• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Functionality tuning based on morphological and structural control of low-dimensional hydroxide nanomaterials

Research Project

Project/Area Number 15H03534
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

Ma Renzhi  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, グループリーダー (90391218)

Co-Investigator(Renkei-kenkyūsha) TAKADA Kazunori (EBINA Yasuo)  物質・材料研究機構, エネルギー・環境材料拠点, 拠点長 (30354400)
Research Collaborator SUN Pengzhan  
MA Wei  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2016: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywords水酸化物 / ナノシート / イオン伝導 / 複合材料 / 燃料電池 / 遷移金属 / ナノ構造 / 機能開拓 / ナノコーン / イオン交換 / グラフェン / 脱塩処理
Outline of Final Research Achievements

We succeed in synthesizing a hybrid thin film/membrane featured with a superlattice structure by combining hydroxide nanosheet and graphene oxide at the molecular level. It showed a highly selective ion separation/transport property with the relative selectivity of monovalent to trivalent cations reached above 30. In addition, we discovered that hydroxide nanosheets exhibited a very high ionic conductivity approaching 10-1 S/cm. This conductivity is 10 to 100 times higher than that of conventional hydroxide ion conductor. In contrast, the conductivity in the thickness direction of the nanosheets was found to be on the order of 10-6 S/cm. Such a highly anisotropic conduction characteristic is thought to be derived from the two-dimensional structure of nanosheets.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (19 results)

All 2018 2017 2016 2015

All Journal Article (9 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 9 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (9 results) (of which Int'l Joint Research: 6 results,  Invited: 7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Recent progress on exploring exceptionally high and anisotropic H+/OH ion conduction in two-dimensional materials2018

    • Author(s)
      Pengzhan Sun, Renzhi Ma,Takayoshi Sasaki
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 1 Pages: 33-43

    • DOI

      10.1039/c7sc04019a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Liquid phase exfoliation of MoS2 assisted by formamide solvothermal treatment and enhanced electrocatalytic activity based on (H3Mo12O40P/MoS2)n multilayer structure2017

    • Author(s)
      Jinzhao Huang, Xiaolong Deng, Hao Wan, Fashen Chen, Yifan Lin, Xijin Xu, Renzhi Ma, Takayoshi Sasaki
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 6 Issue: 4 Pages: 5227-5237

    • DOI

      10.1021/acssuschemeng.7b04873

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Layered rare-earth hydroxide nanocones with facile host composition modification and anionexchange feature: Topotactic transformation into oxide nanocones for upconversion2017

    • Author(s)
      Yishun Zhong, Gen Chen, Xiaohe Liu, Dan Zhang, Ning Zhang, Junhui Li, Shuquan Liang, Renzhi Ma, Guanzhou Qiu
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 24 Pages: 8185-8191

    • DOI

      10.1039/c7nr02001e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Large-scale preparation, chemical exfoliation, and structural modification of layered zinc hydroxide nanocones: Transformation into zinc oxide nanocones for enhanced photocatalytic properties2017

    • Author(s)
      Dan Zhang, Xiaohe Liu, Hao Wan, Ning Zhang, Shuquan Liang, Renzhi Ma, Guanzhou Qiu
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 5 Issue: 7 Pages: 5869-5879

    • DOI

      10.1021/acssuschemeng.7b00597

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Single-layer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity2017

    • Author(s)
      Pengzhan Sun, Renzhi Ma, Xueyin Bai, Kunlin Wang, Hongwei Zhu, Takayoshi Sasaki
    • Journal Title

      Science Advances

      Volume: 2 Issue: 4

    • DOI

      10.1126/sciadv.1602629

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Intrinsic High Water/Ion Selectivity of Graphene Oxide Lamellar Membranes in Concentration Gradient-Driven Diffusion2016

    • Author(s)
      P. Sun, R. Ma, H. Deng, Z. Song, Z. Zhen, K. Wang, T. Sasaki, Z. Xu, and H. Zhu
    • Journal Title

