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Thermal separation of radioactive cesium in polluted soil by assisted with nano-sized magnetite

Research Project

Project/Area Number 15H02844
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Modeling and technologies for environmental conservation and remediation
Research InstitutionPrefectural University of Hiroshima

Principal Investigator

MITOMA Yoshiharu  県立広島大学, 生命環境学部, 教授 (20301674)

Co-Investigator(Kenkyū-buntansha) 奥田 哲士  龍谷大学, 理工学部, 准教授 (60343290)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2017: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywords放射性セシウム / 熱分離 / 磁気分離 / 塩化鉄 / 除染 / 放射性汚染物質 / ナノ粒子 / 分級 / 環境材料 / 環境技術 / 廃棄物処理 / 有害化学物質 / 放射線
Outline of Final Research Achievements

Soon after the Fukushima Dai-ichi Nuclear Power Plant sustained a powerful earthquake on March 11 in 2011, it was inundated by a huge tsunami that led to failed resumption of power. Even today, cesium-contaminated sites near the plant present difficulties for public health and the environment. Under these circumstances, we demonstrated that iron chloride (III) is extremely effective for removing of cesium in polluted soil under heating conditions. This research explains the efficiency of iron chloride for dry separation of cesium in soils of three kinds such as sandy soil, field soil, and clay. Results of many investigations indicate the optimum conditions under comparative mild conditions like lower heating and lack of wastewater. For instance, an addition from 0.2 wt% to 10 wt% of iron chlorides to total targeted soil facilitated a 99 % of separation of cesium in polluted soil at 900 oC for 2 hours treatment.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (32 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (4 results) Journal Article (11 results) (of which Int'l Joint Research: 10 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) (of which Int'l Joint Research: 6 results,  Invited: 5 results) Book (4 results)

  • [Int'l Joint Research] Ulsan University(South Korea)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Politehnica University of Bucharest(Romania)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Ulsan University(韓国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Politehnica University of Bucharest(Romania)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Sustainable recovery of precious metals from end-of-life vehicles shredder residue by a novel hybrid ballmilling and nanoparticles enabled froth flotation process2018

    • Author(s)
      Mallampati, Srinivasa Reddy; Lee, Byoung Ho; Mitoma, Yoshiharu; Simion, Cristian
    • Journal Title

      Journal of Cleaner Production

      Volume: 171 Pages: 66-75

    • DOI

      10.1016/j.jclepro.2017.09.279

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heterogeneous nano-Fe/Ca/CaO catalytic ozonation for selective surface hydrophilization of plastics containing brominated and chlorinated flame retardants (B/CFRs): separation from automobile shredder residue by froth flotation2017

    • Author(s)
      Mallampati Srinivasa Reddy; Lee Byoung Ho; Mitoma Yoshiharu; Simion Cristian
    • Journal Title

      Environmental science and pollution research international

      Volume: 24 Pages: 4469-4479

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrodehalogenation of hexachloro- and hexabromobenzene by metallic calcium in ethanol, in the presence of Rh/C catalyst2017

    • Author(s)
      Katayama Yumi; Aoyagi Mitsuru; Matsumoto Takuya; Harada Hiroyuki; Egashira Naoyoshi; Mitoma Yoshiharu; Simion Alina M; Simion Cristian
    • Journal Title

      Environmental science and pollution research international

      Volume: 24 Issue: 1 Pages: 591-597

    • DOI

      10.1007/s11356-016-7785-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Selective sequential separation of ABS/HIPS and PVC from automobile and electronic waste shredder residue by hybrid nano-Fe/Ca/CaO assisted ozonisation process2017

    • Author(s)
      Mallampati, Srinivasa Reddy; Lee, Byoung Ho; Mitoma, Yoshiharu; Simion, Cristian
    • Journal Title

      Waste Management

      Volume: 60 Pages: 428-438

    • DOI

      10.1016/j.wasman.2017.01.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dual mechanochemical immobilization of heavy metals and decomposition of halogenated compounds in automobile shredder residue using a nano-sized metallic calcium reagent2016

    • Author(s)
      Mallampati Srinivasa Reddy, Lee Byoung Ho, Mitoma Yoshiharu, Simion Cristian
    • Journal Title

