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Fabrication of envionment-sensitive Pi-electron nano-porous materials using stacked-graphene edges and its properties

Research Project

Project/Area Number 15H03537
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials engineering
Research InstitutionShinshu University

Principal Investigator

HAYASHI Takuya  信州大学, 学術研究院工学系, 教授 (80313831)

Co-Investigator(Kenkyū-buntansha) 村松 寛之  信州大学, 学術研究院工学系, 准教授 (70509984)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2015: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywordsグラフェン / CSCNT / π電子 / カップ積層型カーボンナノチューブ / ナノカーボン
Outline of Final Research Achievements

By spray coating the graphene/ graphene oxide flake, we prepared a filtration membrane for desalination and other separation. As a result, 85~96% desalination was achieved. It was found that not only the hole within the graphene, but also the edge space and interlayer space were crucial for the efficient atomic/ molecular separation.
Oxidation of cup-stacked carbon nanotube resulted in the expansion of the interlayer spacings and cleavage of the tube, which enabled us to make the most of the internal graphene edge. It was found that the surface area increased up to 400% of the untreated nanotube.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (10 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results) Presentation (7 results)

  • [Journal Article] Effective NaCl and dye rejection of hybrid graphene oxide/graphene layered membranes2017

    • Author(s)
      Morelos-Gomez Aaron、Cruz-Silva Rodolfo、Muramatsu Hiroyuki、Ortiz-Medina Josue、Araki Takumi、Fukuyo Tomoyuki、Tejima Syogo、Takeuchi Kenji、Hayashi Takuya、Terrones Mauricio、Endo Morinobu
    • Journal Title

      Nature Nanotechnology

      Volume: 12 Issue: 11 Pages: 1083-1088

    • DOI

      10.1038/nnano.2017.160

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Linear carbon chains inside multi-walled carbon nanotubes: Growth mechanism, thermal stability and electrical properties2016

    • Author(s)
      Cheon-Soo Kang, Kazunori Fujisawa, Yong-Il Ko, Hiroyuki Muramatsu, Takuya Hayashi , Morinobu Endo, Hee Jou Kim, Daun Lim, Jin Hee Kim, Yong Chae Jung, Mauricio Terrones, Mildred S. Dresselhaus, Yoong Ahm Kim
    • Journal Title

      Carbon

      Volume: 107 Pages: 217-224

    • DOI

      10.1016/j.carbon.2016.05.069

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Optical sensitivity of mussel protein-coated double-walled carbon nanotubes on the iron conjugation bond2016

    • Author(s)
      Yong-Il Ko, Cheon-Soo Kang, Eun-Ae Shin, Yong Chae Jung, Hiroyuki Muramatsu, Takuya Hayashi, Yoong Ahm Kim, Mildred S. Dresselhaus
    • Journal Title

      RSC advances

      Volume: 6 Issue: 20 Pages: 16308-16313

    • DOI

      10.1039/c5ra27842b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Hummers法によるCSCNTの短尺化2017

    • Author(s)
      鵜飼宗典, 林卓哉, 村松寛之
    • Organizer
      情報通信学会信越支部大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ソルボサーマル還元法によるグラフェンに担持させたシリコンのリチウムイオン二次電池負極特性評2017

    • Author(s)
      藤野文範, 大城順己, 林卓哉, 村松寛之
    • Organizer
      情報通信学会信越支部大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カップ積層型カーボンナノチューブに担持させた白金粒子に樹脂系材料による被膜法が与える影響2017

    • Author(s)
      小泉拓真, 勝呂博, 横川泰貴, 鵜飼宗典, 村松寛之, 林卓哉
    • Organizer
      情報通信学会信越支部大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カップ積層型カーボンナノチューブに担持させた白金粒子に樹脂系材料による被膜法が与える影響2016

    • Author(s)
      小泉 拓真・梶浦 良紀・田中 義也・勝呂 博・村松 寛之・林 卓哉
    • Organizer
      電子情報通信学会信越支部大会
    • Place of Presentation
      長岡技科大
    • Year and Date
      2016-10-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 窒素およびホウ素を共ドープしたグラフェンを用いた水素発生反応2016

    • Author(s)
      梶浦 良紀・田中 義也・村松 寛之・林 卓哉
    • Organizer
      電子情報通信学会信越支部大会
    • Place of Presentation
      長岡技科大
    • Year and Date
      2016-10-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mussel Protein-Dispersed Double-Walled Carbon Nanotube and Metal Absorbed Biocomposite2015

    • Author(s)
      高 永一,姜 天水,村松 寛之,林 卓哉
    • Organizer
      炭素材料学会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
  • [Presentation] グラフェンへのナノ気孔導入の検討2015

    • Author(s)
      平出博樹, 高永一, 姜天水, 前川大輝, 高橋昌宏, 早坂祥, 林卓哉, 村松寛之
    • Organizer
      平成27年度電子情報通信学会信越支部大会
    • Place of Presentation
      新潟工科大学
    • Year and Date
      2015-10-03
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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