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Creation of new nanospaces which have adjustable pore size and molecular separation property

Research Project

Project/Area Number 15H03767
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionShinshu University

Principal Investigator

Iiyama Taku  信州大学, 学術研究院理学系, 教授 (30313828)

Co-Investigator(Kenkyū-buntansha) 内田 太郎  信州大学, 先鋭領域融合研究群環境・エネルギー材料科学研究所, 助教(特定雇用) (70581643)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords微小空間設計 / ナノ空間 / 吸着 / 分子分離 / 分子貯蔵 / イオン液体 / 機能性空間 / 機能性材料 / 表面・界面物性 / 先端機能デバイス / 反応・分離工学 / 化学物理 / ナノ材料 / パラフィン / 空間制御 / 分子混合 / 有害物質除去 / グリーンケミストリー
Outline of Final Research Achievements

There is a strong demand for establish of an efficient molecular separation method without energy consuming. In this study, we introduce nonvolatile liquids such as ionic liquids into nanospaces to adjust the effective pore size and the molecular separation properties.
We used Ionic liquids and paraffins as the nonvolatile substance, and mesoporous silicas as the adsorption medium. We established its synthesis method and characterizing adsorption properties and was confirmed that the effective pore size of the synthesized porous materials can be controlled, and it exhibits specific adsorption phenomenon for some organic molecules.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (24 results)

All 2018 2017 2016 2015

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Journal Article] Mesoscopic Investigation of an “Immiscible” Cyclohexane and Water Micro-Mixture in Carbon Micropores by Contrast Variation Small-Angle Neutron Scattering2018

    • Author(s)
      Masatsugu Yoshimoto, Yukihiko Yoshida, Yohei Noda, Satoshi Koizumi, Shinichi Takata, Junichi Suzuki, Akinori Hoshikawa, Toru Ishigaki, Sumio Ozeki, Taku Iiyama
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 3 Pages: 336-339

    • DOI

      10.1246/cl.171055

    • NAID

      130006434031

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Is Physisorption Useful for Fine Pore Structure Control? Control of Pore Structure and Properties of SBA-15 by Paraffin Physisorption2018

    • Author(s)
      Taro Uchida, Minoru Deguchi, Keisuke Asakura, Sumio Ozeki, and Taku Iiyama
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 1 Pages: 27-30

    • DOI

      10.1246/cl.170873

    • NAID

      130006302109

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores2017

    • Author(s)
      Ryusuke Futamura, Taku Iiyama, Yuma Takasaki, Yury Gogotsi, Mark Biggs, Mathieu Salanne, Julie Segalini, Patrice Simon, Katsumi Kaneko
    • Journal Title

      Nature Materials

      Volume: 16 Issue: 12 Pages: 1225-1232

    • DOI

      10.1038/nmat4974

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Kinetics of Interlayer Expansion of a Layered Silicate Driven by Caffeine Intercalation in the Water Phase Using Transmission X-ray Diffraction2017

    • Author(s)
      Tomohiko Okada, Takumi Yoshida, Taku Iiyama
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 121 Pages: 6919-6925

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusually Stable Plastic Crystal Phase of CCl4 Confined in Graphitic Slit-Shaped Micropores from Neutron Diffraction2017

    • Author(s)
      Masatsugu Yoshimoto, Ryusuke Futamura, Akinori Hoshikawa, Toru Ishigaki, Taro Uchida, Taku Iiyama
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 7 Pages: 923-925

    • DOI

      10.1246/cl.170142

    • NAID

      130005709516

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 物質添加による細孔特性制御2017

    • Author(s)
      出口 実、浅倉啓介、是兼由李子、尾関寿美男、内田太郎、飯山 拓
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜、慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effects of polarization on superionic state in nanopores between conductive carbon walls2017

    • Author(s)
      FUTAMURA Ryusuke, IIYAMA Taku, SIMON Patrice, SALANNE Mathieu, GOGOTSI Yury, KANEKO Katsumi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜、慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Intermolecular Structure of Binary Mixture in Confined Spaces: by XRD, ND, and RMC2017

    • Author(s)
      Taku Iiyama, Masatsugu Yoshimoto, Ryusuke Futamura, Toshiya Otomo and Sumio Ozeki
    • Organizer
      6th Symposium on Challenges for Carbon-based Nanoporous Materials (CBNM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mesoscopic Investigation to Binary Mixture of Water and Cyclohexanbe by SANS and ND2017

