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Systematic study of cold ion-polar molecule reactions for interstellar chemistry

Research Project

Project/Area Number 15H03753
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Geochemistry/Cosmochemistry
Research InstitutionSophia University

Principal Investigator

Okada Kunihiro  上智大学, 理工学部, 教授 (90311993)

Co-Investigator(Kenkyū-buntansha) 崎本 一博  国立研究開発法人宇宙航空研究開発機構, その他部局等, 助教 (60170627)
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2015: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywordsイオン極性分子反応 / シュタルク分子速度フィルター / イオントラップ / クーロン結晶 / 星間分子 / レーザー冷却 / 低温イオン分子反応 / 極性分子 / 捕獲速度定数 / PRS理論 / イオン分子反応
Outline of Final Research Achievements

The purpose of this study is to develop a new temperature variable Stark velocity filter in order to clarify the reaction temperature dependence of various ion-polar molecular reactions at low temperatures. In this study, we developed a Wavy Stark velocity filter and succeeded in changing the translational temperature of acetonitrile (CH3CN) over 6.5-110 K without changing the output beam position of polar molecular beams. Additionally, we succeeded in measuring the translational temperature dependence of the reaction rate constant of CH3CN + Ne+ → products and found that there is a large translational temperature dependence in the reaction probability. The completion of the Wavy Stark velocity filter has paved the way to experimentally reveal the translational temperature dependence of ion-polar molecular reactions at low temperatures.

Academic Significance and Societal Importance of the Research Achievements

本研究の成果によって,これまで実験が困難であった低温(-260℃~-173℃)におけるイオンと極性分子の気相化学反応を測定する手段を新たに提供できるようになったこと,およびそれを用いた実証実験に成功したことが学術的に重要な貢献であると考える。

Report

(4 results)
  • 2018 Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (29 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Remarks (2 results)

  • [Int'l Joint Research] Texas A&M University(米国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Dipole enhancement of the protonium formation cross section in antiproton collisions with excited hydrogen atoms2018

    • Author(s)
      K Sakimoto
    • Journal Title

      Eur. Phys. J. D

      Volume: 72 Issue: 1 Pages: 171-7

    • DOI

      10.1140/epjd/e2017-80394-0

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 衝突反応における形状共鳴の系統的な見方2018

    • Author(s)
      崎本一博
    • Journal Title

      日本物理学会誌

      Volume: 73 Pages: 6-14

    • NAID

      130007472153

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a wavy Stark velocity filter for studying interstellar chemistry2017

    • Author(s)
      K. Okada, Y. Takada, N. Kimura, M. Wada, and H.A. Schuessler
    • Journal Title

      Review of Scientific Instruments

      Volume: 88 Issue: 8 Pages: 0831061-11

    • DOI

      10.1063/1.4997721

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] イオンのクーロン結晶が拓く星間分子生成反応の研究2016

    • Author(s)
      岡田 邦宏
    • Journal Title

      日本物理学会誌

      Volume: 71 Pages: 695-700

    • NAID

      130006906737

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Systematics of shape resonances in reactive collisions2016

    • Author(s)
      K Sakimoto
    • Journal Title

      Physical Review A

      Volume: 94 Issue: 4

    • DOI

      10.1103/physreva.94.042701

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quasi-equilibrium characterization of mixed ion Coulomb crystals2015

    • Author(s)
      Kunihiro Okada, Masanari Ichikawa, Michiharu Wada, and Hans A. Schuessler
    • Journal Title

      Physical Review Applied

      Volume: 4 Issue: 5

    • DOI

      10.1103/physrevapplied.4.054009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Characterization of ion Coulomb crystals for fundamental sciences2015

    • Author(s)
      Kunihiro Okada, Masanari Ichikawa, MichiharuWada
    • Journal Title

      Hyperfine Interactions

      Volume: 236 Issue: 1-3 Pages: 87-94

    • DOI

      10.1007/s10751-015-1188-y

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction rate measurements between sympathetically cooled ions and velocity selected polar molecules: search for the deuterium isotope effects2015

    • Author(s)
      Yusuke Takada and Kunihiro Okada
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 635 Issue: 2 Pages: 022031-022031

