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On investigation of molecules selective transport at thermos-fluid gas-liquid interface by hybrid nonlinear optical imaging technique

Research Project

Project/Area Number 15H02223
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionKeio University

Principal Investigator

SATO Yohei  慶應義塾大学, 理工学部(矢上), 教授 (00344127)

Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥44,200,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥10,200,000)
Fiscal Year 2018: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2017: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2016: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2015: ¥20,540,000 (Direct Cost: ¥15,800,000、Indirect Cost: ¥4,740,000)
Keywords熱流動界面 / 水分子のダイナミクス / イオンのダイナミクス / エバネッセント波 / ラマン散乱光イメージング / CARS / 非共鳴バックグラウンドノイズ / 熱流動界面時空間分子選択的輸送現象 / 非線形ラマン散乱 / ハイブリットイメージング法 / 分子選択的輸送ダイナミクス理論 / 平衡・非平衡領域 / ラマンスペクトル非線形回帰分析 / ラマン多波長イメージング法 / 分子選択時輸送ダイナミクス理論
Outline of Final Research Achievements

Motion of molecules and ions in the vicinity of the interface between liquid and solid is always affected by both thermofluid dynamics and the interface. There have not existed the effective intrusive measurement techniques without fluorescence probes. In the present study, it is possible to investigate dynamics of molecules and ions in the vicinity of the interface based on the new analytical methods using the captured weak Raman scattering light from molecules and ions. Especially the dynamics of metal ions in solution were investigated using the analytical results based on Raman scattering light from water molecules, because the metal ions are Raman inactive.

Academic Significance and Societal Importance of the Research Achievements

生物の細胞から、我々の周りの環境資源である水に至るまで、分子やイオンが、重要な役割を担っている。しかし、数値シミュレーションを用いても、未だに、そのダイナミクスは、完全には解明することは出来ず、ましてや、実験において解明することは不可能だと思われている。本研究では、ラマン散乱光において、水分子をノイズとして捉えるのではなく、微弱な光の情報の中から、分子やイオンの、振動モードや結合状態の情報を捉えることに成功し、本研究の成果は、癌細胞遊走や、水質浄化等に至るまで、貢献できることが期待される。

Report

(5 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (37 results)

All 2019 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (3 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (28 results) (of which Int'l Joint Research: 13 results,  Invited: 1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results) Funded Workshop (1 results)

  • [Int'l Joint Research] フランス原子力・代替エネルギー庁(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] フランス原子力・代替エネルギー庁 (CEA)(France)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] フランス原子力・代替エネルギー庁(フランス)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Precise near-wall pH measurement in pressure-driven and electrically-driven flows using nanoscale laser-induced fluorescence imaging2019

    • Author(s)
      Reiko KURIYAMA, Yuta TANAKA, Shimon AKIYAMA, Yohei SATO
    • Journal Title

      Measurement Science and Technology

      Volume: 30

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] マイクロ・ナノスケールにおける熱流動可視化技術の発展 (表面近傍計測ならびに非侵襲化への取り組み)2019

    • Author(s)
      栗山怜子, 佐藤洋平
    • Journal Title

      伝熱

      Volume: 58 Pages: 8-14

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Origin of blue shift of water molecules at interfaces of hydrophilic cyclic compounds2017

    • Author(s)
      Tomobe, K., Yamamoto, E., Kojic, D., Sato, Y., Yasui, M. & Yasuoka, K.
    • Journal Title

      Science Advances

      Volume: 3 Issue: 12

    • DOI

      10.1126/sciadv.1701400

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 交差型CARS分光顕微鏡を用いた電解質混合溶液の非侵襲濃度計測2019

    • Author(s)
      西川祐貴, 長田晃輔, 嘉副裕, 佐藤洋平
    • Organizer
      2019年度日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電解質溶液・石英ガラス界面極近傍における水分子挙動の解明2019

    • Author(s)
      黒栁颯人, 宮島昂宏, 山本詠士, 佐藤洋平
    • Organizer
      2019年度日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 壁面ゼータ電位の変化に伴う固液界面極近傍における水分子振動モードの計測2019

    • Author(s)
      熊谷哲, 木下晴貴, 嘉副裕, 佐藤洋平
    • Organizer
      2019年度日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電解質混合溶液における水分子の水素・非水素結合の評価2019

    • Author(s)
      吉﨑駿人, 馬場徹太, 山本詠士, 佐藤洋平
    • Organizer
      2019年度日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電解質溶液のイオン濃度変化による水分子の水素・非水素結合の評価2019

    • Author(s)
      福井健策, 川合裕高, 山本詠士, 佐藤洋平
    • Organizer
      2019年度日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温度勾配下における水分子ダイナミクスの電場による制御2019

    • Author(s)
      加藤優佑, 山本詠士, 佐藤 洋平
    • Organizer
      第40回日本熱物性シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Water dynamics under thermal gradient and electric field2019

    • Author(s)
      Yusuke KATO, Yohei SATO, Eiji YAMAMOTO
    • Organizer
      International Conference on Molecular Simulation
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crossed CARS sensing technique for non-intrusive ion concentration measurement2018

    • Author(s)
      Osada, K., Kojima, K., Yamamoto, E. & Sato, Y.
    • Organizer
      The 26th International Conference on Raman Spectroscopy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of simultaneous measurement of concentration and temperature distribution in electrolyte solution using three-wavelength Raman imaging2018

    • Author(s)
      Takechi, M., Tanaka, M., Yamamoto, E. & Sato, Y.
    • Organizer
      The 26th International Conference on Raman Spectroscopy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Raman spectroscopy for differentiated live cell identification using evanescent wave & volume illumination2018

