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Martensite hardening mechanism in high carbon steels based on a new principle

Research Project

Project/Area Number 15H02304
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

PING Dehai  国立研究開発法人物質・材料研究機構, 構造材料研究拠点, 主幹研究員 (80354207)

Co-Investigator(Kenkyū-buntansha) 阿部 太一  国立研究開発法人物質・材料研究機構, 構造材料研究拠点, 主幹研究員 (50354155)
大沼 正人  北海道大学, 工学研究院, 教授 (90354208)
Project Period (FY) 2015-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥44,720,000 (Direct Cost: ¥34,400,000、Indirect Cost: ¥10,320,000)
Fiscal Year 2019: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2016: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2015: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Keywords鉄鋼材料 / 炭素鋼 / TEM / 相変態 / オメガ相 / 双晶境界 / 電子線回折 / 炭化物 / マルテンサイト構造 / 構造・機能材料 / マルテンサイト / 透過電子顕微鏡 / 金属物性 / ① 構造・機能材料 / ② 金属物性 / ③ 鉄鋼材料 / マルテンサイト変態 / ⑤ オメガ相
Outline of Final Research Achievements

No carbon, iron is iron. Iron with carbon becomes steel. Thus, it is very important to understand the role of carbon in steels. Understanding the role of carbon atoms in the microstructural evolution of carbon steels has been a key point in developing new steels. In about 100 years before this research project, it had been commonly accepted that the carbon atoms are in body-centered cubic (BCC) Fe to form a single crystal of Fe(C) martensite. Martensite is a hard structure. However, we have observed there are two crystalline phases (BCC-Fe and hexagonal ω-Fe in the Fe-C martensite. The ω-Fe is only distributed in the twinning boundary region. Based on this new finding, we started this research project. we have confirmed that the ω-Fe phase really exists together with BCC-Fe in Fe-C martensite, and have explained the formation mechanism, and also confirmed that the ω-Fe is the precursor of well-known cementite.

Academic Significance and Societal Importance of the Research Achievements

新たに発見した「鉄鋼中のオメガ相の形成」という視点から焼き入れ硬化現象について新原理の構築しました。鉄鋼材料研究の新しい方向性を切り拓き、21世紀の技術基盤となる新たな鉄鋼材料学を構築する。炭素鋼は、ごく一般的な汎用鉄鋼材料であり、鉄鋼材料として最もよく使われている。その中において、Fe-C合金は、典型的な二元合金炭素鋼である。また、炭素は、炭素鋼の性質に最も影響するため、熱処理時の炭素鋼中における炭素の挙動に関する研究は、多くの研究者の興味を引いている。

Report

(6 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (29 results)

All 2020 2019 2018 2017 2016 2015

All Journal Article (12 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 12 results,  Open Access: 7 results,  Acknowledgement Compliant: 2 results) Presentation (17 results) (of which Int'l Joint Research: 9 results)

  • [Journal Article] A transition of ω-Fe3C→ ω′-Fe3C → θ′-Fe3C in Fe-C martensite2020

    • Author(s)
      D. H. Ping, H. P. Xiang, H. Chen, L. L. Guo, K. Gao, and X. Lu
    • Journal Title

      Scientific Reports

      Volume: 10 Issue: 1 Pages: 6081-6081

    • DOI

      10.1038/s41598-020-63012-9

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Simulated electron diffraction patterns of ω-Fe in Fe-C martensite2019

    • Author(s)
      Ping D. H.、Xiang H. P.
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 4 Pages: 045105-045105

    • DOI

      10.1063/1.5065432

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] ω-Fe particle size and distribution in high-nitrogen martensitic steels2018

    • Author(s)
      Ping D. H.、Ohnuma M.
    • Journal Title

      Journal of Materials Science

      Volume: 53 Issue: 7 Pages: 5339-5355

    • DOI

      10.1007/s10853-017-1938-0

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lath formation mechanisms and twinning as lath martensite substructures in an ultra low-carbon iron alloy2018

