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Design of materials for the environmental purification including radioactive cesium dust by effective utilization of fiber

Research Project

Project/Area Number 15H02886
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Clothing life/Dwelling life
Research InstitutionYamagata University (2018-2019)
Fukushima University (2015-2017)

Principal Investigator

KANAZAWA HITOSHI  山形大学, 大学院有機材料システム研究科, 客員教授 (50143128)

Project Period (FY) 2015-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2019: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Keywords吸着 / 分子間相互作用 / 繊維 / ポリアミノ酸 / 分子認識 / 放射性セシウム / タンパク質 / セルロース / 汚染物質 / 化学的改質 / セシウム / 改質 / 環境浄化 / 有機化合物 / αヘリックス / βシ-ト構造 / グラフト化 / 分子形態 / フィルター / プルシャンブルー
Outline of Final Research Achievements

[Design of environmental purification materials using fibers] I found that various fibers adsorb organic compounds selectively by each fiber when they are put in the organic compounds vapor mixture atmosphere. A serious of poly(amino acid)s were prepared in order to consider the adsorption property of protein fibers. When the poly(amino acid)s were put in organic compound vapor mixture atmosphere, each poly(amino acid) showed each own selective adsorption pattern. As a result, for example, it was found that poly(L-alanine) and poly(L-valine) can be distinguished from each other by the present adsorption method, although an IR spectroscopy is not effective for it. [Handling of radioactive cesium-adsorbed dust] Radioactive cesium was chemically tested and it was found that it exists in a "water-insoluble state". Assuming that the radioactive cesium adsorbed dust has a negative charge, the adsorption by fibers having a positive charge was examined. The results are under consideration.

Academic Significance and Societal Importance of the Research Achievements

「高分子に対する低分子の吸着は、互いの分子の相互作用によって、選択的に起こる」という仮説のもとで、一連の研究を行ってきた。その結果、高分子に対する有機化合物蒸気の吸着をガスクロマト分析することによって、構造類似の高分子の識別が可能になる事を見出した。例えば、ナイロン66とナイロン6は、各種機器では識別できないが、吸着実験によって、識別可能である。類似の研究は、世界中の研究に見られない。従って、本研究は独創的で、学術的意義は大きいと考えられる。「放射性セシウムの対策には、それらを吸着した粉塵の吸着除去が最終的課題になる」と考えた。実際に放射性セシウムを含む物質を扱うので、研究の意義はある。

Report

(3 results)
  • 2019 Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (27 results)

All 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (24 results) (of which Int'l Joint Research: 15 results,  Invited: 1 results) Book (1 results)

  • [Journal Article] 放射性セシウムの化学的考察―風評被害を考える2016

    • Author(s)
      金澤 等, 稲田 文, 中村和由
    • Journal Title

      地域創造(福島大学)

      Volume: 28 Pages: 3-16

    • NAID

      40020986292

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] アミノ酸NCAの結晶化と固相重合2016

    • Author(s)
      金澤 等
    • Journal Title

      日本化学会 有機結晶部会ニュースレター

      Volume: 38 Pages: 80-86

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Re-examination of the Polymerization of Amio Acid NCAs. 75. Secondary-amine initiated polymerization of amino acid NCAs2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      the 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      福岡国際会議場(福岡市博多区)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of Chemically Stable Polymeric Materials 84. Improvement in the adhesion property of polymer composites.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      the 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      福岡国際会議場(福岡市博多区)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of Chemically Stable Polymeric Materials 78. Modification of chemically stable polymeric materials 78. Preparation of silicone/fluorocarbon resins useful for PSA tape backing.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      2nd International Pressure Sensitive Adhesive Technoforum (IPSAT)
    • Place of Presentation
      東京国際交流会館平成プラザ(東京都江東区青海)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of Chemically Stable Polymeric Materials 79. Preparation of silicone resin sheets to which double-coated adhesive tapes are adhered.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      2nd International Pressure Sensitive Adhesive Technoforum (IPSAT)
    • Place of Presentation
      東京国際交流会館平成プラザ(東京都江東区青海)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of chemically stable polymeric materials 80. Improvement in the adhesion property of GFRP and CFRP2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      The 10th Asian-Australasian Conference on Composite Materials (ACCM-10),
    • Place of Presentation
      釜山(韓国)
    • Year and Date
      2016-10-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of Chemically Stable Polymeric Materials 81. Improvement of the adhesion property of CFRP/CFRTP and preparation of PET reinforced epoxy resin.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      The 10th Asian-Australasian Conference on Composite Materials (ACCM-10)
    • Place of Presentation
      釜山(韓国)
    • Year and Date
      2016-10-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学的に安定な高分子の改質82. クルマなどの軽量化を目指した高分子・複合材料の接着性改良2016

    • Author(s)
      稲田 文, 金澤 等
    • Organizer
      繊維学会秋季大会
    • Place of Presentation
      山形大学工学部(山形県米沢市)
    • Year and Date
      2016-09-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] アミノ酸 NCA 重合の再検討 76. アミノ酸NCAの重合機構の不明な点の解決2016

