,900,000、Indirect Cost: ¥7,770,000)
Keywords有機LED / 有機無機ハイブリッド / 量子ドット / ペロブスカイト / 有機-無機ハイブリッドデバイス / ハロゲン化鉛系ペロブスカイト / 有機-無機ハイブリッドデイバス / 有機-無機ハイブリッド / 有機EL / 無機ナノ粒子
Outline of Final Research Achievements

All-inorganic perovskite (CsPbX3, X = Cl, Br, or I) quantum dots (QDs) have recently attracted considerable interest for light-emitting device (LED) applications such as thin film displays and solid-state lighting, owing to electroluminescence emission with narrow full width at half maximum (FWHM), tunable color properties in the visible light range, and ease of solution processability. Here, we demonstrated low driving voltage and high efficiency CsPbBr3 QDs light-emitting devices (QD-LEDs) using a ligand exchange method and washing process with an ester solvent c to remove excess ligands. The LED with ligand exchange CsPbBr3 QDs exhibited a low turn-on voltage of 2.6 V and EQE of 8.7%. Control of the interfacial perovskite QDs through ligand removal and energy level alignment in the device structure are promising methods for obtaining high PLQYs in film state and high device efficiency.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 2 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 6 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Addition of Lithium 8-Quinolate into Polyethylenimine Electron-Injection Layer in OLEDs: Not Only Reducing Driving Voltage but Also Improving Device Lifetime2017

    • Author(s)
      Chiba Takayuki、Pu Yong-Jin、Ide Takahumi、Ohisa Satoru、Fukuda Hitoshi、Hikichi Tatsuya、Takashima Dai、Takahashi Tatsuya、Kawata So、Kido Junji
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 21 Pages: 18113-18119

    • DOI

      10.1021/acsami.7b02658

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment2017

    • Author(s)
      Chiba Takayuki、Hoshi Keigo、Pu Yong-Jin、Takeda Yuya、Hayashi Yukihiro、Ohisa Satoru、Kawata So、Kido Junji
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 21 Pages: 18054-18060

    • DOI

      10.1021/acsami.7b03382

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solution-Processed Tandem Organic Light-Emitting Devices2016

    • Author(s)
      Takayuki Chiba
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 73 Issue: 5 Pages: 464-474

    • DOI

      10.1295/koron.2016-0028

    • NAID

      130005419005

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Organic Light-Emitting Devices with Tandem Structure2016

    • Author(s)
      Takayuki Chiba, Yong-Jin Pu, Junji Kido
    • Journal Title

      Topics in Current Chemistry

      Volume: 374 Issue: 3 Pages: 33-33

    • DOI

      10.1007/s41061-016-0031-5

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solution-processable electron injection materials for organic light-emitting devices2015

    • Author(s)
      Takayuki Chiba, Yong-Jin Pu, Junji Kido
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 44 Pages: 11567-11576

    • DOI

      10.1039/c5tc02421h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Efficient Electron Injection by Size- and Shape-Controlled Zinc Oxide Nanoparticles in Organic Light-Emitting Devices2015

    • Author(s)
      Yong-Jin Pu, Norito Morishita, Takayuki Chiba, Satoru Ohisa, Masahiro Igarashi, Akito Masuhara, and Junji Kido
    • Journal Title

      ACS Applied Materials Interfaces

      Volume: 7 Issue: 45 Pages: 25373-25377

    • DOI

      10.1021/acsami.5b07742

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] 塗布型電子注入層による有機EL素子の 低電圧化と長寿命化2017

    • Author(s)
      千葉 貴之
    • Organizer
      第64回 応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県 パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] High-Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment2017

    • Author(s)
      Takayuki Chiba
    • Organizer
      IMID 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic LEDs for Displays and Lighting2017

    • Author(s)
      Junji Kido
    • Organizer
      ICEP2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress in Organic Light-Emitting Devices2017

    • Author(s)
      Junji Kido
    • Organizer
      Japan-Taiwan Bilateral Polymer Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ハロゲンアニオン交換による赤色ペロブスカイト量子ドットを用いた高性能発光デバイス2017

    • Author(s)
      林幸宏、千葉貴之、城戸淳二
    • Organizer
      第65回応用物理学会 春期学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] High-Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment2017

    • Author(s)
      Keigo Hoshi, Takayuki Chiba, Junji Kido
    • Organizer
      2017 MRS Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of High Performance OLED for Displays and Lighting2016

    • Author(s)
      Junji Kido
    • Organizer
      The Asion Conference on Organic Electronics 2016
    • Place of Presentation
      Kyoto, Kyoto University
    • Year and Date
      2016-12-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solution-processed multi photon emission organic light-emitting devices2016

    • Author(s)
      Takayuki Chiba
    • Organizer
      11th International Conference of Electroluminescence and Optoelectronic Devices
    • Place of Presentation
      North Carolina, Sheraton Raleigh Hotel
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of High Performance OLED for Displays and Lighting2016

    • Author(s)
      Junji Kido
    • Organizer
      The 18th International Workshop on Inorganic and Organic Electroluminescence
    • Place of Presentation
      Taiyuan, Taiyuan University of Technology
    • Year and Date
      2016-07-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of High Performance OLED Materials andDevices2016

    • Author(s)
      Junji Kido
    • Organizer
      International Conference on the Science and Technology of Synthetic Metals 2016
    • Place of Presentation
      Guangzhou, South China University
    • Year and Date
      2016-06-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 塗布型白色リン光 マルチフォトンエミッション有機EL素子2016

    • Author(s)
      千葉 貴之
    • Organizer
      第63回 応用物理学会春季学術講演会
    • Place of Presentation
      東京都 東京工業大学大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 塗布型マルチフォトンエミッション有機EL素子2015

    • Author(s)
      千葉 貴之
    • Organizer
      第64回 高分子討論会
    • Place of Presentation
      宮城県 東北大学 川内キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Remarks] ラボニュース

    • URL

      http://oled.yz.yamagata-u.ac.jp/view.cgi?p=290

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] LEDおよびその製造法2018

    • Inventor(s)
      千葉貴之、城戸淳二、保志圭吾、林幸宏、江部日向子、佐藤純
    • Industrial Property Rights Holder
      千葉貴之、城戸淳二、保志圭吾、林幸宏、江部日向子、佐藤純
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-024037
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機ハイブリッドデバイス2018

    • Inventor(s)
      千葉貴之、城戸淳二、宇田川和男、熊谷大地
    • Industrial Property Rights Holder
      千葉貴之、城戸淳二、宇田川和男、熊谷大地
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-024191
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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