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A new anisotropic nanofiber/polymer composite made of different polymers for the AB-different polymer blending

Research Project

Project/Area Number 15H02298
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionKeio University

Principal Investigator

HOTTA Atsushi  慶應義塾大学, 理工学部(矢上), 教授 (30407142)

Co-Investigator(Kenkyū-buntansha) 前田 知貴  茨城大学, フロンティア応用原子科学研究センター, 助教 (00754730)
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥44,330,000 (Direct Cost: ¥34,100,000、Indirect Cost: ¥10,230,000)
Fiscal Year 2018: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2017: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2016: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Fiscal Year 2015: ¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Keywords複合材料 / コンポジット / ファイバー / 配向 / エレクトロスピニング / ポリマー / ファイバ / ポリマ
Outline of Final Research Achievements

Polymer composites containing polymer matrix with polymeric nanofibers made of different types of polymers were fabricated. We have enhanced the elastic moduli of the new types of polymer composites primarily by considering the reinforcing effects of the nanofibers. To achieve the goal, cellulose nanofibers (C-NF) with excellent mechanical property were fabricated through the saponification of electrospun cellulose-acetate (CA) nanofibers. It was also revealed that the elastic modulus of the nanofibers could be enhanced by annealing the CA nanofibers before the saponification. Additionally, to improve the reinforcing effects of the nanofibers, the orientation and the surface modification of C-NF were carried out. Successively the C-NF were compounded into biodegradable polycaprolactone (PCL) to eventually obtain eco-friendly composites. The new composites possessed high elastic modulus closer to the theoretical value, higher than that of the composites made by the conventional methods.

Academic Significance and Societal Importance of the Research Achievements

樹脂ポリマ材料の高強度化手法の1つとして、線状の繊維などの1次元ポリマ分散材の複合化が知られている。このような複合材料は軽量性や強度の高さから航空機部品などに応用されている。本研究では、自然由来かつ高強度のセルロースの線状ナノポリマ分散材を生分解性ポリマに複合化することで、環境に優しい新規なポリマ分散型複合材料をデザインし、生分解性ポリマの応用範囲拡大の可能性を見出した。さらに、本研究で確立した新しい複合化手法を、さまざまなポリマ分散型の複合材料に応用することで、異種のポリマとポリマを結びつけ,従来よりも理論弾性率により近い弾性率を有する複合材料を作製するメソッドを新たに見出すことができた。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (28 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 3 results) Presentation (16 results) (of which Int'l Joint Research: 8 results) Book (6 results)

  • [Journal Article] Annealing and saponification of electrospun cellulose-acetate nanofibers used as reinforcement materials for composites2018

    • Author(s)
      S. Inukai, N. Kurokawa, A. Hotta
    • Journal Title

      Composites Part A : Applied Science and Manufacturing

      Volume: 113 Pages: 158-165

    • DOI

      10.1016/j.compositesa.2018.07.028

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermomechanical properties of highly transparent self-reinforced polylactide composites with electrospun stereocomplex polylactide nanofibers2018

    • Author(s)
      N. Kurokawa, A. Hotta
    • Journal Title

      Polymer

      Volume: 153 Pages: 214-222

    • DOI

      10.1016/j.polymer.2018.08.018

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of poly(butylene succinate) composites with aligned cellulose-acetate nanofibers2018

    • Author(s)
      Kurokawa Naruki、Kimura Shunta、Hotta Atsushi
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 135 Issue: 24 Pages: 45429-45429

    • DOI

      10.1002/app.45429

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PEG-based nanocomposite hydrogel: Thermoresponsive sol-gel transition controlled by PLGA-PEG-PLGA molecular weight and concentration2017

    • Author(s)
      M. Miyazaki, T. Maeda, K. Hirashima, N. Kurokawa, K. Nagahama and A. Hotta
    • Journal Title

      Polymer

      Volume: 115 Pages: 246-254

    • DOI

      10.1016/j.polymer.2017.03.016

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancement of the gas barrier property of polypropylene by introducing plasma-treated silane coating with SiOx-modified top-surface2015

    • Author(s)
      K. Tsuji, M. Nakaya, A. Uedono, and A. Hotta
    • Journal Title

      Surface and Coatings Technology

      Volume: 284 Pages: 377-383

    • DOI

      10.1016/j.surfcoat.2015.10.027

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Syndiotactic polypropylene nanofibers obtained from solution electrospinning process at ambient temperature2015

    • Author(s)
      T. Maeda, K. Takaesu, and A. Hotta
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 133 Issue: 13 Pages: 43238-43238

    • DOI

      10.1002/app.43238

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Surface-modified cellulose nanofibers for the effective reinforcing materials of poly(ε-caprolactone) composites2018

    • Author(s)
      H. Ichimura, N. Kurokawa, A. Hotta
    • Organizer
      2018 MRS Fall Meeting & Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanical Properties of Poly(vinyl alcohol) Composites with Electrospun Cellulose Nanofibers Annealed at Different Temperatures2018

    • Author(s)
      S. Inukai, N. Kurokawa, A. Hotta
    • Organizer
      2018 MRS Fall Meeting & Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solidification of poly (2-methoxyethyl aclylate) via block copolymerization with poly (methyl methacrylate) and its properties2018

    • Author(s)
      N. Kurokawa, F. Endo, K. Bito, T. Maeda, A. Hotta
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mechanical properties of poly(butylene succinate) composites with aligned cellulose-acetate nanofibers2017

