Creation of Transition-metal Complexes with Anionic Aromatic Ligands Bearing Heavy Atoms in the Skeletons
| Project/Area Number |
15H03774
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Saitama University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
山本 芳彦 名古屋大学, 工学(系)研究科(研究院), 助教授 (60283412)
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| Co-Investigator(Renkei-kenkyūsha) |
TANAKA Ken 東京工業大学, 大学院物質理工学院, 教授 (40359683)
NAGASE Shigeru 京都大学, 福井謙一記念研究センター, シニアリサーチフェロー (30134901)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
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| Keywords | メタロール配位子 / 遷移金属錯体 / サンドイッチ構造 / 触媒反応 / スタンノール / トリプルデッカー型錯体 / 電子供与能 / アニオン性フェロセン / メタロール / 物性化学 / 触媒化学 / プルンボール / ナノ粒子 / ヘテロバイメタリック錯体 |
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| Outline of Final Research Achievements |
The reactions of dilithio-stannoles and a -plumbole, which are dianionic aromatic compounds, with transition-metal reagents afforded transition-metal complexes bearing stannole and plumbole ligands. The structures of thus obtained complexes were determined by X-ray diffraction analysis and their unique electronic characteristics and properties were evaluated. The reaction using the plumbole complex as a catalyst was found.
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Report
(4 results)
Research Products
(24 results)
