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Formation behavior and mechanism of advanced LSI interconnections by dynamic nano-reflow method

Research Project

Project/Area Number 15H02307
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionTohoku University

Principal Investigator

Koike Junichi  東北大学, 未来科学技術共同研究センター, 教授 (10261588)

Co-Investigator(Kenkyū-buntansha) 安藤 大輔  東北大学, 工学研究科, 助教 (50615820)
須藤 祐司  東北大学, 工学研究科, 准教授 (80375196)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥45,110,000 (Direct Cost: ¥34,700,000、Indirect Cost: ¥10,410,000)
Fiscal Year 2017: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2016: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2015: ¥27,170,000 (Direct Cost: ¥20,900,000、Indirect Cost: ¥6,270,000)
Keywords半導体 / 配線 / リフロー / 微細化 / 半導体超微細化 / 機能・構造材料 / 多層配線 / 構造・機能材料
Outline of Final Research Achievements

Performance of LSI devices has been continuously improved by shrinking device components. Recent devices encounter a problem of forming very narrow multilayer interconnections. In this project, we found the conditions to form 15 nm wide interconnections (M2 lines and vias) by a dynamic nano-reflow method of depositing Cu alloy at elevated temperatures. With this method, an alloying element was segregated at Cu/insulator interface and enhanced the wettability of the deposited metals. We also found that controlling parameters are surface curvature gradient in the initial deposition stage and thermal stress gradient during heating and cooling. The effects of each driving force are nearly the same magnitude. Based on the obtained results, we could simulate reflow behavior.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (48 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (7 results) Journal Article (15 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 15 results,  Open Access: 7 results,  Acknowledgement Compliant: 2 results) Presentation (23 results) (of which Int'l Joint Research: 18 results,  Invited: 9 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 3 results)

  • [Int'l Joint Research] Lam Research Corporation(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 国立台湾交通大学(台湾)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Lam Research Corporation(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] TSMC(台湾)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Korea Institute of Industrial Technolofy/Hanyang University(韓国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Lam Research Corporation(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] TSMC(台湾)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] New contact metallizationn scheme for FinFET and beyond2018

    • Author(s)
      J. Koike, M. Hosseini, D. Ando, and Y. Sutou
    • Journal Title

      Proceedings of IEEE EDTM

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Material innovation for MOL, BEOL, and 3D integration2018

    • Author(s)
      J. Koike, M. Hosseini, H. T. Hai, D. Ando and Y. Sutou
    • Journal Title

      Proceedings of IEEE IEDM

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Co and CoTix for contact plug and barrier layer in integrated circuits2018

    • Author(s)
      Maryamsadat Hosseini, Daisuke Ando, Yuji Sutou, Junichi Koike
    • Journal Title

      Microelectronic Engineering

      Volume: 189 Pages: 78-84

    • DOI

      10.1016/j.mee.2017.12.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Inverse Resistance Change Cr2Ge2Te6-Based PCRAM Enabling Ultralow-Energy Amorphization2018

    • Author(s)
      Shogo Hatayama, Yuji Sutou, Satoshi Shindo, Yuta Saito, Yun-Heub Song, Daisuke Ando, and Junichi Koike
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 3 Pages: 2725-2734

    • DOI

      10.1021/acsami.7b16755

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Co-Ti alloy for a barrier and contact materials in advanced MOL2017

    • Author(s)
      J. Koike, M. Hosseini, D. Ando and Y. Sutou
    • Journal Title

      Proceedings of Advanced Metallization Conference

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Co/Si contact properties with an amorhous interlayer of CoTix2017

    • Author(s)
      M. Hosseini, Y. Sutou and J. Koike
    • Journal Title

      Proceedings of ADMETA Plus 2017

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feasibility study of Cu paste printing techniquie to fill deep via halls for low cost 3D TSV applications2017

    • Author(s)
      H. T. Hai, K.-W. Lee, D. Ando, Y. Sutou, M. Koyanagi, and J. Koike
    • Journal Title

      Proceedings of IEEE IITC 2017

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metallurgical and electrical characterization of ultrathin CoTix liner/barrier for Cu interconnects2017

