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Development of Highly Selective Organic Transformation Based on the Planar-Chirality

Research Project

Project/Area Number 15H03780
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

Kamikawa Ken  大阪府立大学, 理学(系)研究科(研究院), 教授 (40316021)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2017: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywordsplanar-chirality / manganese complex / 面不斉 / 有機化学 / 面不斉遷移金属錯体 / 閉環メタセシス
Outline of Final Research Achievements

We reported catalytic enantioselective synthesis of planar chiral (arene)chromium complexes via asymmetric ring-closing metathesis. Meanwhile, corresponding Cp manganese complexes were also studied asymmetric ring-closing metathesis of the ortho-substituted Cp manganese complexes with two alkenyl tethers. As the results, we have succeeded to synthesize the planar chiral manganese complexes with extremely high enantioselectivities. Furthermore, an optically active manganese complex can be utilized as the precursor for the synthesis of chiral phosphine ligands with Cp manganese as a platform.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (59 results)

All 2018 2017 2016 2015

All Journal Article (13 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 13 results,  Acknowledgement Compliant: 7 results) Presentation (46 results) (of which Int'l Joint Research: 12 results,  Invited: 2 results)

  • [Journal Article] Synthesis of Substituted Helicenes by Ir-Catalyzed Annulative Coupling of Biarylcarboxylic Acid Chlorides with Alkynes2018

    • Author(s)
      Kamikawa, K.; Den, H.; Tsurusaki, A.; Nagata, T.; Miura, M.
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 91 Issue: 7 Pages: 1069-1074

    • DOI

      10.1246/bcsj.20180081

    • NAID

      130007404788

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1,1’-Binaphthyl-substituted Diphosphene: Synthesis, Structures, and Chiral Optical Properties2018

    • Author(s)
      Tsurusaki, A.; Ura, R.; Kamikawa, K.
    • Journal Title

      Dalton Trans.

      Volume: 47 Issue: 13 Pages: 4437-4441

    • DOI

      10.1039/c8dt00441b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molybdenum-Catalyzed Enantioselective Synthesis of Planar-Chiral (5h-Phosphacyclopentadienyl)manganese(I) Complexes and Application in Asymmetric Catalysis2017

    • Author(s)
      Ogasawara, M.; Tseng, Y.-Y.; Uryu, M.; Ohya, N.; Chang, N.; Ishimoto, H.; Arae, S.; Takahashi, T.; Kamikawa, K.
    • Journal Title

      Organometallics

      Volume: 36 Issue: 20 Pages: 4061-4069

    • DOI

      10.1021/acs.organomet.7b00704

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntehsis, Structures, and Properties of Hexapole Helicenes: Assembling Six [5]Helicene Substructures into Highly Twisted Aromatic Systems2017

    • Author(s)
      Hosokawa, T.; Takahashi, Y.; Matsushima, T.; Watanabe, S.; Kikkawa, S.; Azumaya, I.; Tsurusaki, A.; Kamikawa, K.
    • Journal Title

      J. Am Chem. Soc.

      Volume: 139 Issue: 51 Pages: 18512-18521

    • DOI

      10.1021/jacs.7b07113

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates2017

    • Author(s)
      Hoshimoto Yoichi、Ashida Keita、Sasaoka Yukari、Kumar Ravindra、Kamikawa Ken、Verdaguer Xavier、Riera Antoni、Ohashi Masato、Ogoshi Sensuke
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 28 Pages: 8206-8210

    • DOI

      10.1002/anie.201703187

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Kinetic Resolution of Planar-Chiral (h5-Bromocyclopentaddenyl)manganese(I) Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis2017

    • Author(s)
      Ogasawara, M.; Tseng, Y.-Y.; Liu, Q.; Chang, N.; Yang, X.; Takahashi, T.; Kamikawa, K.
    • Journal Title

      Organometallics

      Volume: 36 Issue: 7 Pages: 1430-1435

    • DOI

      10.1021/acs.organomet.7b00125

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganeses (I) Scaffold to Achieve High Enantioselectivity2017

    • Author(s)
      Kamikawa, K.; Tseng, Y.-Y.; Jisn, J.-H.; Takahashi, T.; Ogasawara, M.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 4 Pages: 1545-1553

