| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2015: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
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| Outline of Final Research Achievements |
We synthesized a number of new complexes containing transition metal-heavier Group 14 element (Si, Ge) multiple bonds (double bonds, triple bonds, etc.), and clarified the characteristic molecular structures of them. We examined the reactions of them with various organic molecules, and discovered several new types of reactions such as cycloaddition reactions, in which the metal-Group 14 element multiple bonds played important roles. Moreover, taking advantage of the characteristic reactivity of these complexes, we succeeded in developing some transformation reactions of organic molecules mediated or catalyzed by these complexes.
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