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Nanotuning of silica-based membranes with thin-film processing

Research Project

Project/Area Number 15H02313
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionHiroshima University

Principal Investigator

Tsuru Toshinori  広島大学, 工学研究科, 教授 (20201642)

Co-Investigator(Kenkyū-buntansha) 郡司 天博  東京理科大学, 理工学部先端化学科, 教授 (20256663)
伊藤 賢志  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 研究グループ長 (90371020)
Co-Investigator(Renkei-kenkyūsha) KANEZASHI MASAKOTO  広島大学, 大学院工学研究院, 准教授 (10467764)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥44,850,000 (Direct Cost: ¥34,500,000、Indirect Cost: ¥10,350,000)
Fiscal Year 2017: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2016: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2015: ¥22,230,000 (Direct Cost: ¥17,100,000、Indirect Cost: ¥5,130,000)
Keywords膜分離 / シリカ / オルガノシリカ / シリカ膜 / 細孔 / 分離 / 薄膜 / ゾル-ゲル / 分離膜 / Molecular-Net Sieving / 評価 / 膜 / 気体 / ナノろ過
Outline of Final Research Achievements

Molecular-Net Sieving where silica network space separates molecules based on the molecular-sieving mechanism was proposed to develop highly permselective membranes. For this purpose, new silicon alkoxides with POSS structures were developed, and the pore structures were evaluated by ellipsometric porosimetry and positron annihilation. Furthermore, pore sizes of silica-based membranes were successfully controlled by optimizing sol preparation condition, and the size of the liking units of bridged alkoxy silanes. In addition, pH swing method was effective to increase permeances.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (64 results)

All 2018 2017 2016 2015

All Journal Article (33 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 32 results,  Acknowledgement Compliant: 8 results,  Open Access: 3 results) Presentation (26 results) (of which Int'l Joint Research: 18 results,  Invited: 20 results) Book (4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis and reactivity of hydride-bridged ruthenium dithiolene complexes2018

    • Author(s)
      Takuya Sagawa, Satoru Tsukada, Kazuki Yamamoto, Takahiro Gunji
    • Journal Title

      Polyhedron

      Volume: 139 Pages: 196-200

    • DOI

      10.1016/j.poly.2017.10.023

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Ruthenium Dithiolene Complex/Polysiloxane Films and Their Responses to CO Gas2018

    • Author(s)
      Satoru Tsukada, Takuya Sagawa, Kazuki Yamamoto, Takahiro Gunji
    • Journal Title

      Molecules

      Volume: 23 Issue: 4 Pages: 845-845

    • DOI

      10.3390/molecules23040845

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pyrimidine-bridged organoalkoxysilane membrane for high-efficiency CO2 transport via mild affinity2017

    • Author(s)
      Liang Yu, Masakoto Kanezashi, Hiroki Nagasawa, Joji Oshita, Akinobu Naka, Toshinori Tsuru
    • Journal Title

      Separation Purification Technology

      Volume: 178 Pages: 232-241

    • DOI

      10.1016/j.seppur.2017.01.039

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of heat treatment on the nanoporosity of silica PECVD films elucidated by low-energy positron annihilation and ellipsometric porosimetry2017

    • Author(s)
      Yoshimoto Shigeru、Kumagai Kazuhiro、Hosomi Hiroyuki、Takeda Masaaki、Tsuru Toshinori、Ito Kenji
    • Journal Title

      Journal of Applied Physics

      Volume: 122 Issue: 18 Pages: 185304-185304

    • DOI

      10.1063/1.5004187

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of POSS-derived robust RO membranes for water desalination2017

    • Author(s)
      Kazuki Yamamoto, Sayako Koge, Takahiro Gunji, Masakoto Kanezashi, Toshinori Tsuru, and Joji Ohshita
    • Journal Title

      Desalination

      Volume: 404 Pages: 322-327

    • DOI

      10.1016/j.desal.2016.11.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation and properties of organic-inorganic hybrid polymer films using [Ti4(μ3-O)(OiPr)5(μ-OiPr)3(PhPO3)3]・thf2017

    • Author(s)
      Ryohei Hayami, Keisuke Wada, Takuya Sagawa, Satoru Tsukada, Seiji Watase, Takahiro Gunji
    • Journal Title

      Polymer Journal

      Volume: 49 Issue: 2 Pages: 223-228

    • DOI

      10.1038/pj.2016.108

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and properties of organic-inorganic hybrid materials using titanium phosphonate cluster2017

    • Author(s)
      Ryohei Hayami, Keisuke Wada, Izumi Nishikawa, Takuya Sagawa, Kazuki Yamamoto, Satoru Tsukada, Takahiro Gunji
    • Journal Title

      Polym. J.