    • Author(s)
      M. Hosseini and J. Koike
    • Journal Title

      Proceedings of IEEE IITC 2017

      Volume: 1 Pages: 1-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Amorphous CoTix as a liner/diffusion barrier material for advanced copper metallization2017

    • Author(s)
      M. Hosseini and J. Koike
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 721 Pages: 134-142

    • DOI

      10.1016/j.jallcom.2017.05.335

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of plasma surface finish on wettability and mechanical properties of SAC305 solder joints2016

    • Author(s)
      K.-H. Kim, J. Koike, J.-W. Yoon, and S. Yoo
    • Journal Title

      Journal of electronic materials

      Volume: 45 Issue: 12 Pages: 6184-6191

    • DOI

      10.1007/s11664-016-4908-4

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Amorphous Co-Ti alloy as a single layer barrier for Co local interconnect structure2016

    • Author(s)
      M. Hosseini, J. Koike, Y. Sutou, L. Zhao, S. Lai and R. Arghavani
    • Journal Title

      Proceedings of IITC/AMC 2016

      Volume: 1 Pages: 162-164

    • DOI

      10.1109/iitc-amc.2016.7507718

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Contact resistivity for amorphous and crystalline GeCu2Te3 to W electrode for phase change random access memory2016

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, Y. Saito, and Y.-H. Song
    • Journal Title

      Materials Science in Semicndcutor Processing

      Volume: 47 Pages: 1-6

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] XAFS analysis on amorphous and crystalline new phase change material GeCu2Te32016

    • Author(s)
      K. Kamimura, S. Hosokawa, N. Happo, H. Ikemoto, Y. Sutou, S. Shindo, Y. Saito, and J. Koike
    • Journal Title

      Journal of optoelectronics and advanced materials

      Volume: 18 Pages: 248-253

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The investigation of an amorphous Co-Hf alloy as an ultrathin single layer barrier in LSI devices2016

    • Author(s)
      H. Koide, D. Ando, Y. Sutou, and J. Koike
    • Journal Title

      Proceedings of ADMETA 2016

      Volume: 1 Pages: 35-36

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diffusion barrier property of MnSixOy layer formed by chemical vapor deposition for Cu advanced interconnect application2015

    • Author(s)
      N. M. Phuong, Y. Sutou, J. Koike
    • Journal Title

      Thin Solid Films

      Volume: 580 Pages: 56-60

    • DOI

      10.1016/j.tsf.2015.03.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Cu paste metallization for stress critical applications in electrical packaging2018

    • Author(s)
      J. Koike
    • Organizer
      Internation workshop on reliability and stress-related phenomena
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] サブ10nm FinFETにおける低接触抵抗の実現に向けたコバルト合金の特性2018

    • Author(s)
      小池淳一 マリャムサダト ホセイニ 安藤大輔 須藤祐司
    • Organizer
      電子情報通信学会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] New contact metallization scheme for FinFET and beyond2018

    • Author(s)
      J. Koike, M. Hosseini, D. Ando and Y. Sutou
    • Organizer
      IEEE Electron Device Technology Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low contact resistivity between Co and nーSi with a CoTix interface layer2018

    • Author(s)
      M. Hosseini, J. Koike, D. Ando, and Y. Sutou
    • Organizer
      Meeting of Advanced Metallization
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co alloy for middle of line for FinFET of sub-7 nm2018

    • Author(s)
      J. Koike
    • Organizer
      Semicon China, CSTIC
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Metallurgical and electrical characterization of ultrathin CoTix liner/barrier for Cu interconnects2017

    • Author(s)
      M. Hosseini
    • Organizer
      International Interconnect Technology Conference
    • Place of Presentation
      台湾新竹市
    • Year and Date
      2017-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Feasibility study of Cu paste printing technique to fill deep via holes for low cost 3D TSV applications2017

    • Author(s)
      H. T. Hai
    • Organizer
      International Interconnect Technology Conference
    • Place of Presentation
      台湾新竹市
    • Year and Date
      2017-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] LSI多層配線の単層拡散バリア層としての非晶質コバルト合金の特性2017

    • Author(s)
      小池淳一
    • Organizer
      応用物理学会2017年春季講演大会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 先端配線におけるライナー・バリア機能を有する非晶質コバルト合金の特性2017