      Environmental Science and Pollution Research

      Volume: 23 Issue: 22 Pages: 22783-22792

    • DOI

      10.1007/s11356-016-7458-7

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Novel separation and immobilization of heavy metals in municipal solid waste gly ash by grinding with nano-Fe/Ca/CaO/[PO4] mixture2016

    • Author(s)
      Mallampati Srinivasa Reddy, Simion Cristian, Mitoma Yoshiharu
    • Journal Title

      Environmental Progress & Sustainable Energy

      Volume: 35 Pages: 1693-1698

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hydrodechlorination of PCDD/PCDF/PCB contaminants by simple grinding of contaminated soils with a nano-size calcium reagent,2016

    • Author(s)
      Mitoma, Yoshiharu; Simion, Alina M.; Mallampati, Srinivasa Reddy; Miyata, Hideaki; Kakeda,Mitsunori; Simion, Cristian.
    • Journal Title

      Environ. Prog. Sustain. Energy

      Volume: 35 Issue: 1 Pages: 34-40

    • DOI

      10.1002/ep.12183

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mechanisms of solidification and subsequent embrittlement of dephosphorization slag used in a subtidal zone as an alternative to sea sand and prevention of solidification by adding dredged soil,2016

    • Author(s)
      Hitomi Yano, Tetsuji Okuda, Satoshi Nakai, Wataru Nishijima, Terumi Tanimoto, Satoshi Asaoka, Shinjiro Hayakawa, Satoru Nakashima
    • Journal Title

      Clean Technologies and Environmental Policy

      Volume: 18 Issue: 4 Pages: 1-10

    • DOI

      10.1007/s10098-016-1110-6

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Immobilization and volume reduction of heavy metals in municipal solid waste fly ash using nano-size calcium and iron-dispersed reagent2015

    • Author(s)
      Mallampati, Srinivasa Reddy; Mitoma, Yoshiharu; Simion, Cristian; Lee, Byoung Ho.
    • Journal Title

      J. Air Waste Manage

      Volume: 65 Issue: 10 Pages: 1247-1255

    • DOI

      10.1080/10962247.2015.1077175

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solevnt-free synthesis and application of nano-Fe/Ca/Cao/[PO4] composite for dual separation and immobilization of stable and radioactive cesium in contaminated soils.2015

    • Author(s)
      Mallampati, Srinivasa, Reddy; Mitoma, Yoshiharu; Okuda, Tetsuji; Simion, Cristian; Lee ,Byeong, Kyu.
    • Journal Title

      J. Hazar. Mater.

      Volume: 297 Pages: 74-82

    • DOI

      10.1016/j.jhazmat.2015.04.071

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent.2015

    • Author(s)
      Lee, Chi-Hyeon; Nguyen Thi Thanh Truc; Mitoma, Yoshiharu; Mallampati, Srinivasa, Reddy.
    • Journal Title

      J. Hazar. Mater.

      Volume: 297 Pages: 239-247

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 機能性マグネタイトを土壌分級助剤として用いる常温乾式除染方法とその装置2017

    • Author(s)
      三苫好治
    • Organizer
      電気学会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Effective remediation of radioactive cesium-contaminated dry soils with a functional magnetite and intrinsic performances2017

    • Author(s)
      Y. Mitoma
    • Organizer
      International Conference & Exhibition on Advanced & Nano Materials (ICANM-2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 機能性磁性鉄粉を用いた乾式土壌分級による除染技術2017

    • Author(s)
      久保ひとみ,三苫好治,中島春介,岩間彩,佐藤友祐
    • Organizer
      第6回環境放射能除染研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 触媒上原子状水素吸着量が与える脱塩素化反応効率への影響評価2017

    • Author(s)
      片山裕美,三苫好治
    • Organizer
      第26回環境化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electrochemical detection of atomic hydrogen on calcium-assisted catalyst and its hydrodechlorination efficiency2017

    • Author(s)
      Y. Katayama and Y. Mitoma
    • Organizer
      BIT’s 8th Annual Global Congress of Catalysis-2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Y. Katayama and Y. Mitoma, Effect of zeta potential for Pd/C and Rh/C on the efficiency of dechlorination using a Ca-based hydrodechlorination2017