      Volume: 49 Issue: 9 Pages: 665-669

    • DOI

      10.1038/pj.2017.34

    • NAID

      40021299670

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and CO 2 permeation properties of amine-silica membranes using a variety of amine types2017

    • Author(s)
      Yu Liang、Kanezashi Masakoto、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 541 Pages: 447-456

    • DOI

      10.1016/j.memsci.2017.07.024

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gas permeation properties for organosilica membranes with different Si/C ratios and evaluation of microporous structures2017

    • Author(s)
      Kanezashi Masakoto、Yoneda Yuri、Nagasawa Hiroki、Tsuru Toshinori、Yamamoto Kazuki、Ohshita Joji
    • Journal Title

      AIChE Journal

      Volume: 63 Issue: 10 Pages: 4491-4498

    • DOI

      10.1002/aic.15778

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo-induced sol-gel synthesis of polymer-supported silsesquioxane membranes2017

    • Author(s)
      H. Nagasawa, M. Nishibayashi, M. Kanezashi, T. Yoshioka and T. Tsuru
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 12 Pages: 7150-7157

    • DOI

      10.1039/c6ra21161e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Microstructure Tuning of a Pyrimidine-bridged Organoalkoxysilane Membrane for CO2 Separation2017

    • Author(s)
      Liang Yu, Masakoto Kanezashi, Hiroki Nagasawa, Joji Oshita, Akinobu Naka, Toshinori Tsuru
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 5 Pages: 1316-1326

    • DOI

      10.1021/acs.iecr.6b04460

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Favorable organosilica membranes for gas separation (GS) and reverse osmosis (RO): The effect of preparation conditions on structural and the correlation between gas and liquid permeation properties2017

    • Author(s)
      Suhaina M. Ibrahim, Hiroki Nagasawa, Masakoto Kanezashi, and Toshinori Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 526 Pages: 242-251

    • DOI

      10.1016/j.memsci.2016.12.036

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pore size tuning of sol-gel-derived triethoxysilane (TRIES) membranes for gas separation2017

    • Author(s)
      Kanezashi Masakoto、Matsugasako Rui、Tawarayama Hiromasa、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 524 Pages: 64-72

    • DOI

      10.1016/j.memsci.2016.11.006

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-Arylamino-1-azaazulenes2017

    • Author(s)
      Tsukada, S.; Nakazawa, M.; Okada, Y.; Ohtsu, K.; Abe, N.; Gunji, T.
    • Journal Title

      Heterocycles

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] [Ti4(m3-O)(OiPr)5(m-OiPr)3(PhPO3)3]thfを用いる有機-無機ハイブリッド高分子膜の調製2017

    • Author(s)
      郡司天博,速水良平,塚田学
    • Journal Title

      粉体および粉末冶金

      Volume: 64 Pages: 130-134

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiO2-ZrO2 nanofiltration membranes of different SiO2/ZrO2 molar ratios: stability in hot water and acid/alkaline solutions2017

    • Author(s)
      Waravut Puthai, Masakoto Kanezashi, Hiroki Nagasawa, ToshinoriTsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 524 Pages: 700-711

    • DOI

      10.1016/j.memsci.2016.11.045

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Propylene/propane Permeation Properties of Metal-doped Organosilica Membranes with Controlled Network Sizes and Adsorptive Properties2016

    • Author(s)
      Masakoto Kanezashi, Shuji Miyauchi, Shinjiro Hayakawa, Hiroki Nagasawa, Tomohisa Yoshioka, Toshinori Tsuru
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 59 Issue: 4 Pages: 140-148

    • DOI

      10.1627/jpi.59.140

    • NAID

      130005262956

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2016-07-01
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Syntheses of cage octasilicate polymers2016

    • Author(s)
      Takahiro Gunji, Takahiro Igarashi, Satoru Tsukada, and Yoshimoto Abe
    • Journal Title

      J. Sol-Gel Sci. & Tech.

      Volume: 76 Issue: 1 Pages: 21-26

    • DOI

      10.1007/s10971-016-3998-z

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Properties of diketonato Metal Complexes as Catalysts for the Synthesis of Polyurethane2016

    • Author(s)
      Hayami, R.; Tsukada, S.; Abe, Y.; Gunji, T.
    • Journal Title

      Mat.Tech.

