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Organic-inorganic bonding through VUV-surface activation

Research Project

Project/Area Number 15H02297
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionKyoto University

Principal Investigator

SUGIMURA HIROYUKI  京都大学, 工学研究科, 教授 (10293656)

Co-Investigator(Kenkyū-buntansha) 一井 崇  京都大学, 工学研究科, 准教授 (30447908)
宇都宮 徹  京都大学, 工学研究科, 助教 (70734979)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥44,590,000 (Direct Cost: ¥34,300,000、Indirect Cost: ¥10,290,000)
Fiscal Year 2017: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2016: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2015: ¥22,490,000 (Direct Cost: ¥17,300,000、Indirect Cost: ¥5,190,000)
Keywords異種接合 / 表面接合 / 真空紫外光 / 高分子材料 / 無機材料 / 金属材料 / 光化学反応 / 自己集積化単分子膜 / 原子平坦面 / 表面処理 / 光化学
Outline of Final Research Achievements

Hetero-surface bonding technology between organic and inorganic surfaces has been developed based on VUV surface activation, self-assembled monolayer coating and surface flatning. Roughness of the inroganic surfaces had crucial effects on bonding temperature. In case of Al/COP(cyclo-olefin polymer, Tg = 140 C), bonding was sucessful only at temperatures higherr than 100 C with the rougness of Rrms = 25 nm, which is a few tens of degree below Tg, while the roughness ot Rrms = 10 nm lowered the bonding temperature down to bleow 70 C. When atomically flat inorganic surfaces were supplied, bonding at room tempeature was enabled. This room temerature surface bonding has been successfully acheived on bonding Al, Si or Ti with VUV-modified COP.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015

All Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 2 results) Presentation (22 results) (of which Invited: 1 results) Book (2 results)

  • [Journal Article] 真空紫外光表面処理による合成樹脂部材の活性化表面接合2018

    • Author(s)
      杉村博之
    • Journal Title

      成形加工

      Volume: 30 Pages: 107-111

    • NAID

      130007890519

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low Damage Reductive Patterning of Oxidized Alkyl Self-Assembled Monolayers through Vacuum Ultraviolet Light Irradiation in an Evacuated Environment2017

    • Author(s)
      Soliman Ahmed I. A.、Tu Yudi、Utsunomiya Toru、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Langmuir

      Volume: 33 Issue: 41 Pages: 10829-10837

    • DOI

      10.1021/acs.langmuir.7b02739

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Protective layer for cycloolefin polymer against an aromatic solvent prepared by chemical vapor deposition using cyclosiloxane as a raw molecule2017

    • Author(s)
      Utsunomiya Toru、Kanzawa Taiki、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Thin Solid Films

      Volume: 638 Pages: 28-33

    • DOI

      10.1016/j.tsf.2017.07.026

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vacuum ultraviolet trimming of oxygenated functional groups from oxidized self-assembled hexadecyl monolayers in an evacuated environment2017

    • Author(s)
      Soliman Ahmed I.A.、Utsunomiya Toru、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Applied Surface Science

      Volume: 416 Pages: 971-979

    • DOI

      10.1016/j.apsusc.2017.04.037

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of reduced graphene oxide micro patterns by vacuum-ultraviolet irradiation: From chemical and structural evolution to improving patterning precision by light collimation2017

    • Author(s)
      Tu Yudi、Nakamoto Hiroshi、Ichii Takashi、Utsunomiya Toru、Khatri Om Prakash、Sugimura Hiroyuki
    • Journal Title

      Carbon

      Volume: 119 Pages: 82-90

    • DOI

      10.1016/j.carbon.2017.04.008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Study of the adhesion and interface of the low-temperature bonding of vacuum ultraviolet-irradiated cyclo-olefin polymer using electron microscopy2016

    • Author(s)
      Shin Horiuchi; Hideki Hakukawa; Yong Jong Kim; Hideya Nagata; Hiroyuki Sugimura
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 4 Pages: 473-479

    • DOI

      10.1038/pj.2016.3

    • NAID

      40020778363

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical Preparation of Alkoxy Self-assembled Monolayers on Si from 1,2-Epoxyalkane Molecules2016

    • Author(s)
      Ahmed I. A. Soliman; Sho Kokufu; Toru Utsunomiya; Takashi Ichii; Hiroyuki Sugimura
    • Journal Title

      Chem. Lett.,

      Volume: 45 Pages: 561-563

    • NAID

      130005150475

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Vacuum-Ultraviolet Promoted Oxidative Micro Photoetching of Graphene Oxide2016

    • Author(s)
      Yudi Tu; Toru Utsunomiya; Takashi Ichii, and ; Hiroyuki Sugimura
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Pages: 10267-10635

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chemical conversion of self-assembled hexadecyl monolayers with active oxygen species generated by vacuum ultraviolet irradiation in an atmospheric environment2016

    • Author(s)
      Ahmed I. A. Soliman; Takashi Ichii; Toru Utsunomiya; Hiroyuki Sugimura
    • Journal Title

      Soft Matter

      Volume: 11 Issue: 28 Pages: 5678-5687

    • DOI

      10.1039/c5sm00823a

    • NAID

      120005670860

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高平滑チタンとポリマー材料の光活性化室温接合2018

    • Author(s)
      林立庭,宇都宮徹,一井崇,杉村博之
    • Organizer
      表面技術協会第137回講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 真空紫外光による材料表面処理2017