    • Author(s)
      金澤 等,稲田 文,中島 孝明
    • Organizer
      繊維学会秋季大会
    • Place of Presentation
      山形大学工学部(山形県米沢市)
    • Year and Date
      2016-09-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] A novel Technique to Increase the Adhesion Property of FRP and CFRP Materials.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      International Conference on Composites and Nano Engineering (ICCE-24)
    • Place of Presentation
      海南島(中国)
    • Year and Date
      2016-07-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Improvement in the Adhesion Property of Chemically Stable Plastics and FRPS.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada
    • Organizer
      International Conference on Composites and Nano Engineering (ICCE-24)
    • Place of Presentation
      海南島(中国)
    • Year and Date
      2016-07-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フキノトウ含有の放射性セシウムの年次変化2016

    • Author(s)
      稲田 文, 金澤 等
    • Organizer
      第5回環境放射能除染学会研究発表会
    • Place of Presentation
      福島県文化センター(福島県福島市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 環境に存在する放射性セシウムの化学的性質2016

    • Author(s)
      金澤 等, 稲田 文
    • Organizer
      第5回環境放射能除染学会研究発表会
    • Place of Presentation
      福島県文化センター(福島県福島市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Modification of Chemically Stable Polymeric Materials 72. Improvement of the adhesion property of polyolefins, FRP and CFRP.2016

    • Author(s)
      Hitoshi Kanazawa, Aya Inada and Takuto Tanaka
    • Organizer
      ACA (Asian Conference on Adhesion)
    • Place of Presentation
      東京国際交流会館平成プラザ(東京都江東区青海)
    • Year and Date
      2016-06-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular interaction between polymers and low-molecular weight compounds. 20 Adsorption of organic compounds to polymer films.2016

    • Author(s)
      Aya Inada , Hitoshi Kanazawa and Yuki Yamaguchi
    • Organizer
      ACA (Asian Conference on Adhesion)
    • Place of Presentation
      東京国際交流会館平成プラザ(東京都江東区青海)
    • Year and Date
      2016-06-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学的に安定な高分子の改質 70. 安定な高分子材料,FRP,CFRPの接着性改良2016

    • Author(s)
      金澤 等, 稲田 文, 田中拓翔
    • Organizer
      第27回プラスチック成形加工学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江東区)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 化学的に安定な高分子材料の改質 69.高分子複合材料・FRP,GFRPの接着性改良2016

    • Author(s)
      金澤 等, 稲田 文, 田中拓翔, 新井貴裕
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江東区)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 繊維・高分子材料と有機化合物の相互作用 22 ポリマーフィルムの吸着特性2016

    • Author(s)
      稲田 文, 金澤 等
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江東区)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 繊維・高分子材料と有機化合物の相互作用21. ポリマーフィルムの吸着特性2016

    • Author(s)
      稲田 文, 金澤 等
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] N-カルボキシアミノ酸無水物の反応性の再検討 73. 第1級アミンと第3級アミン開始重合機構の考察2016

    • Author(s)
      金澤 等, 稲田 文, 金澤裕貴
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Re-examination of Amio Acid NCA Polymerization 65. Preparation of mono-dispersed high molecular weight polypeptides by the polymerization of amino acid N-carboxy anhydride initiated by tertiary amine2015

    • Author(s)
      H. Kanazawa, Y. Kanazawa, A.Inada
    • Organizer
      PACIFICHEM(環太平洋国際化学会議)
    • Place of Presentation
      ホノルル市(USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Re-examination of Amio Acid NCA Polymerization 64. Preparation of mono-dispersed high molecular weight polypeptides by the primary amine initiated polymerization of amino acid N-carboxy anhydride2015

    • Author(s)
      H. Kanazawa, A.Inada
    • Organizer
      PACIFICHEM(環太平洋国際化学会議)
    • Place of Presentation
      ホノルル市(USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular interaction between polymers and low-molecular weight compounds 19. Identification of poly(amino acid)s2015

    • Author(s)
      H. Kanazawa, A.Inada
    • Organizer
      PACIFICHEM(環太平洋国際化学会議)
    • Place of Presentation
      ホノルル市(USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of chemically stable polymeric materials 61. Improvement in the adhesive property of polymeric and FRP materials2015

    • Author(s)
      H. Kanazawa, T. Tanaka, A. Inada and T. Arai
    • Organizer
      PACIFICHEM(環太平洋国際化学会議)
    • Place of Presentation
      ホノルル市(USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of chemically stable polymeric materials 60. Improvement in the adhesive property of polymeric and FRP materials2015

    • Author(s)
      H. Kanazawa, A.Inada, T.Tanaka
    • Organizer
      PACIFICHEM(環太平洋国際化学会議)
    • Place of Presentation
      ホノルル市(USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Book] Advances in Organic Crystal Chemistry, Topochemical polymerization of amino acid N-carboxy anhydrides in crystalline state2016

    • Author(s)
      H. Kanazawa, et al.
    • Total Pages
      706
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-11-04  

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