    • DOI

      10.1088/1742-6596/635/2/022031

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of antiprotonic helium and ionization in low-energy collisions of antiprotons with He atoms in the ground and metastable states2015

    • Author(s)
      K. Sakimoto
    • Journal Title

      Physical Review A

      Volume: 91 Issue: 4

    • DOI

      10.1103/physreva.91.042502

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of true-muonium formation in muon collision processes2015

    • Author(s)
      K Sakimoto
    • Journal Title

      Eur. Phys. J. D

      Volume: 69 Issue: 12

    • DOI

      10.1140/epjd/e2015-60427-6

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] 低温イオン-極性分子反応の分岐比測定へ向けたイオントラップ飛行時間型質量分析計の開発2018

    • Author(s)
      岡田邦宏,木村直樹,和田道治,Hans A. Schuessler
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] リニア型シュタルク分子速度フィルターによる低速分子線の生成2017

    • Author(s)
      高田裕介,木村直樹,和田道治, Hans A. Schuessler, 岡田邦宏
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 反陽子と励起水素原子の衝突における反陽子水素生成断面積の異常増大2017

    • Author(s)
      崎本一博
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] A laboratory study of interstellar ion-polar molecule reactions2017

    • Author(s)
      Kunihiro Okada
    • Organizer
      1st North American Conference on Trapped Ions (NACTI 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 反陽子とポジトロニウムの衝突による反水素生成:elliptic state による違い2017

    • Author(s)
      崎本一博
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 温度可変シュタルク分子速度フィルターの開発2016

    • Author(s)
      高田裕介,岡田邦宏
    • Organizer
      原子衝突学会第41回年会
    • Place of Presentation
      富山大学五福キャンパス(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 温度可変シュタルク分子速度フィルターの開発II2016

    • Author(s)
      高田裕介,岡田邦宏,
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学角間キャンパス(石川県・金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 衝突反応に見られる形状共鳴の系統的解析2016

    • Author(s)
      崎本一博
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学角間キャンパス(石川県・金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Study on the Effective Rotational Temperature Dependence of the Reaction-Rate Constants between Cold Ions and Slow Polar Molecules2016

    • Author(s)
      Yusuke Takada, Kunihiro Okada
    • Organizer
      12th European Conference on Atoms, Molecules and Photons(ECAMP12)
    • Place of Presentation
      Goethe-University, Campus Westend (Frankfurt am Main, Germany)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオンのクーロン結晶が拓く低温イオン化学2016

    • Author(s)
      岡田邦宏
    • Organizer
      第64回質量分析総合討論会
    • Place of Presentation
      ホテル阪急エキスポパーク(大阪府・吹田市)
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 温度可変シュタルク分子速度フィルターの開発2016

    • Author(s)
      高田裕介,岡田邦宏
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学,宮城県仙台市
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 衝突反応における形状共鳴の新しい見方2016

    • Author(s)
      崎本一博
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学,宮城県仙台市
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低温イオン-極性分子反応における回転温度依存性の検出2015

    • Author(s)
      高田裕介,岡田邦宏
    • Organizer
      原子衝突学会第40回年会
    • Place of Presentation
      首都大学東京,東京都八王子市
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] 共鳴多光子イオン化によって生成した冷却O2+分子イオンと低速極性分子の反応速度測定2015

    • Author(s)
      高田裕介,岡田邦宏
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学,大阪府吹田市
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 原子衝突過程によるtrue-muonium生成反応の理論的研究2015

    • Author(s)
      崎本一博
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学,大阪府吹田市
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Reaction rate measurements between sympathetically cooled ions and velocity selected polar molecules: search for the deuterium isotope effects2015

    • Author(s)
      Yusuke Takada and Kunihiro Okada
    • Organizer
      XXIX International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC2015)
    • Place of Presentation
      Toledo, Spain, Toledo Congress Centre
    • Year and Date
      2015-07-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 上智大学理工学部・原子物理研究室

    • URL

      http://www.ph.sophia.ac.jp/~ttak-ken/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 上智大学理工学部・原子物理研究室

    • URL

      http://www.ph.sophia.ac.jp/~ttak-ken/index.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2022-08-26  

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