    • Author(s)
      Kawai, H., Uchigasaki, A., Uwamori, H. & Sato, Y.
    • Organizer
      The 26th International Conference on Raman Spectroscopy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Influence of ion concentration on water molecules vibration mode measured by Raman spectroscopy2018

    • Author(s)
      Baba, T., Miyajima, T., Yamamoto, E. & Sato, Y.
    • Organizer
      The 26th International Conference on Raman Spectroscopy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Non-intrusive concentration measurement for electrolyte solution using CARS microscopy2017

    • Author(s)
      Satoshi Yamaguchi, Takayuki Minami & Yohei Sato
    • Organizer
      The Sixth International Symposium on Micro and Nano Technology
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Non-intrusive concentration measurement for CO2/N2 mixture flow using CARS microscopy2017

    • Author(s)
      Jun Miyaoka, Kota Kojima & Yohei Sato
    • Organizer
      The Sixth International Symposium on Micro and Nano Technology
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Concentration and zeta-potential measurements for gold nanoparticles using built-in device for evanescent wave illumination2017

    • Author(s)
      Miyajima, T., Watanabe, S. & Sato, Y.
    • Organizer
      The Ninth JSME-KSME Thermal and Fluids Engineering Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ノイズ低減化を施したCARS顕微鏡によるCO2・N2混合気流の非侵襲濃度計測2016

    • Author(s)
      宮岡淳, 小島航太, 山本憲, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2016
    • Place of Presentation
      愛媛大学(愛媛県・松山市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] ノイズ低減化を施したCARS顕微鏡による電解質混合溶液の非侵襲濃度計測2016

    • Author(s)
      山口智史, 皆見貴幸, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2016
    • Place of Presentation
      愛媛大学(愛媛県・松山市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 組込型デバイスEvaChipを用いたマイクロデバイス内の金ナノ粒子濃度計測2016

    • Author(s)
      渡邉菖平, 漆谷真帆, Hadji Céline, Virot Leopold, Icard Béatrice, Agache Vincent, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2016
    • Place of Presentation
      愛媛大学(愛媛県・松山市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] Development of evanescent wave for a chip for distribution measurements of physical quantities in the vicinity of liquid-solid interface2016

    • Author(s)
      Atuhisa Uchigasaki, Maho Urushidani & Yohei Sato
    • Organizer
      The Fifth Micro and Nano Flows
    • Place of Presentation
      Milan (Italy)
    • Year and Date
      2016-09-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of non-intrusive and micron-resolution CARS sensing for gas mixture flow considering reduction of non-resonant background noise2016

    • Author(s)
      Kota Kojima, Yuki Yamagata, Ken Yamamoto & Yohei Sato
    • Organizer
      The 18th International Symposium on the Applicatioin of Laser and Imaging Techniques to Fluid Mechanics
    • Place of Presentation
      Lisbon (Portugal)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CARS and p-CARS measurements of ion concentration in electrolyte solution: Influence of non-resonant background noise on non-intrusive detection2016

    • Author(s)
      Takayuki Minami, Takeshi Noguchi, Reiko Kuriyama & Yohei Sato
    • Organizer
      The 18th International Symposium on the Applicatioin of Laser and Imaging Techniques to Fluid Mechanics
    • Place of Presentation
      Lisbon (Portugal)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of multi-wavelength spontaneous Raman imaging for ion concentration and temperature distribution in microfluidic device2016

    • Author(s)
      M. Tanaka, K. Yamamoto, Y. Sato & K. Hishida
    • Organizer
      The First Pacific Rim Thermal Engineering Conference
    • Place of Presentation
      Hawaii (U.S.A.)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Sophisticated integration of laser measurement techniques and their expansion to nano/micro thermofluid dynamics2016

    • Author(s)
      Y. Sato
    • Organizer
      The First Pacific Rim Thermal Engineering Conference
    • Place of Presentation
      Hawaii (U.S.A.)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 自発ラマンイメージング法を用いた多変量空間分布の非侵襲計測2015

    • Author(s)
      田中満依子, 山本憲, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全反射ラマンイメージングを用いた固液界面極近傍における分子拡散現象の解明2015

    • Author(s)
      木下正治, 立石哲郎, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 非共鳴バックグランドノイズを考慮した混合気流内のCARS 顕微鏡を用いた非侵襲センシング法の開発2015

    • Author(s)
      小島航太, 渡邉菖平, 山縣侑生, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 偏光 CARS を用いた電界質溶液混合場におけるイオン濃度分布非侵襲計測2015

    • Author(s)
      皆見貴幸, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全反射ラマン散乱光を用いたマイクロチャネル流固液界面極近傍のイオン拡散非侵襲イメージング2015

    • Author(s)
      立石哲郎, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ナノ・マイクロ熱流動レーザ計測に影響を及ぼす分子拡散現象の定量的評価2015

    • Author(s)
      服部司, 佐藤洋平
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 全反射試料証明装置2016

    • Inventor(s)
      佐藤洋平, 漆谷真帆, 牧野秀介
    • Industrial Property Rights Holder
      佐藤洋平, 漆谷真帆, 牧野秀介
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-26
    • Acquisition Date
      2017-01-18
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 全反射試料証明装置2016

    • Inventor(s)
      佐藤洋平, 漆谷真帆, 牧野秀介
    • Industrial Property Rights Holder
      佐藤洋平, 漆谷真帆, 牧野秀介
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-26
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Funded Workshop] The First International Symposium on Sophisticated Coupling and Integration of Genius+Kernel Technologies (GKTEC)2017

    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2022-11-04  

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