    • Author(s)
      Y. Katayama and Y. Mitoma
    • Organizer
      International Conference on Environmental and Computer Science (ICECS 2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fractionalization of Actual Contaminated Soil Containing High Concentrations of Radioactive Cesium by a Nano-size Fe/Ca Composite under Solvent-free and non-Heating Conditions2017

    • Author(s)
      Mitoma Y., Katayama Y., Mallampati S. R., Simion C.
    • Organizer
      BIT’s 3rd World Congress of Smart Materials 2017
    • Place of Presentation
      Bangkok (Thailand)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reduction of halogenated benzenes using a metallic Ca-catalyst method.2016

    • Author(s)
      Ymi Katayama, Ryo Kato, Hiroyuki Harada, Simion Cristian, Yoshiharu Mitoma.
    • Organizer
      日本化学会第96春季年会(2016),
    • Place of Presentation
      同志社大学京田辺キャンパス, 京都.
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hybrid Nano-sized calcium and magnetite dispersion enabled remediation of multiple soil contaminants2016

    • Author(s)
      Yoshiharu Mitoma
    • Organizer
      International Conference & Exhibition on Advanced & Nano Materials
    • Place of Presentation
      Montreal (Canada)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マグネタイトを利用する土壌中セシウ ムの非加熱無排水式除染技術2016

    • Author(s)
      三苫好治,久保ひとみ,森茂久,中島春介,岩 間彩
    • Organizer
      第5回 環境放射能除染研究発表会
    • Place of Presentation
      福島県
    • Related Report
      2016 Annual Research Report
  • [Presentation] Dry, non-heated decontamination of radioactive cesium polluted soils using paramagnetic Fe3O4.2015

    • Author(s)
      Yoshiharu Mitoma, Cristian Simion, Srinivasa Reddy Mallampati, Tetsuji Okuda, Kenichi Nakata.
    • Organizer
      2015環太平洋国際化学会議(PACIFICHEM2015).
    • Place of Presentation
      Hawaii Convention Center, USA.
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MULTI-FUNCTIONED REMEDIATION TECHNIQUE FOR INORGANIC POLLUTANTS IN SOIL, USING A NANO-SIZED CALCIUM DISPERSING SYSTEM.2015

    • Author(s)
      Yoshiharu Mitoma, Srinivasa Reddy Mallampati, Hiromi Danjo, Hitomi Kubo, Mitsunori Kakeda,Simion Cristian.
    • Organizer
      PTIM2015(1ST INTERNATIONAL CAPARICA CONFERENCE ON POLLUTANT TOXIC IONS AND MOLECULES)
    • Place of Presentation
      Largo Aldeia dos Capuchos. Caparica, PORTUGAL.
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PCBs’ Dry Hydrodechlorination in Soil with Iron Powder, in the Presence of a Crystalohydrate, under Moderate Heating Conditions.2015

    • Author(s)
      Mitoma, Yoshiharu
    • Organizer
      BIT's 6th Annual Global Congress of Catalysis (GCC 2015).
    • Place of Presentation
      Xi’an Qujiang International Conference Center, CHINA.
    • Year and Date
      2015-09-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Metal Nanoparticles: Metallic Nanoparticles Used in Soil Remediation Procedures2016

    • Author(s)
      Yoshiharu Mitoma, Sirinivasa Reddy Mallampati, Tetsuji Okuda, Cristian Simion
    • Total Pages
      1186
    • Publisher
      CRC press
    • Related Report
      2016 Annual Research Report
  • [Book] Dual Soil Decontamination Procedures2016

    • Author(s)
      Yoshiharu Mitoma, Alina M Simion, Cristian Simion
    • Total Pages
      342
    • Publisher
      InTech
    • Related Report
      2016 Annual Research Report
  • [Book] ナノ粒子化したカルシウム/鉄系ハイブリッド無機材料による放射性セシウム汚染土壌の乾式分級技術2016

    • Author(s)
      三苫好治
    • Total Pages
      256
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report
  • [Book] CRC Concise Encyclopedia of Nanotechnology,2015

    • Author(s)
      Mitoma, Yoshiharu; Mallampati, Srinivasa, Reddy; Okuda, Tetsuji; Simion, Cristian.
    • Total Pages
      1186
    • Publisher
      CRC Press
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-11-04  

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