Comprehensive analyses of volatiles in the Earth's interior using SIMS

• Project/Area Number: 15H03751
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Petrology/Mineralogy/Economic geology
• Research Institution: Japan Agency for Marine-Earth Science and Technology
• Principal Investigator: SHIMIZU Kenji 国立研究開発法人海洋研究開発機構, 高知コア研究所, 技術研究員 (30420491)
• Co-Investigator(Kenkyū-buntansha): 伊藤 元雄 国立研究開発法人海洋研究開発機構, 高知コア研究所, グループリーダー代理 (40606109) ; 上野 雄一郎 東京工業大学, 理学院, 教授 (90422542)
• Research Collaborator: ITO Shoichi ; USHIKUBO Takayuki ; HAMADA Morihisa ; MATSUURA Fumihiro
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000); Fiscal Year 2017: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2016: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2015: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
• Keywords: 揮発性物質 / SIMS / 火山ガラス / メルト包有物 / 地球内部物質循環 / 二次イオン質量分析 / 揮発性元素 / 二次イオン質量分析計

Outline of Final Research Achievements

The deep volatile cycles particularly water is indispensable for understanding the dynamics and chemical evolution of the Earth interior. However the systematic analytical method for volatile in rock samples are not well established in the solid sample, so it was far too far to elucidate its full view. In this study, we established analyses using a secondary ion mass spectrometer (SIMS) for concentration of volatile elements (water, carbon dioxide, fluorine, chlorine, chlorine and sulfur) and isotopic ratios (hydrogen, sulfur) in a least degassed deep submarine volcanic glass and a small melt inclusion incorporated in the magmatic minerals crystallized in deep crustal region. We are applying these analyses to the volcanic glasses at various tectonic setting and we are expecting to bring new development to elucidation of the deep volatile cycles of the Earth interior.