    • Author(s)
      Maryamsadat Hosseini
    • Organizer
      シリコン材料・デバイス研究会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2017-02-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Metallurgical and electrical characterization of ultrathin CoTix liner/barrier for Cu interconnects2017

    • Author(s)
      M. Hosseini and J. Koike
    • Organizer
      IEEE International Interconnect Technology Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Feasibility study of Cu paste printing techniquie to fill deep via halls for low cost 3D TSV applications2017

    • Author(s)
      H. T. Hai, K.-W. Lee, D. Ando, Y. Sutou, M. Koyanagi, and J. Koike
    • Organizer
      IEEE International Interconnect Technology Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co-Ti alloy for a barrier and contact materials in advanced MOL2017

    • Author(s)
      J. Koike, M. Hosseini, D. Ando and Y. Sutou
    • Organizer
      Advanced Metallization Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Co/Si contact properties with an amorhous interlayer of CoTix2017

    • Author(s)
      M. Hosseini, Y. Sutou and J. Koike
    • Organizer
      Advanced Metallization Conference Asian Session
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Material innovation for MOL, BEOL, and 3D integration2017

    • Author(s)
      J. Koike, M. Hosseini, H. T. Hai, D. Ando and Y. Sutou
    • Organizer
      IEEE International Electron Device Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A new amorphous alloy having liner/barrier function for sub-10 nm technology node of LSI interconnection2016

    • Author(s)
      小池淳一
    • Organizer
      ENGE2016
    • Place of Presentation
      韓国済州市
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal stability and diffusion barrier property of a Co-Ti layer for advanced copper metallization2016

    • Author(s)
      Maryamsadat Hosseini
    • Organizer
      Advanced metallization conference Asian session
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The investigation of an amorphous Co-Hf alloy as an ultrathin single-layer barrier in LSI devices2016

    • Author(s)
      小出紘之
    • Organizer
      Advanced metallization conference Asian session
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Amorphous Co-Ti alloy as a single layer barrier for Co local interconnect structure2016

    • Author(s)
      Maryamsadat Hosseini
    • Organizer
      IITC/AMC 2016
    • Place of Presentation
      San Jose, USA
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cu/酸化物層/Siの密着強度と拡散バリア性2016

    • Author(s)
      齋藤友大、安藤大輔、須藤祐司、小池淳一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] CVD法によるMnOx拡散バリア層の形成に伴うポーラスSiOHへのMn拡散2016

    • Author(s)
      小出紘之、王甲、安藤大輔、須藤祐司、小池淳一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] The effect of the Mn penetration in porous SiOCH for CVD-Mn diffusion barrier2015

    • Author(s)
      H. Koide, H. Wang, D.Ando, Y. Sutou, J. Koike
    • Organizer
      Advanced Metallization Conference 2015 Asian Session
    • Place of Presentation
      韓国 ソウル
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Grain growth and resistivity reduction of reflowed Cu-Mn in SiOC trench lines2015

    • Author(s)
      K. Satou, T. Saito, D.Ando, Y. Sutou, J. Koike
    • Organizer
      Advanced Metallization Conference 2015 Asian Session
    • Place of Presentation
      韓国 ソウル
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical contact property and interfacial reaction of Mn on surface-treated-InGaAs2015

    • Author(s)
      E. Lee, D. Ando, Y. Sutou, J. Koike
    • Organizer
      Advanced Metallization Conference 2015 Asian Session
    • Place of Presentation
      韓国 ソウル
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] SEMICONDUCTOR DEVICES INCLUDING COBALT ALLOYS AND FABRICATION2018

    • Inventor(s)
      Junichi Koike, Reza Arghavani
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] SEMICONDUCTOR DEVICES INCLUDING COBALT ALLOYS AND FABRICATION2018

    • Inventor(s)
      Junichi Koike, Reza Arghavani
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] SEMICONDUCTOR DEVICES INCLUDING COBALT ALLOYS AND FABRICATION2017

    • Inventor(s)
      Junichi Koike, Reza Arghavani
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
    • Overseas

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Published: 2015-04-16   Modified: 2022-08-25  

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