    • Author(s)
      Ping D. H.、Guo S. Q.、Imura M.、Liu X.、Ohmura T.、Ohnuma M.、Lu X.、Abe T.、Onodera H.
    • Journal Title

      Scientific Reports

      Volume: 8 Issue: 1 Pages: 14264-14264

    • DOI

      10.1038/s41598-018-32679-6

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nanoclusters of α-Fe naturally formed in twinned martensite after martensitic transformation2018

    • Author(s)
      Liu X.、Ping D. H.、Xiang H. P.、Lu X.、Shen J.
    • Journal Title

      Journal of Applied Physics

      Volume: 123 Issue: 20 Pages: 205111-205111

    • DOI

      10.1063/1.5034146

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] In situ heating TEM observations on carbide formation and α-Fe recrystallization in twinned martensite2018

    • Author(s)
      Liu X.、Man T. H.、Yin J.、Lu X.、Guo S. Q.、Ohmura T.、Ping D. H.
    • Journal Title

      Scientific Reports

      Volume: 8 Issue: 1 Pages: 14454-14454

    • DOI

      10.1038/s41598-018-32896-z

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A Simple Method for Observing <i>ω</i>-Fe Electron Diffraction Spots from &lt;112&gt;<sub><i>α</i>-Fe</sub> Directions of Quenched Fe–C Twinned Martensite2018

    • Author(s)
      D. H. Ping, A. Singh, S. Q. Guo, T. Ohmura, M. Ohnuma, T. Abe, H. Onodera
    • Journal Title

      ISIJ International

      Volume: 58 Issue: 1 Pages: 159-164

    • DOI

      10.2355/isijinternational.ISIJINT-2017-270

    • NAID

      130007340360

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electron diffraction characterization of quenched Fe-C martensite2018

    • Author(s)
      T. W. Liu, D. H. Ping, T. Ohmura, M. Ohnuma
    • Journal Title

      Journal of Materials Science

      Volume: 53 Issue: 4 Pages: 2976-2984

    • DOI

      10.1007/s10853-017-1731-0

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TEM investigations on lath martensite substructure in quenched Fe-0.2C alloys2018

    • Author(s)
      Man T.H.、Liu T.W.、Ping D.H.、Ohmura T.
    • Journal Title

      Materials Characterization

      Volume: 135 Pages: 175-182

    • DOI

      10.1016/j.matchar.2017.11.039

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Microstructural Evolution and Carbides in Quenched Ultra-low Carbon (Fe–C) Alloys2017

    • Author(s)
      D. H. Ping, T. W. Liu, M. Ohnuma, T. Ohmura, T. Abe and H. Onodera
    • Journal Title

      ISIJ International

      Volume: 57 Issue: 7 Pages: 1233-1240

    • DOI

      10.2355/isijinternational.ISIJINT-2016-624

    • NAID

      130005808192

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Understanding Solid-Solid (fcc - omega + bcc) Transition at Atomic Scale2015

    • Author(s)
      D. H. Ping
    • Journal Title

      Acta. Metall. Sin. (Engl. Lett.)

      Volume: 28 Issue: 6 Pages: 663-670

    • DOI

      10.1007/s40195-015-0283-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] A new nanoscale metastable iron phase in carbon steels2015

    • Author(s)
      T. Liu, D. Zhang, Q. Liu, Y. Zheng, Y. Su, X. Zhao, J. Yin, M. Song, D. Ping
    • Journal Title

      Scientific Reports

      Volume: 5 Issue: 1

    • DOI

      10.1038/srep15331

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Microstructural Evolution in Carbon Steel2019

    • Author(s)
      D. H. Ping
    • Organizer
      The 10th International Conference on Advanced Materials and Processing
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanostructure in Quenched Fe-C Martensite2018

    • Author(s)
      D. H. Ping, X. Liu, X. Lu, T. Ohmura and M. Ohnuma
    • Organizer
      6th International Indentation Workshop (IIW6) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microstructural Characterization of Water-quenched High Carbon Fe-C Alloys2018