    • DOI

      10.1021/jacs.6b11243

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganeses (I) Scaffold to Achieve High Enantioselectivity2017

    • Author(s)
      Kamikawa, K.; Tseng, Y.-Y.; Jisn, J.-H.; Takahashi, T.; Ogasawara, M.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Pages: 1545-1553

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of N-Aryl Carbazoles by a Palladium-Catalyzed Direct C-H Arylation of 2-N,N-(Diarylamino)phenyl Triflates2017

    • Author(s)
      Uwa, K.; Tseng, Y.-Y.; Kamikawa, K.
    • Journal Title

      Eur. J. Org. Chem..

      Volume: 11 Issue: 4 Pages: 892-895

    • DOI

      10.1002/ejoc.201601467

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Stereoselective synthesis of N-arylindoles and related compounds with axially chiral N–C bond2016

    • Author(s)
      Kinoshita, S.; Kamikawa, K.
    • Journal Title

      Tetrahedron

      Volume: - Issue: 34 Pages: 1-6

    • DOI

      10.1016/j.tet.2015.11.053

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ring-Closing Metathesis of (η5-Alkenylcyclopentadienyl)(alkenylphosphine)manganese(I) Dicarbonyl Complexes2015

    • Author(s)
      Tseng, Y.-Y.; Kamikawa, K.; Wu, Q.; Takahashi, T.; Ogasawara, M.
    • Journal Title

      Adv. Synth. Catal.

      Volume: 357 Issue: 10 Pages: 2255-2264

    • DOI

      10.1002/adsc.201500343

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous Induction of Axial and Planar-Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis2015

    • Author(s)
      K. Kamikawa, S. Arae, W.-Y. Wu, C. Nakamura, T. Takahashi, M. Ogasawara
    • Journal Title

      Chemistry-A European Journal

      Volume: 21 Issue: 13 Pages: 4954-4957

    • DOI

      10.1002/chem.201500226

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Double Helicene by a Palladium-Catalyzed Cross-Coupling Reaction: Structure and Pysical Properties2015

    • Author(s)
      Kashihara, H.; Asada, T.; Kamikawa, K.
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 17 Pages: 6521-6527

    • DOI

      10.1002/chem.201500074

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ヘリセニルトリプチセンの合成と物性2018

    • Author(s)
      川西 紘輝・高橋 裕輔・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] [5]および[7]ヘリセン構造を有する六重ヘリセンに関する合成、および理論化学的考察2018

    • Author(s)
      細川 朋佳・麻田 俊雄・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of S-shaped diaza [10] helicene by palladium-catalyzed double dehydrogenative C-H coupling reaction2018

    • Author(s)
      KAWASHIMA, Takahiro; TAKAHASHI, Yusuke; TSURUSAKI, Akihiro; KAMIKAWA, Ken
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ジベンゾ[b,e]ホスフィンドリジン-4-スルフィドの合成2018

    • Author(s)
      松本 啓世・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ヘリセニルアライン重合によるポリ[5]ヘリセンの合成と物性2018

    • Author(s)
      高橋 裕輔・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 軸不斉ビナフチル置換ジホスフェンの光学特性2018

    • Author(s)
      浦 里華子・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] トリス(2,6-ジビニルフェニル)ホスフィンの閉環メタセシス反応2018

    • Author(s)
      嶋谷 洋輝・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Catalytic Asymmetric Synthesis of Planer-Chiral Ferrocenyl Complexes via Rh-Catalyzed Asymmetric Ring-Opening Reaction2018

    • Author(s)
      ISODA, Takamu; OHYA, Naoki; TSURUSAKI, Akihiro; KAMIKAWA, Ken
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 面不斉金属錯体を基盤とするホスフィン‐オレフィン配位子の合成と不斉触媒反応への応用2018

    • Author(s)
      大矢 直輝・曾 雅怡・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 面不斉金属錯体を基盤とするホスフィン‐オレフィン配位子の合成と不斉触媒反応への応用2017

    • Author(s)
      大矢 直輝・曾 雅怡・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      東京、慶応義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 1,1'-ビナフチル置換ジホスフェンの合成2017

    • Author(s)
      浦 里華子・津留崎 陽大・神川 憲
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      東京、慶応義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] [5]ヘリセン誘導体の[2+2+2]環化三量化反応による六重ヘリセンの合成と物性2017

    • Author(s)
      細川朋佳・津留崎陽大・神川憲
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      東京、慶応義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 6つの[5]ヘリセン骨格を持つ六重ヘリセンの熱異性化挙動2017

    • Author(s)
      細川朋佳・津留崎陽大・神川憲
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      東京、慶応義塾大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis and Structures of 1,1’-Binaphthyl-Substituted Diphosphene and its Gold(I) Complex2017

    • Author(s)
      Rikako Ura, Akihiro Tsurusaki, Ken Kamikawa
    • Organizer
      Joint Symposium of Asia Five Universities
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ir-Catalyzed Annulative Coupling Reaction of Biarylcarboxylic Acid Chlorides with Alkynes to Synthesize Substituted Helicenes2017

    • Author(s)
      Hiroakira DEN, Tomoya NAGATA, Ken KAMIKAWA, Masahiro MIURA
    • Organizer
      Joint Symposium of Asia Five Universities
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of Hexapole Helicenes with Highly Distorted Structures2017

    • Author(s)
      Tomoka HOSOKAWA, Yusuke TAKAHASHI, Tomoya MATSUSHIMA, Soichiro WATANABE, Shoko KIKKAWA, Isao AZUMAYA, Akihiro TSURUSAKI, Ken KAMIKAWA
    • Organizer
      Joint Symposium of Asia Five Universities
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大きなねじれ構造を有する六重ヘリセンの合成、および物性2017

    • Author(s)
      細川朋佳・高橋裕輔・松島智也・吉川晶子・東屋功・渡邊総一郎・津留崎陽大・神川憲
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 1,1'-ビナフチル置換ジホスフェンと錯形成2017

    • Author(s)
      浦 里華子・津留崎 陽大・神川 憲
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] ビアリールカルボン酸クロリドとアルキンとから置換ヘリセン類を合成するためのイリジウム触媒による環化反応の研究2017

    • Author(s)
      傳 浩聡、神川 憲、永田 智也、三浦雅博
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 面不斉ハーフメタロセン配位子を活用した不斉触媒反応2017

    • Author(s)
      大矢直輝・曽雅怡・津留崎陽大・神川憲
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ビアリールカルボン酸クロリドとアルキンとから置換ヘリセン類を合成するためのイリジウム触媒による環化反応の研究2017

    • Author(s)
      傳 浩聡、永田 智也、神川 憲、三浦雅博
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 1,1'-ビナフチル置換ジホスフェンとその金(I)錯体の合成と構造2017

    • Author(s)
      浦 里華子・津留崎 陽大・神川 憲
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大きなねじれ構造を有する六重ヘリセンの合成、および物性2017

    • Author(s)
      細川朋佳・高橋裕輔・松島智也・吉川晶子・東屋功・渡邊総一郎・津留崎陽大・神川憲
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of Phosphine-Olefin Ligands Based on a Planar-Chiral Transition-Metal Scaffold: Highly Active and Robust Asymmetric Catalysis2016

    • Author(s)
      Ken Kamikawa
    • Organizer
      11th International Conference of Cutting-Edge Organic Chemistry in Asia (ICCEOCA-11)
    • Place of Presentation
      Korea
    • Year and Date
      2016-10-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 面不斉シクロペンタジエニルマンガンカルボニル錯体を基盤とした第二世代型P-オレフィン配位子の開発2016

    • Author(s)
      神川 憲、チェン ヤーイー、小笠原正道
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京、早稲田大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] イリジウム触媒を用いるビアリールカルボン酸クロライドとアルキンとの環化反応による置換ヘリセン類の合成2016

    • Author(s)
      傳 浩聡、永田 智也、神川 憲、三浦雅博
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京、早稲田大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Development of Phosphine-Olefin Ligands Based on a Planar-Chiral Transition-Metal Scaffold: Highly Active and Robust Asymmetric Catalysisment of Phosphine-Olefin Ligands Based on a Planar-Chiral Transition-Metal Scaffold: Highly Active and Robust Asymmetric Catalysis2016