      CHEMICAL SCIENCE

      Volume: 7 Issue: 12 Pages: 6988-6994

    • DOI

      10.1039/c6sc02865a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Controllable fabrication of urchin-like Co3O4 hollow spheres for highperformance supercapacitors and lithium-ion batteries2016

    • Author(s)
      Fashen Chen, Xiaohe Liu, Zhian Zhang, Ning Zhang, Anqiang Pan, Shuquan Liang, Ma RZ
    • Journal Title

      Dalton Transactions

      Volume: 45 Issue: 38 Pages: 15155-15161

    • DOI

      10.1039/c6dt02603f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Highly Selective Charge-Guided Ion Transport through a Hybrid Membrane Consisting of Anionic Graphene Oxide and Cationic Hydroxide Nanosheets Superlattice Units2016

    • Author(s)
      Pengzhan Sun, Renzhi Ma, Wei Ma, Jinghua Wu, Kunlin Wang, Takayoshi Sasaki, Hongwei Zhu
    • Journal Title

      NPG Asia Materials

      Volume: 8 Issue: 4 Pages: e259-e259

    • DOI

      10.1038/am.2016.38

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Perovskite Solar Cell Using a Two-Dimensional Titania Nanosheet Thin Film as the Compact Layer2015

    • Author(s)
      Can Li, Yahui Li, Yujin Xing, Zelin Zhang, Xianfeng Zhang, Zhen Li, Yantao Shi, Tingli Ma, Renzhi Ma, Kunlin Wang, Jinquan Wei
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 7 Issue: 28 Pages: 15117-15122

    • DOI

      10.1021/acsami.5b01959

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Chemical synthesis and hetero-assembly of 2D hydroxide nanosheets for energy-related applications2018

    • Author(s)
      Renzhi Ma, Takayoshi Sasaki
    • Organizer
      KEIO International Symposium on 2D Materials 2018 (K2D-18)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2D functional nanosheets: Soft chemical synthesis, assembly and properties2017

    • Author(s)
      Renzhi Ma, Takayoshi Sasaki
    • Organizer
      The 12th Japan-France Workshop on Nano-materials (NanoMat2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ion conducting and electrocatalytic properties of single-layer metal hydroxide nanosheets2017

    • Author(s)
      Renzhi Ma, Pengzhan Sun, Wei Ma, Takayoshi Sasaki
    • Organizer
      IUPAC 13th International Conference on Novel Materials and their Synthesis (NMS-XIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノシートと酸化グラフェンとのヘテロ集積材料2017

    • Author(s)
      馬仁志、佐々木高義
    • Organizer
      グラフェン・酸化グラフェン合同シンポジウム
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Soft chemical exfoliation of layered oxides and hydroxides: 2D functional nanosheets2016

    • Author(s)
      Renzhi Ma, Takayoshi Sasaki
    • Organizer
      RIKEN CEMS Topical Meeting 2016
    • Place of Presentation
      日本埼玉県和光市理化学研究所
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Two-dimensional hydroxide nanosheets2016

    • Author(s)
      Renzhi Ma, Takayoshi Sasaki
    • Organizer
      International Forum on Advanced Functional Materials for Young Scientists
    • Place of Presentation
      中国アモイ厦門理工大学
    • Year and Date
      2016-04-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 二次元ナノシートのヘテロ集積化とその応用2015

    • Author(s)
      馬仁志
    • Organizer
      表面技術協協会関東支部講演会
    • Place of Presentation
      信州大学
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Function Exploration of Hetero-assembled Redoxable Nanosheets and Graphene2015

    • Author(s)
      Renzhi Ma
    • Organizer
      The 2nd International Symposium of Advanced Inorganic Materials
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2015-10-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transition-metal Based Hydroxide Nanostructures with Diverse Application Prospects2015

    • Author(s)
      Renzhi Ma
    • Organizer
      IUPAC 11th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      Qinhuangdao, China
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] 燃料電池および水電解装置2016

    • Inventor(s)
      馬仁志、佐々木高義、孫鵬展
    • Industrial Property Rights Holder
      国立研究開発法人物質・材料研究機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-251111
    • Filing Date
      2016-12-26
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi