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In-situ multiple measurements for integrated elucidation of lithium/oxygen transport/reaction phenomena and battery performance improvement

Research Project

Project/Area Number 15H02347
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Hirai Shuichiro  東京工業大学, 工学院, 教授 (10173204)

Co-Investigator(Kenkyū-buntansha) 植村 豪  東京工業大学, 工学院, 特任准教授 (70515163)
河村 雄行  岡山大学, 環境生命科学研究科, 教授 (00126038)
Project Period (FY) 2015-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥43,940,000 (Direct Cost: ¥33,800,000、Indirect Cost: ¥10,140,000)
Fiscal Year 2019: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2018: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2017: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Keywordsリチウム空気電池 / 熱工学 / エネルギー生成・変換
Outline of Final Research Achievements

The lithium-air battery is the secondary battery with the largest theoretical capacity. However, high rate discharge required for practical use cannot be realized. Because the low oxygen diffusivity in the electrolyte limits the discharge performance. In this study, low energy X-ray CT, XRD, and microfiber type oxygen sensor are used to elucidate and improve the oxygen transport and reaction phenomena in the cathode.
As a result, it was clarified that sufficient oxygen was not transported into the deep part of the cathode. The discharge reaction and precipitation of reaction products occurred near the electrode surface. Furthermore, it was shown that high rate discharge can be realized by improving the electrode structure and the impregnation state of the electrolyte.

Academic Significance and Societal Importance of the Research Achievements

本研究で活用したin-situ計測技術は,リチウム空気電池だけでなく,他の二次電池や燃料電池など,多数の電気化学デバイス内で生じる現象の計測に活用でき,理学・工学の広範囲の学術領域で使用される新規性がある.さらに研究対象であるリチウム空気電池については,その理論容量の大きさから,電気自動車用の重要な電源となるだけでなく,再生可能エネルギーの利用・普及に向けた,大容量かつ安全な蓄電デバイスとしても重要な役割が果たせる.本研究で対象とする水系リチウム空気電池では電解液に塩化リチウム水溶液を用いるため,従来の有機電解液を用いたリチウムイオン電池のような,短絡時の火災リスクも大幅に低減できる.

Report

(6 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (9 results)

All 2020 2018 2017 2016 2015

All Presentation (9 results) (of which Int'l Joint Research: 3 results)

  • [Presentation] リチウム空気電池正極性能に及ぼす電極構造と酸素輸送現象2020

    • Author(s)
      植村豪,長尾賢斗,山下雄大,藤本翔悟,桝田哲太郎,兒玉学,今西誠之,平井 秀一郎
    • Organizer
      日本伝熱シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水系リチウム空気電池正極構造が性能に及ぼす影響に関する研究2018

    • Author(s)
      植村豪,山下雄大,平井秀一郎
    • Organizer
      2018年度日本機械学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 微細ファイバーセンサーを用いたリチウム空気電池正極多孔質内の酸素濃度計測2017

    • Author(s)
      藤本 翔悟, 植村 豪, 今西 誠之, 平井 秀一郎
    • Organizer
      日本機械学会2017年度年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] OPTICAL MEASUREMENT OF OXYGEN CONCENTRATION2017

    • Author(s)
      S. Fujimoto, S. Uemura, N. Imanishi, S. Hirai
    • Organizer
      The 9th JSME-KSME Thermal and Fluids Engineering Conference (TFEC9)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxygen Concentration Measurement in the Porous Cathode of Aqueous Lithium-Air Battery By Fine Optical Fiber2017

    • Author(s)
      Shogo Fujimoto, Suguru Uemura, Nobuyuki Imanishi and Shuichiro Hirai
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of O2 Concentration and Precipitates on the Lithium Air Battery2016

    • Author(s)
      2)Suguru Uemura, Kosuke Torikai, Tomoaki Furuyama, Takashi Sasabe, Nobuyuki Imanishi, Shuichiro Hirai
    • Organizer
      ECS meeting, PRiME2016
    • Place of Presentation
      Hawaii Convention Center(Honolulu, Hawaii)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リチウム空気電池性能特性に及ぼす酸素濃度・析出物の影響2016

    • Author(s)
      植村豪, 古山知諒, 鳥飼孝介, 笹部崇, 今西誠之, 平井秀一郎
    • Organizer
      第53回日本伝熱シンポジウム
    • Place of Presentation
      グランキューブ大阪(大阪)
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] 低エネルギーX線CT計測による水系リチウム空気電池電極内析出挙動の可視化2015

    • Author(s)
      古山知諒, 植村豪, 笹部崇, 今西誠之, 平井秀一郎
    • Organizer
      日本機械学会 熱工学コンファレンス2015
    • Place of Presentation
      大阪大学 吹田キャンパス
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] フロー型リチウム空気電池における物質移動・反応の数値シミュレーション2015

    • Author(s)
      桝田哲太郎, 植村豪, 平井秀一郎
    • Organizer
      日本機械学会 熱工学コンファレンス2015
    • Place of Presentation
      大阪大学 吹田キャンパス
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-11-04  

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