    • Author(s)
      Ken Kamikawa
    • Organizer
      International Symposium on Pure & Applied Chemistry 2017
    • Place of Presentation
      Malaysia
    • Year and Date
      2016-08-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Phosphine-Olefin Ligands Based on a Planar-Chiral Transition-Metal Scaffold: Design, Synthesis and Application in Asymmetric Catalysisd on a Planar-Chiral Transition-Metal Scaffold: Design, Synthesis and Application in Asymmetric Catalysis2016

    • Author(s)
      Ken Kamikawa, Ya-Yi Tseng, Tamotsu Takahashi, Masamichi Ogasawara
    • Organizer
      Molecular Chirality Asia 2016
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2016-04-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鈴木-宮浦クロスカップリングを用いた新規ダブルヘリセン類の合成およびその物性2016

    • Author(s)
      柏原 仁志・麻田 俊雄・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒C-H活性化反応を活用したアリールカルバゾール類の合成2016

    • Author(s)
      宇和 紘志・曾 雅怡・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd 触媒を用いた脱水素型C-Hカップリング反応によるアザヘリセン類の合成2016

    • Author(s)
      河野 兆治・松本 裕貴・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of Highly Efficient Planar-Chiral Phosphine-Olefin Ligands Based on Transition Metal Complexes and Their Application to Asymmetric Reactions2016

    • Author(s)
      4.TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ir触媒を用いるビアリールカルボン酸クロライドとアルキンとの環化反応による置換ヘリセン類の合成2016

    • Author(s)
      傳 浩聡・永田 智也・神川 憲・三浦 雅博
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis the planar chiral phosphine-olefin ligand based on the transition metal scaffold and application in asymmetric catalysis2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      The International Chemical Congress of PACIFIC BASIN SOCIETIES 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of the planar chiral phosphine-olefin ligand based on a transition metal scaffold and application in asymmetric catalysis2015

    • Author(s)
      KAMIKAWA, Ken; TSENG, Ya-Yi; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Azahelicene by Palladium-Catalyzed Dehydrogenative C-H Coupling Reaction2015

    • Author(s)
      KONO, Choji, MATSUMOTO,Yuki; KAMIKAWA Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic Asymmetric Synthesis of Axially Chiral Phosphinobiaryl by C-H Functionalization2015

    • Author(s)
      YASUDA, Rie; KAMIKAWA, Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ynthesis of Carbazoles by Palladium Catalyzed C-H Arylation2015

    • Author(s)
      UWA, Koji; TSENG, Ya-Yi; KAMIKAWA, Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ring-Closing Metathesis of (h5-Alkenylcyclopentadienyl) (Alkenylphophine)manganese(I) Dicarbonyl Complexes and Their Application to Asymmetric Reactions2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 面不斉遷移金属錯体を基盤とするホスフィンーオレフィン配位子の設計および不斉触媒反応への応用2015

    • Author(s)
      チェン ヤーイー・神川憲・高橋保・小笠原正道
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船橋(東京都・江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒下のクロスカップリング反応によりダブルヘリセンの合成および構造と物性2015

    • Author(s)
      柏原 仁志・麻田 俊雄・神川 憲
    • Organizer
      13.基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県・松山市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Planar Chiral Phosphine-Olefin Ligands Based on a Transition Metal Scaffold and Application in Asymmetric Catalysis2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      触媒討論会
    • Place of Presentation
      三重大学(三重県・津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒C-H結合活性化反応によるN-アリールカルバゾールの合成2015

    • Author(s)
      宇和 紘志・曾 雅怡・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd 触媒を用いた脱水素型C-Hカップリング反応によるアザヘリセン類の合成2015

    • Author(s)
      河野 兆治・松本 裕貴・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] モリブデン触媒不斉閉環メタセシスによる面不斉シクロペンタジエニル-マンガン錯体の触媒的不斉合成2015

    • Author(s)
      小笠原 正道・曾 雅怡・常 寧輝・呉 猜・呉 威毅・高橋 保・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] C-H官能基化による軸不斉ホスフィノビアリール類の触媒的不斉合成2015

    • Author(s)
      安田 理恵・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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