      Volume: 34 Pages: 11-17

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly distorted octahedral molybdenum(II) complexes: synthesis, crystal structures, and properties of [Mo(S2C6H4)(CO)2(PMenPh3-n)2] (n = 0-3)2016

    • Author(s)
      Satoru Tsukada, Naoya Abe, and Takahiro Gunji
    • Journal Title

      Polyhedron

      Volume: 117 Pages: 73-79

    • DOI

      10.1016/j.poly.2016.05.035

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fine Electronic State Tuning of Cobaltadithiolene Complexes by Substituent Groups on the Benzene Ring2016

    • Author(s)
      sukada, S.; Kondo, M.; Sato, H.; Gunji, T
    • Journal Title

      Polyhedron

      Volume: 117 Pages: 265-272

    • DOI

      10.1016/j.poly.2016.05.062

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ゾル-ゲル法によるPOSSを利用した元素ブロック高分子の合成2016

    • Author(s)
      郡司天博
    • Journal Title

      セラミックス

      Volume: 51 Pages: 765-769

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanopore structure relevant to the D2O permeation into silica thin films as studied by secondary ion mass spectrometry, ellipsometric porosimetory and positron annihilation2016

    • Author(s)
      K Ito, H Hosomi, T Nakamura and M Takeda
    • Journal Title

      Journal of Physics:

      Volume: 79 Pages: 012027-012027

    • DOI

      10.1088/1742-6596/791/1/012027

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of non-commercial ceramic SiO2-ZrO2 and organosilica BTESE membranes in a highly oxidative medium: Performance in hydrogen peroxide2016

    • Author(s)
      R. Abejon, S.B. Ibrahim, P. Nagasawa, T. Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 520 Pages: 740-748

    • DOI

      10.1016/j.memsci.2016.08.042

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanofiltration performance of SiO2-ZrO2 membranes in aqueous solutions at high temperatures2016

    • Author(s)
      Waravut Puthai; Masakoto Kanezashi; Hiroki Nagasawa; Toshinori Tsuru
    • Journal Title

      Separation and Purification Technology

      Volume: 168 Pages: 238-247

    • DOI

      10.1016/j.seppur.2016.05.028

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of β-diketonato metal complexes as catalysts for the synthesis of polyurethane2016

    • Author(s)
      Hayami, Ryohei; Tsukada, Satoru; Gunji, Takahiro
    • Journal Title

      Mat. Tech.

      Volume: 34 Pages: 11-17

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tailoring the separation behavior of polymer-supported organosilica layered-hybrid membrane by a post treatment: a detailed comparison of HCl and HN3 vapor treatment2016

    • Author(s)
      Genghao Gong, Hiroki Nagasawa, Masakoto Kanezashi and Toshinori Tsuru
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 8 Issue: 17 Pages: 11060-11069

    • DOI

      10.1021/acsami.6b01986

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Network engineering of a BTESE membrane for improved gas performance via a novel pH-swing method2016

    • Author(s)
      Xin Yu, Lie Meng, Takuya Niimi, Hiroki Nagasawa, Masakoto Kanezashi, Tomohisa Yoshioka, and Toshinori Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 511 Pages: 219-227

    • DOI

      10.1016/j.memsci.2016.03.060

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of ethenylene-bridged organosilica membranes for desalination applications2016

    • Author(s)
      Xu, Rong; Lin, Peng; Zhang, Qi; Zhong, Jing; Tsuru, Toshinori
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 55 Issue: 7 Pages: 2183-2190

    • DOI

      10.1021/acs.iecr.5b04439

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of firing temperature on the water permeability of SiO2-ZrO2 membranes used for nanofiltration2016

    • Author(s)
      Waravut Puthai, Masakoto Kanezashi, Hiroki Nagasawa, Katsumi Wakamura, Hiroshi Ohnishi, and Toshinori Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 497 Pages: 348-356

    • DOI

      10.1016/j.memsci.2015.09.040

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Preparation, properties, and structure of polysiloxanes by acid-catalyzed controlled hydrolytic co-polycondensation of polymethy(methoxy)siloxane and polymethoxysiloxane2015