    • Author(s)
      T. Maeda, S. Kimura, N. Kurokawa and A. Hotta
    • Organizer
      APS March Meeting 2017
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2017-03-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of PEG-rich PLGA-PEG-PLGA for the PLGA-PEG-PLGA/laponite hydrogels with thermoresponsive sol-gel transitions2017

    • Author(s)
      K. Tanimoto, T. Maeda and A. Hotta
    • Organizer
      APS March Meeting 2017
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2017-03-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermomechanical properties and transparency of self-reinforced polylactide composites with stereocomplex polylactide nanofibers2017

    • Author(s)
      N. Kurokawa and A. Hotta
    • Organizer
      APS March Meeting 2017
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2017-03-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異なる温度で熱処理したセルロースナノファイバーを複合したポリビニルアルコールの力学物性2017

    • Author(s)
      犬飼駿也、黒川成貴、堀田篤
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] エレクトロスピニング法による結晶性エチレンプロピレンエラストマーファイバーの作製2016

    • Author(s)
      遠藤冬玲, デローサ クラウディオ, 堀田篤
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス(神奈川県・横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] CNTへATRPグラフトしたスチレン鎖長がCNTの分散性およびCNT/ポリスチレン複合材料の力学物性に与える影響2016

    • Author(s)
      遠藤冬玲, 水上遼平, 堀田篤
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス(神奈川県・横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸素プラズマ処理および湿度環境がPDMS基板へのPVAナノファイバーの選択的紡糸に与える影響2016

    • Author(s)
      石井裕也, 堀田篤
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Annealing effects on the crystalline structures of syndiotactic polystyrene after the crystalline β to α form structural transition induced by mechanical strain2016

    • Author(s)
      F. Endo, A. Hotta
    • Organizer
      APS March Meeting 2016
    • Place of Presentation
      Baltimore (USA)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrospun PVA-nanofiber patterning on a PDMS substrate by O2 plasma treatment2015

    • Author(s)
      T. Maeda, N. Kurokawa, M. Nakadoi, Y. Ishii, N. Kobayashi, and A. Hotta
    • Organizer
      14th Pacific Polymer Conference
    • Place of Presentation
      Hawaii (USA)
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A newly designed controlled drug-release platform with both anti-thrombogenicity and endothelialization: micropatterned-diamond-like carbon combined with biocompatible polymer2015

    • Author(s)
      K. Bito, T. Hasebe, T. Maeda, S. Maegawa, Y. Yamato, T. Matsumoto, T. Mine, T. Suzuki, A. Hotta
    • Organizer
      2015 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston (USA)
    • Year and Date
      2015-11-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 抗血栓性ポリマーファイバーを被覆した動脈瘤破裂治療用カバードステントの開発2015

    • Author(s)
      白幡智史,長谷部光泉,尾藤健太,前川駿人,中野裕揮,田中美夏,大和裕哉,松本知博,鈴木哲也,堀田篤
    • Organizer
      第38回日本バイオレオロジー学会年会
    • Place of Presentation
      学術総合センター(東京都・千代田区)
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] 配向性ファイバーをコンポジットしたポリジメチルシロキサン膜の弾性率およびCO2分離性評価2015

    • Author(s)
      黒川祐衣,堀田篤
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 多孔質構造を有するポリブチレンサクシネートファイバーの作製およびそのプラズマ表面改質による生分解速度制御2015

    • Author(s)
      黒川祐衣,堀田篤
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Book] 樹脂/繊維複合材料の界面制御,成形加工と評価:長繊維セルロースナノファイバーを複合したPVAの力学物性2018

    • Author(s)
      犬飼駿也、黒川成貴、堀田篤
    • Total Pages
      8
    • Publisher
      技術情報協会
    • ISBN
      9784861046902
    • Related Report
      2017 Annual Research Report
  • [Book] 次世代ポリオレフィン総合研究, Vol. 10、ポリオレフィン材料の高ガスバリア化にむけたダイヤモンドライクカーボン (DLC)薄膜コーティングの開発2016

    • Author(s)
      青木拓,堀田篤
    • Total Pages
      162
    • Publisher
      三恵社
    • Related Report
      2016 Annual Research Report
  • [Book] Comprehensive Guide for Nanocoatings Technology2015

    • Author(s)
      T. Maeda, K. Hagiwara, T. Hasebe, and A. Hotta
    • Total Pages
      29
    • Publisher
      Nova Science Publishers Inc.
    • Related Report
      2015 Annual Research Report
  • [Book] Poly(Ethylene Terephthalate): Blends, Composites and Nanocomposites2015

    • Author(s)
      T. Maeda, F. Endo, A. Hotta
    • Total Pages
      22
    • Publisher
      Elsevier
    • Related Report
      2015 Annual Research Report
  • [Book] Printing on Polymers: Fundamentals and Applications2015

    • Author(s)
      K. Tsuji, T. Maeda, A. Hotta
    • Total Pages
      18
    • Publisher
      Elsevier
    • Related Report
      2015 Annual Research Report
  • [Book] 次世代ポリオレフィン総合研究,Vol. 92015

    • Author(s)
      黒川成貴,中村浩二,堀田篤
    • Total Pages
      8
    • Publisher
      三恵社
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2020-03-30  

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