    • Author(s)
      X. Liu, X. Lu, D. H. Ping, T. Ohmura, M. Ohnuma
    • Organizer
      6th International Indentation Workshop (IIW6) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A possible γ-Fe(C) → ω-Fe3C → ω′-Fe3C → θ′-Fe3C → θ-Fe3C transition pathway2018

    • Author(s)
      D. H. Ping, T. Ohmura, M. Ohnuma
    • Organizer
      日本鉄鋼協会
    • Related Report
      2018 Annual Research Report
  • [Presentation] In situ heating TEM observations on the carbide formation in twinned martensite2018

    • Author(s)
      X. Liu, X. Lu, D. H. Ping
    • Organizer
      日本鉄鋼協会
    • Related Report
      2018 Annual Research Report
  • [Presentation] A NEW MECHANISM FOR THE FORMATION OF θ-Fe3C IN CARBON STEELS2018

    • Author(s)
      D. H. Ping, T. Ohmura
    • Organizer
      6th International Conference on Advanced Steels (ICAS 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] As-quenched Microstructure in High Carbon Ferrous Alloys2018

    • Author(s)
      X. Liu, X. Lu, D. H. Ping
    • Organizer
      日本鉄鋼協会、第175回春季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] In-Situ heating TEM study on twinned martensite in quenched Fe-C alloys2017

    • Author(s)
      D. H. Ping, T. H. Man, T. W. Liu, T. Ohmura, Y. Tomota, M. Ohnuma
    • Organizer
      日本鉄鋼協会、第173回春季講演大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Tempering behavior of twinned region in a 0.2 mass%C martensitic steel studied by in-situ TEM observation2017

    • Author(s)
      T. H. Man, T. W. Liu, D. H. Ping, T. Ohmura
    • Organizer
      日本金属学会2017年春期講演大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electron Diffraction Analysis of Martensite in Quenched High Carbon Steels2017

    • Author(s)
      T. W. Liu, D. H. Ping, I. Watanabe, T. Ohmura, M. Ohnuma
    • Organizer
      International Conference on Martensitic Transformations (ICOMAT 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The observation of ω-Fe from <112> zone axes of twinned martensite2017

    • Author(s)
      D. H. Ping, A. Singh, S. Q. Guo, T. Abe, H. Onodera, T. Ohmura, M. Ohnuma
    • Organizer
      日本鉄鋼協会、第174回秋季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Metastable omega phase in carbon and nitrogen steels2016

    • Author(s)
      D. Ping, T. Ohmura, M. Ohnuma
    • Organizer
      5th Asian conference on heat treat and surface engineering
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2016-11-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TEM characterization of omega-Fe phase in quenched carbon steels2016

    • Author(s)
      T. W. Liu, D. H. Ping, T. Ohmura, M. Ohnuma
    • Organizer
      5th Asian conference on heat treat and surface engineering
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2016-11-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electron diffraction analysis of martensite in quenched Fe-C alloys2016

    • Author(s)
      Liu Tianwei, Ping Dehai, Ohmura Takahito, Ohnuma Masato
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学 豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Metastable ω-Fe in quenched Fe-C alloys2016

    • Author(s)
      D. H. Ping, T. W. Liu, T. Ohmura, M. Ohnuma
    • Organizer
      日本鉄鋼協会、第172回秋季講演大会
    • Place of Presentation
      大阪大学 豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Metastable omega phase in carbon and nitrogen steels2016

    • Author(s)
      D. H. Ping, T. Ohmura, M. Ohnuma
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing(PRICM9)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Understanding the transition of austenite to omega and ferrite at atomic scale2015

    • Author(s)
      D. H. Ping
    • Organizer
      Asia Steel International Conference 2015 (Asia Steel 2015)
    • Place of Presentation
      Pacifico Yokohama,Yokohama,日本(Japan)
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2022-11-04  

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