    • Author(s)
      Takahiro Gunji, Hironori Kaburagi, Satoru Tsukada, Yoshimoto Abe
    • Journal Title

      J. Sol-Gel Sci. & Tech.

      Volume: 75 Issue: 3 Pages: 564-573

    • DOI

      10.1007/s10971-015-3727-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Carbon Monoxide Addition to Ruthenium-Dithiolene Complex and Polysiloxane Hybrid Film Formation2015

    • Author(s)
      Satoru Tsukada, Takuya Sagawa, Takahiro Gunji
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 10 Issue: 9 Pages: 1881-1883

    • DOI

      10.1002/asia.201500617

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of POSS derivatives by the dehydrogenative condensation of T<sub>8</sub><sup>H</sup> with alcohols2015

    • Author(s)
      Satoru Tsukada, Yusuke Sekiguchi, Shoto Takai, Yoshimoto Abe, Takahiro Gunji
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 123 Issue: 1441 Pages: 739-743

    • DOI

      10.2109/jcersj2.123.739

    • NAID

      130005096348

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Development of Titanium Phosphonate Clusters as Element Blocks2017

    • Author(s)
      Takahiro Gunji, Satoru Tsukada
    • Organizer
      The 2nd International Symposium on Polymeric Materials Based on Element-Blocks
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2017-01-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Evaluation of pore structures of PECVD silica films by slow positron annihilation lifetime spectroscopy and ellipsometric porosimetry2017

    • Author(s)
      Shigeru Yoshimoto, Kenji Ito, Hiroyuki Hosomi, Masaaki Takeda, Toshinori Tsuru
    • Organizer
      3rd China-Japan Joint Workshop on Positron Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of heat treatment on the nanoporosity of silica PECVD films elucidated by the low-energy positron lifetime technique and ellipsometric porosimetry2017

    • Author(s)
      Shigeru Yoshimoto, Kenji Ito, Hiroyuki Hosomi, Masaaki Takeda, Toshinori Tsuru
    • Organizer
      12th International Workshop on Positron and Positronium Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カゴ型シルセスキオキサン元素ブロックの合成2017

    • Author(s)
      郡司天博
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ゾル・ゲル法による白金担持メソポーラスシリカの調製2017

    • Author(s)
      郡司天博,鈴木遥,塚田学
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Synthesis and properties of cage octasilicate polymers cross-linked by alcohols2017

    • Author(s)
      Takahiro Igarashi, Takahiro Gunji, and Satoru Tsukada
    • Organizer
      19th International Sol-Gel Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of metal complex-containing polysiloxane or polysilsesquioxane films2017

    • Author(s)
      Satoru Tsukada, Takuya Sagawa, Midori Takemasa, and Takahiro Gunji
    • Organizer
      19th International Sol-Gel Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] セラミック多孔膜による高度分離:ナノ~サブナノ細孔の設計,評価と応用2017

    • Author(s)
      都留稔了
    • Organizer
      日本化学会第97春季年会ATPセッション
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Robust reverse osmosis (RO)/nanofiltration (NF) membranes with thermal stability and chlorine tolerance for expanding applications to various types of water resource2017

    • Author(s)
      T. Tsuru
    • Organizer
      The 3rd Asian Symposium on Water Reuse
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] シリカおよびオルガノシリカを用いたナノ/サブナノ多孔膜の開発と環境・エネルギーへの応用2017

    • Author(s)
      都留 稔了
    • Organizer
      第24回ヤングセラミスト・ミーティング特別講演
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Nano/subnanoporous ceramic membranes for molecular separation in gas and liquid phase2016

    • Author(s)
      T. Tsuru
    • Organizer
      The third Advanced Materials Conference
    • Place of Presentation
      Langkawi, Malaysia
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of SiO2-based nano/subnano-porous membranes and pore-size evaluation by nanopermporometry (NPP) and normalized Knudsen-based permeance (NKP)2016

    • Author(s)
      T. Tsuru
    • Organizer
      International Zeolite Membrane Meeting (IZMM)
    • Place of Presentation
      Dalian, China
    • Year and Date
      2016-08-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enhanced SO3 Decomposition in A Highly Stable Catalytic Membrane Reactor for Iodine-Sulfur Thermochemical Cycle2016