    • Author(s)
      Masatsugu Yoshimoto, Taku Iiyama
    • Organizer
      6th Symposium on Challenges for Carbon-based Nanoporous Materials (CBNM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パラフィンの物理吸着によるSBA15の吸着特性制御2017

    • Author(s)
      出口実、内田太郎、尾関 寿美男、飯山 拓
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カーボンナノ細孔中でイオン液体が形成する“非クーロン的”構造の制約依存性2017

    • Author(s)
      二村竜祐、飯山拓、Patrice Simon、Mathieu Salanne、Mark J. Biggs、Yury Gogotsi、金子克美
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 細孔径分布を考慮した吸着アルゴンの分子間構造の検討2017

    • Author(s)
      吉元政嗣、二村竜祐、飯山拓
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] コンファインド系における水・エタノール混合状態の分子構造の解析2016

    • Author(s)
      吉元政嗣、飯山拓、尾関寿美男、大友季哉
    • Organizer
      日本中性子科学会第16回年会
    • Place of Presentation
      名古屋、名古屋大学
    • Year and Date
      2016-12-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Non-Coulombic Structure of Ionic Liquid Confined in Carbon Micropores with HR MC-Aided X-Ray Scattering2016

    • Author(s)
      Katsumi Kaneko, Ryusuke Futamura, Taku Iiyama, Yuma Takasaki, Mathieu Salanne, Yury Gogotsi, Mark Biggs and Patrice Simon
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      アメリカ、San Francisco
    • Year and Date
      2016-11-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Intermolecular Structure of Binary Mixture in Confined Spaces2016

    • Author(s)
      Taku Iiyama, Masatsugu Yoshimoto, Ryusuke Futamura, Toshiya Otomo and Sumio Ozeki
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      アメリカ、San Francisco
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 物質添加による細孔構造制御2016

    • Author(s)
      出口実、是兼由季子、浅倉啓介、内田太郎、尾関寿美男、飯山拓
    • Organizer
      第30回日本吸着学会研究発表会
    • Place of Presentation
      長崎、長崎大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 回折法とHRMC法を用いた疎水性ナノ空間中における水-エタノール混合状態の分子間構造の解明2016

    • Author(s)
      吉元政嗣、飯山拓、尾関寿美男、大友季哉
    • Organizer
      第30回日本吸着学会研究発表会
    • Place of Presentation
      長崎、長崎大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] X線を用いた細孔中の電解質溶液構造の解明2016

    • Author(s)
      黒木崇伸、吉元政嗣、棚池修、二村竜祐、内田太郎、飯山拓
    • Organizer
      第30回日本吸着学会研究発表会
    • Place of Presentation
      長崎、長崎大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Study of binary mixture structure of water and ethanol in slit-like pore by X-ray and neutron diffraction and Hybrid Reverse Monte Carlo method2016

    • Author(s)
      M. Yoshimoto, T. Iiyama, S. Ozeki, T. Otomo
    • Organizer
      12th International Conference on the Fundamentals of Adsorption (FOA12)
    • Place of Presentation
      Friedrichshafen/Lake Constance, Germany
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of intermolecular structures of water and solutions in confined spaces by reverse Monte Carlo method2016

    • Author(s)
      T. Iiyama, R. Futamura, T. Ota, M. Yoshimoto, A. Hoshikawa, T. Ishigaki
    • Organizer
      12th International Conference on the Fundamentals of Adsorption (FOA12)
    • Place of Presentation
      Friedrichshafen/Lake Constance, Germany
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体 Emim[EtSO4]による SBA-15 の表面修飾と吸着挙動の解明2015

    • Author(s)
      是兼由李子、浅倉啓介、内田太郎、尾関寿美男、飯山拓
    • Organizer
      第29回日本吸着学会研究発表会
    • Place of Presentation
      徳島大学
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] メソポーラスシリカへのイオン液体の修飾とその手法の検討2015

    • Author(s)
      是兼 由李子、浅倉 啓介、飯山 拓、尾関 寿美男
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 2成分混合吸着における水素結合構造のマクロな視点からの解明2015

    • Author(s)
      井上奈穂、牧野浩之、内田太郎、飯山 拓
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] RMC法による細孔内イオン液体の構造解析2015

    • Author(s)
      飯山 拓、高崎 優真、是兼 由李子、吉元 政嗣、二村 竜祐、内田 太郎、尾関 寿美男
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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