Research Products

• [Journal Article] High-precision <i>in situ</i> analysis of Pb isotopes in melt inclusions by LA-ICP-MS and application of Independent Component Analysis (2018)
  • Author(s): Hamada, M., Kimura, J., Chang, Q., Hanyu, T., Ushikubo, T., Shimizu, K., Ito, M., Ozawa, T. and Iwamori, H.
  • Journal Title: GEOCHEMICAL JOURNAL Volume: 52 Issue: 1 Pages: 69-74
  • DOI: 10.2343/geochemj.2.0497
  • NAID: 130006333264
  • ISSN: 0016-7002, 1880-5973
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Collision-induced post-plateau volcanism: evidence from a seamount on Ontong Java Plateau (2017)
  • Author(s): Hanyu, T., M. L. G. Tejada, K. Shimizu, O. Ishizuka, T. Fujii, J. -I. Kimura, Q. Chang, R. Senda, T. Miyazaki, Y. Hirahara, B. S., Vagalov, K. T., Goto, A. Ishikawa
  • Journal Title: Lithos Volume: 294-295 Pages: 87-96
  • DOI: 10.1016/j.lithos.2017.09.029
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] H₂O, CO₂, F, S, Cl, and P₂O₅ analyses of silicate glasses using SIMS: Report of volatile standard glasses (2017)
  • Author(s): Shimizu, K., T. Ushikubo, M. Hamada, S. Itoh, Y. Higashi, E. Takahashi, M. Ito
  • Journal Title: GEOCHEMICAL JOURNAL Volume: 51 Issue: 4 Pages: 299-313
  • DOI: 10.2343/geochemj.2.0470
  • NAID: 130005868317
  • ISSN: 0016-7002, 1880-5973
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Application of a handheld X-ray fluorescence spectrometer for real-time, high-density quantitative analysis of drilled igneous rocks and sediments during IODP Expedition 352 (2017)
  • Author(s): Ryan, J.G., J.W. Shervais, Y. Li, M.K. Reagan, H.Y. Li, D. Heaton, M. Godard, M. Kirchenbaur, S. Whattam, J.A. Pearce, T. Chapman, W. Nelson, J. Prytulak, K. Shimizu, K. Petronotis
  • Journal Title: Chemical Geology Volume: 451 Pages: 55-66
  • DOI: 10.1016/j.chemgeo.2017.01.007
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Subduction initiation and ophiolite crust: new insights from IODP drilling (2017)
  • Author(s): Reagan, M.K. et al. (共著者28名中27番目、アルファベット順）
  • Journal Title: International Geology Review Volume: - Issue: 11 Pages: 1-12
  • DOI: 10.1080/00206814.2016.1276482
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Ancient depleted mantle as a source of boninites in the Izu-Bonin-Mariana arc: Evidence from Os isotopes in Cr-spinel and magnetite (2016)
  • Author(s): R. Senda, K. Shimizu, and K. Suzuki
  • Journal Title: Chemical Geology Volume: 439 Pages: 110-119
  • DOI: 10.1016/j.chemgeo.2016.06.018
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Alkalic magmatism in the Lyra Basin: A missing link in the late-stage evolution of the Ontong Java Plateau (2015)
  • Author(s): SHIMIZU KENJI, Sano Takashi, TEJADA MARIA LUISA, HYODO Hironobu, SATO KEIKO, SUZUKI KATSUHIKO, CHANG QING, Nakanishi Masao
  • Journal Title: The Origin Evolution, and Environmental Impact of Oceanic Large igneous Provinces, Geological Society of America Special Paper 511 Volume: － Pages: 233-249
  • DOI: 10.1130/2015.2511(13)
  • Peer Reviewed
• [Journal Article] Isotopic evidence for a link between the Lyra Basin and Ontong Java Plateau. The Origin Evolution, and Environmental Impact of Oceanic Large igneous Provinces (2015)
  • Author(s): M. L. G. Tejada, K. Shimizu, K. Suzuki, T. Hanyu, T. Sano, M. Nakanishi, S. Nakai, A. Ishikawa, Q. Chang, T. Miyazaki, Y. Hirahara, T. Takahashi, and R. Senda
  • Journal Title: Geological Society of America Special Paper / Geological Society of America Volume: 511 Pages: 251-269
  • DOI: 10.1130/2015.2511(14)
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Hydrogen-rich hydrothermal environments in the Hadean ocean inferred from serpentinization of komatiites at 300° C and 500 bar (2015)
  • Author(s): Shibuya, T., Yoshizaki, M., Sato, M., Shimizu, K., Nakamura, K., Omori, S., Suzuki, K., Takai, K., Tsunakawa, H., Maruyama, S.
  • Journal Title: Progress in Earth and Planetary Science Volume: 2 Issue: 1 Pages: 1-11
  • DOI: 10.1186/s40645-015-0076-z
  • Peer Reviewed / Open Access
• [Journal Article] Noble gas evidence for the presence of recycled material in magma sources of Shatsky Rise (2015)
  • Author(s): Hanyu, T., Shimizu, K., Sano, T.
  • Journal Title: The Origin Evolution, and Environmental Impact of Oceanic Large igneous Provinces, Geological Society of America Special Paper Volume: 511 Pages: 57-67
  • DOI: 10.1130/2015.2511(03)