    • Author(s)
      L. Meng, X. Yu, M. Kanezashi, and T. Tsuru
    • Organizer
      The 10th Conference of Aseanian Membrane Society (AMS10
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-07-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Robust reverse osmosis and nanofiltration membranes for expanding applications2016

    • Author(s)
      T. Tsuru
    • Organizer
      International Conference on Inorganic Membranes
    • Place of Presentation
      Atlanta, USA
    • Year and Date
      2016-07-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリシロキサン系有機-無機ハイブリッド-最近の展開から2016

    • Author(s)
      郡司天博
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀,東京
    • Year and Date
      2016-06-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Free volume of separation membranes as studied by positron annihilation techniques2016

    • Author(s)
      Kenji Ito
    • Organizer
      14th International Workshop on Slow Positron Beam Techniques & Applications
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] かご型構造を有する元素ブロックの合成2016

    • Author(s)
      郡司天博
    • Organizer
      粉体粉末冶金協会平成28年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Nano/subnano-porous membranes for expanding applications: design and evaluation of porous structures2016

    • Author(s)
      T. Tsuru
    • Organizer
      化学工学会年会国際シンポジウム
    • Place of Presentation
      Osaka
    • Year and Date
      2016-03-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ポリシルセスキオキサンの合成と応用2016

    • Author(s)
      郡司天博
    • Organizer
      高分子学会東北支部宮城地区講演会
    • Place of Presentation
      東北大学
    • Year and Date
      2016-03-11
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Properties of Novel Cage Octasilicate Polymers2015

    • Author(s)
      Takahiro Igarashi, Satoru Tsukada, Takahiro Gunji
    • Organizer
      The 5th Asian Silicon Symposium
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Application of Proton-Conductive Polysilsesquioxane as a Proton-Conductive membrane in PEFC2015

    • Author(s)
      Takahiro Gunji, Satoru Tsukada
    • Organizer
      The 5th Asian Silicon Symposium
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoporosity in Functional Thin Materials Characterized by Positronium Annihilation Techniques2015

    • Author(s)
      Kenji Ito
    • Organizer
      17th International Conference on Positron Annihilation
    • Place of Presentation
      Wuhan, CHINA
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of cage octasilicate polymer2015

    • Author(s)
      Takahiro Gunji, Takahiro Igarashi, Satoru Tsukada, Yoshimoto Abe
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-performance organosilica membranes and expanding applications2015

    • Author(s)
      Toshinori Tsuru
    • Organizer
      International Symposium on Inorganic Membranes (ISIMS), plenary
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-07-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Robust organosilica membranes for expanding liquid-phase separation2015

    • Author(s)
      Toshinori Tsuru
    • Organizer
      Aseanian Membrane Society (AMS)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-07-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrogen production from energy carriers by silica-based catalytic membrane reactors2015

    • Author(s)
      Toshinori Tsuru
    • Organizer
      International Conference on Catalysis in Membrane Reactor (ICCMR)
    • Place of Presentation
      Szczecin, Poland
    • Year and Date
      2015-06-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] ゾル-ゲルテクノロジーの最新動向2017

    • Author(s)
      郡司天博
    • Total Pages
      416
    • Publisher
      シーエムシー出版
    • ISBN
      9784781312583
    • Related Report
      2017 Annual Research Report
  • [Book] Current Trends and Future Developments on (Bio-) Membranes :Chapter 9 Silica Membrane Application for Pervaporation Process2017

    • Author(s)
      Hiroki Nagasawa, Toshinori Tsuru
    • Total Pages
      388
    • Publisher
      Elsevier B.V.
    • Related Report
      2017 Annual Research Report
  • [Book] 元素ブロック材料の創出と応用展開2016

    • Author(s)
      郡司天博, 塚田学, 五十嵐隆浩
    • Total Pages
      9
    • Publisher
      CMC出版
    • Related Report
      2016 Annual Research Report
  • [Book] Carbon Dioxide Capture: Processes, Technology and Environmental Implications2016

    • Author(s)
      Xiuxiu Ren, Masakoto Kanezashi and Toshinori Tsuru
    • Total Pages
      12
    • Publisher
      Nova Publishers
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] ポリシルセスキオキサン系化合物を含む組成物、その製造方法、並びに当該組成物を含む封止材及びフィルム2017

    • Inventor(s)
      伊藤功三郎,多田励起,郡司天博
    • Industrial Property Rights Holder
      伊藤功三郎,多田励起,郡司天博
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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