    • Author(s)
      杉村博之
    • Organizer
      第36回 固体・表面光化学討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 真空紫外光照射によるチタンと高分子材料の常温直接接合2017

    • Author(s)
      林 立庭,宇都宮 徹,一井 崇,杉村 博之
    • Organizer
      第19回関西表面技術フォーラム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高平滑Al基板とポリマーの表面活性化接合2017

    • Author(s)
      羅紫馨,宇都宮徹,一井崇,杉村博之
    • Organizer
      第19回関西表面技術フォーラム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高平滑なアルミ箔と高分子材料の表面活性化接合2017

    • Author(s)
      羅紫馨,宇都宮徹,一井崇,杉村博之
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] チタンと高分子材料の光活性化常温接合2017

    • Author(s)
      林立庭,宇都宮徹,一井崇,杉村博之
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 平滑シリコン表面の官能基終端化によるポリマー材料との常温接合2017

    • Author(s)
      宇都宮徹,藤原吉宏,一井崇,杉村博之
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Si基板と高分子材料の表面活性化接合2016

    • Author(s)
      藤原吉宏、宇都宮徹、一井崇、杉村博之
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学ポートアイランドキャンパス
    • Year and Date
      2016-12-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 有機単分子膜被覆アルミニウムと高分子材料の接合2016

    • Author(s)
      羅紫馨、宇都宮徹、一井崇、杉村博之
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学ポートアイランドキャンパス
    • Year and Date
      2016-12-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Selective Trimming of Surface Oxygenated Groups through Vacuum Ultraviolet Light Irradiation in an Evacuated Environment2016

    • Author(s)
      Ahmed. I. A. Soliman, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      The 63rd AVS International Symposium and Exhibition
    • Place of Presentation
      Music City Center, Nashville, Tennessee, USA
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Room temperature bonding of polymer and silicon wafer using vacuum ultraviolet surface activation2016

    • Author(s)
      Yoshihiro Fujiwara, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      The 63rd AVS International Symposium and Exhibition
    • Place of Presentation
      Music City Center, Nashville, Tennessee, USA
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 平滑シリコンとポリマー材料の光活性化接合2016

    • Author(s)
      藤原吉宏、宇都宮徹、一井崇、杉村博之
    • Organizer
      平成28年度資源・素材関係学協会合同秋季大会
    • Place of Presentation
      岩手大学理工学部キャンパス
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 1.2-Epoxyalkane: Another precursor molecules for self-assembled monolayers on hydrogen terminated Si(111)2016

    • Author(s)
      Toru Utsunomiya, Ahmed I. A. Soliman, Sho Kokufu, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      16th International Conference on Organized Molecular Films (ICOMF16)-LB16
    • Place of Presentation
      Helsinki, Finland
    • Year and Date
      2016-07-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルミニウムの表面粗さが高分子材料との光活性化接合に及ぼす影響2016

    • Author(s)
      孔成棟,宇都宮徹,一井崇,杉村博之
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリコンと高分子材料の光活性化常温接合2016

    • Author(s)
      藤原吉宏,宇都宮徹,一井崇,杉村博之
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Chemical conversions of hexadecyl self-assembled monolayers based on vacuum ultraviolet irradiations in an atmospheric condition2015

    • Author(s)
      Ahmed. I. A. Soliman, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Photo-avtivation bonding between polymer material and aluminum2015

    • Author(s)
      Chengdong Kong,Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異種材料の接合に与える表面処理の効果2015

    • Author(s)
      藤原吉宏,宇都宮徹,一井崇,杉村博之
    • Organizer
      第17回関西表面技術フォーラム
    • Place of Presentation
      甲南大学ポートアイランドキャンパス
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] アルミニウム箔と高分子材料の光活性化接合2015

    • Author(s)
      孔成棟,宇都宮徹,一井崇,杉村博之
    • Organizer
      表面技術協会第132回講演大会
    • Place of Presentation
      信州大学長野キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Quantitative Analysis of Surface Functional Groups at Modified Self-Assembled Monolayers through Vacuum Ultraviolet Irradiation2015

    • Author(s)
      Ahmed I. A. Soliman, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      表面技術協会第132回講演大会
    • Place of Presentation
      信州大学長野キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高分子材料とアルミニウムの光活性化接合2015

    • Author(s)
      孔成棟,宇都宮徹,一井崇,杉村博之
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] uantitative Analysis of Surface Functional Groups of Alkyl Self-Assembled Monolayers Generated through Vacuum Ultraviolet Irradiation2015

    • Author(s)
      Ahmed. I. A. Soliman, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Book] 自動車のマルチマテリアル戦略 : 第2章第6節第3項(高分子と金属の光活性化接合技術)2017

    • Author(s)
      杉村博之
    • Total Pages
      7
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2017 Annual Research Report
  • [Book] 異種材料の接着・接合技術と マルチマテリアル化(第5章第3節 高分子と無機材料の光活性化異種接合)2017

    • Author(s)
      杉村博之
    • Total Pages
      7
    • Publisher
      技術情報協会
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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