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Nanoholes inside polymer particles prepared by UV nano-processing technique above the diffraction limit of light

Research Project

Project/Area Number 15H03539
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials engineering
Research InstitutionTokyo University of Science

Principal Investigator

Kawai Takeshi  東京理科大学, 工学部工業化学科, 教授 (10224718)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywords中空粒子 / ナノ加工 / 紫外線照射 / UV照射
Outline of Final Research Achievements

We demonstrated that UV irradiation onto polystyrene (PS) particles with ~200 nm resulted in the formation of a hole below the wavelength of the UV light. Oxygen in the air and hydroxyl radical in water were absolutely crucial for fabricating the hole inside the PS particles. We also demonstrated that (i) the hole formed in the center of PS particles below 250 nm in diameter, while it formed in the bottom of the particles above 300 nm in diameter, (ii) the hole position depended on the refractive index of the atmosphere, (iii) changing the irradiation angle of UV light provided many holes inside each PS particle, and (iv) this UV irradiation technique can be applied for making the hole pattern on PS films. Further, we proved that TEM 3D-tomography technique is very useful to analyze the hole structure inside PS particles and that FDTD simulation can predict the hole position.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (24 results)

All 2018 2017 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results)

  • [Journal Article] Fractionation of binary polymer blend based on size distribution of particles prepared by phase inversion method2017

    • Author(s)
      Shuji Ichikawa and Takeshi Kawai
    • Journal Title

      Polymer

      Volume: 125 Pages: 276-282

    • DOI

      10.1016/j.polymer.2017.08.006

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-pot fabrication of multiporous polymer particles by phase inversion in emulsions2017

    • Author(s)
      Shuji Ichikawa and Takeshi Kawai
    • Journal Title

      COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

      Volume: 532 Pages: 570-577

    • DOI

      10.1016/j.colsurfa.2017.03.029

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly(styrene-co-acrylonitrile) Particles Prepared by Phase Inversion of W/O Emulsions2017

    • Author(s)
      Shuji Ichikawa, Yoshiro Imura, and Takeshi Kawai
    • Journal Title

      Journal of Oleo Science

      Volume: 66 Issue: 3 Pages: 269-277

    • DOI

      10.5650/jos.ess16176

    • NAID

      130005397215

    • ISSN
      1345-8957, 1347-3352
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dendritic Gold Nanowires Supported on SiO2 Nanoparticles Fabricated by a Seed Growth Method2016

    • Author(s)
      Clara Morita-Imura, Takuya Mori, Yoshiro Imura and Takeshi Kawai
    • Journal Title

      NEW JOURNAL OF CHEMISTRY

      Volume: 40 Issue: 8 Pages: 7048-7052

    • DOI

      10.1039/c6nj00161k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water and organic solvent dispersible gold nanorods that are pH responsive2016

    • Author(s)
      Yoshiro Imura, Kunihiro Fukuda, Clara Morita-Imura, and Takeshi Kawai
    • Journal Title

      ChemistrySelect

      Volume: 98 Issue: 17 Pages: 5404-5408

    • DOI

      10.1002/slct.201601248

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 紫外線照射によるポリスチレン粒子へのナノ螺旋空孔の作製とその光学特性2018

    • Author(s)
      村井洸太, 市川大翔, 伊村芳郎, ワン カーシェン, 河合武司
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 紫外線照射によるポリスチレン粒子への位置選択的な金属担持2018

    • Author(s)
      木下和彦, 市川大翔, 伊村芳郎, ワン カーシェン, 河合武司
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Transparent Conductive Ultrathin Films with High Flexibility Prepared by UV Light Irradiation on Metal NPs Monolayer2017

    • Author(s)
      Takeshi Kawai
    • Organizer
      15th International Conference on Advanced Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of anisotropic polystyrene particle monolayers by UV irradiation and immersion into solvent2017

    • Author(s)
      Hiroto Ichikawa, Ke-Hsuan Wang, Yoshiro Imura, Takeshi Kawai
    • Organizer
      Asian Conference on Oleo Science 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of organic hybrid non-spherical particles by ultraviolet irradiation on polystyrene particle monolayer2017

    • Author(s)
      Jun Yoshida, Ke-Hsuan Wang, Yoshiro Imura, Takeshi Kawai
    • Organizer
      Asian Conference on Oleo Science 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of self-propelled motion of PT-polystyrene hubrid particles prepared by ultraviolet irradiation2017

    • Author(s)
      Shota Ishimaru, Hiroto Ichikawa, Ke-Hsuan Wang, Yoshiro Imura, Takeshi Kawai
    • Organizer
      Asian Conference on Oleo Science 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリスチレン粒子膜への紫外線照射による有機-無機複合異形粒子の作製2017

    • Author(s)
      吉田潤, ワン カーシェン, 伊村芳郎, 河合武司
    • Organizer
      第68回コロイドおよび界面化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 紫外線照射および溶剤浸漬によるポリスチレン粒子加工技術2017

    • Author(s)
      市川大翔, 石丸翔太, ワン カーシェン, 伊村芳郎, 河合武司
    • Organizer
      第68回コロイドおよび界面化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 紫外線照射によるPt-ポリスチレンハイブリッド自走粒子の作製および自走挙動の制御2017

    • Author(s)
      石丸翔太, 市川大翔, 伊村芳郎,ワン カーシェン, 河合武司
    • Organizer
      第68回コロイドおよび界面化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of self-propelled motion of Pt-polystyrene hybrid particles prepared by ultraviolet irradiation2017

    • Author(s)
      Shota Ishimaru, Yoshiro Imura, Ke-hsuan Wang, Takeshi Kawai
    • Organizer
      90th JSCM Anniversary Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] コロイド粒子をレンズとして用いた紫外線照射による有機薄膜への自在形状パターニングとその応用2016

    • Author(s)
      市川大翔, ワンカーシェン, 伊村芳郎, 河合武司
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀 (東京都、江戸川区)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリスチレン粒子へのUV照射による新規中空化技術の開発とその応用2016

    • Author(s)
      高橋実和, ワンカーシェン, 伊村芳郎, 河合武司
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道教育大学旭川校(北海道、旭川市)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] コロイド粒子膜をレンズとして用いた紫外線照射による有機薄膜への自在形状パターニング2016

    • Author(s)
      市川大翔, ワンカーシェン, 伊村芳郎, 河合武司
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道教育大学旭川校(北海道、旭川市)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication technique of the hollow polystyrene nanoparticles by ultraviolet irradiation: Effect of incident angle2015

    • Author(s)
      Takahiro Kiryu, Takeshi Kawai
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu(アメリカ)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of the hollow polystyrene particles by ultravioret irradiation2015

    • Author(s)
      Shusaku Hayakawa, Takeshi Kawai
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu(アメリカ)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication technique of the hollow nanoparticles by ultraviolet irradiation2015

    • Author(s)
      Miwa Takahashi, Takeshi Kawai
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu(アメリカ)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリスチレン粒子膜へのUV照射による中空化技術:入射角の影響2015

    • Author(s)
      霧生貴裕, 高橋実和, 早川周作, 伊村芳郎, 河合武司
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀(東京都、江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリスチレン粒子膜へのUV照射による中空化技術:媒体の役割2015

    • Author(s)
      高橋実和, 霧生貴裕, 早川周作, 伊村芳郎, 河合武司
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀(東京都、江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリスチレン粒子膜へのUV照射による中空化技術:媒体の役割2015

    • Author(s)
      高橋実和, 霧生貴裕, 早川周作, 伊村芳郎, 河合武司
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県、鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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