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Boron and Chlorine contents of basalts from Shatsky Rise, IODP Expedition 324: implications for the alteration of oceanic plateaus (2015)
  • Author(s): Masaya Miyoshi, Takashi Sano, Kenji Shimizu, Adelie Delacour, Toshiaki Hasenaka, Yasushi Mori, Takaaki Fukuoka
  • Journal Title: In: Neal C.R., Sager W., Sano T., Erba E（eds) The Origin, Evolution, and Environmental Impact of Oceanic Large Igneous Provinces. Geological Society of America Special Paper Volume: 511 Pages: 69-84
  • DOI: 10.1130/2015.2511(04)
  • Peer Reviewed / Int'l Joint Research
• [Presentation] 地球内部・表層環境における硫黄同位体比変動の研究に向けた局所硫黄２同位体比分析手法開発 (2017)
  • Author(s): Takayuki Ushikubo, Kenji Shimizu
  • Organizer: 日本地球惑星科学連合大会
  • Invited
• [Presentation] 局所同位体比分析で地球地殻の形成史を探る (2017)
  • Author(s): 牛久保孝行、清水健二、飯塚毅、上原啓幹、小宮剛、谷健一郎、上野雄一郎
  • Organizer: 日本地質学会
  • Invited
• [Presentation] Fluorine as a proxy of water in mantle (2017)
  • Author(s): 清水健二、伊藤元雄、常青、木村純一
  • Organizer: 日本地球惑星科学連合大会
• [Presentation] 海洋性玄武岩ガラスの水、フッ素、セリウムによるボラタイルマントルアレイの発見 (2017)
  • Author(s): 清水健二、伊藤元雄、常青、木村純一
  • Organizer: 日本地球化学会年会
• [Presentation] Hydrogen isotope analyses of forearc volcanic glasses from IODP Exp.352 using IMS 1280-HR (2016)
  • Author(s): T. Ushikubo, K. Shimizu, Y. Ueno
  • Organizer: Goldschmidt Conference 2016
  • Place of Presentation: パシフィコ横浜、神奈川県横浜市
  • Year and Date: 2016-06-28
  • Int'l Joint Research
• [Presentation] Significant uplift of the forearc at the subduction initiation inferred from volcanic glasses in the Bonin fore-arc (IODP Expedition 352) (2016)
  • Author(s): K. Shimizu, T. Ushikubo
  • Organizer: Goldschmidt Conference 2016
  • Place of Presentation: パシフィコ横浜、神奈川県横浜市
  • Year and Date: 2016-06-28
  • Int'l Joint Research
• [Presentation] Volatile behaviors at an immature stage of subduction zone -inferred from volcanic glasses in the Bonin forearc (IODP Exp. 352)- (2016)
  • Author(s): K. Shimizu, T. Ushikubo
  • Organizer: 日本地球惑星科学連合2016年大会
  • Place of Presentation: 幕張メッセ、千葉県千葉市
  • Year and Date: 2016-05-25
  • Int'l Joint Research / Invited
• [Presentation] A seamount on top of Ontong Java Plateau was created by remelting of plateau lithosphere by plate flexure (2016)
  • Author(s): T. Hanyu, M. L. G. Tejada, K. Shimizu, O. Ishizuka, J.-I. Kimura, Q. Chang, R. Senda, T. Miyazaki, K. Goto, A. Ishikawa
  • Organizer: 日本地球惑星科学連合2016年大会
  • Place of Presentation: 幕張メッセ、千葉県千葉市
  • Year and Date: 2016-05-23
  • Int'l Joint Research / Invited
• [Presentation] 超高空間分解能イメージングによる揮発性元素定量分析法の確立：メルト包有物への適用 (2015)
  • Author(s): 伊藤元雄、清水健二、牛久保孝行、小沢恭弘、岩森光
  • Organizer: 2015年度 日本地球化学会
  • Place of Presentation: 神奈川県横浜市 横浜国立大学
  • Year and Date: 2015-09-17
• [Presentation] NanoSIMSによる火山ガラス中の揮発性物質量の分析法ー標準試料の作成、値付けを含めた開発 (2015)
  • Author(s): 清水健二、伊藤元雄、浜田盛久、高橋栄一
  • Organizer: 2015年度 日本地球化学会
  • Place of Presentation: 神奈川県横浜市 横浜国立大学
  • Year and Date: 2015-09-16
• [Presentation] Remelting of Ontong Java Plateau Lithosphere (2015)
  • Author(s): Hanyu, T., Tejada, M.L., Shimizu, K., Ishikawa, A., Kimura, J.-I., Chang, Q.,Senda, R., Miyazaki, T., Goto, K., Ishizuka, O.
  • Organizer: 2015 Goldschmidt Conference
  • Place of Presentation: プラハ（チェコ） コングレスセンター
  • Year and Date: 2015-08-20
  • Int'l Joint Research
• [Presentation] 南鳥島周辺海域のプチスポット (2015)
  • Author(s): 平野 直人, 岩野 英樹, 清水 健二, 森下 泰成, 田村 明弘, 角野 浩史, 坂田 周平, 町田 嗣樹, 石井 輝秋, 檀原 徹, 荒井 章司, 平田 岳史
  • Organizer: 日本地球惑星科学連合2015年大会
  • Place of Presentation: 千葉県千葉市 幕張メッセ
  • Year and Date: 2015-05-28
• [Presentation] Overview of IODP Expedition 352: Testing subduction initiation and ophiolite models by drilling the outer IBM fore-arcs (2015)
  • Author(s): Shimizu, K., Michibayashi, K., Sakuyama, T., Python, M., IODP Exp.352 Scientists
  • Organizer: 日本地球惑星科学連合2015年大会
  • Place of Presentation: 千葉県千葉市 幕張メッセ
  • Year and Date: 2015-05-27
  • Int'l Joint Research / Invited
• [Presentation] 高知コア研究所におけるSIMSを用いた高精度局所同位体比分析法開発の取り組みと、今後の研究の展望 (2015)
  • Author(s): 牛久保孝行, 伊藤元雄, 富岡尚敬, 清水健二, 石川剛志
  • Organizer: 日本地球惑星科学連合2015年大会
  • Place of Presentation: 千葉県千葉市 幕張メッセ
  • Year and Date: 2015-05-26
• [Presentation] IODP Expedition 352 前弧玄武岩とボニナイトの掘削成功 (2015)
  • Author(s): 柵山徹也，道林克禎，Python Marie，清水健二，IODP EXP352乗船研究者一同
  • Organizer: 日本地球惑星科学連合2015年大会
  • Place of Presentation: 千葉県千葉市 幕張メッセ
  • Year and Date: 2015-05-24
• [Patent(Industrial Property Rights)] 仕上研磨用定盤、仕上研磨装置 (2016)
  • Inventor(s): 清水健二
  • Industrial Property Rights Holder: 海洋研究開発機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2016-026048
  • Filing Date: 2016-02-15