| Budget Amount *help |
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2017: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
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| Outline of Final Research Achievements |
One notable result is the [3 + 2] cyclization reaction of vinylaziridine and alkene realized for the first time by using bulky organic sulfur radical, and this work is published in a top chemistry journal, Angwandte Chemie International Edition. As for asymmetric synthesis catalyzed by thiyl radical, we succeeded in developing a new chiral scaffold that can perform cyclization reaction of vinylcyclopropane and alkene. Furthermore, in the carbon-carbon bond formation reaction accompanied by hydrogen atom transfer, we succeeded in developing the first catalytic reaction by thiyl radical.
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